Malayaite (original) (raw)

A valid IMA mineral species

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About MalayaiteHide

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Colour:

Pale creamy-yellow, deep orange-yellow, white, colorless

Crystal System:

Monoclinic

Name:

Named after the type locality of Malaya, Malaysia. That is the mainland part of Malaysia (Peninsular Malaysia), located on the Malaysian Peninsula.

Titanite Group.

The tin (Sn4+) analogue of Titanite. Malayaite from Okehampton, England fluoresces very dull to very pale yellow in shortwave and barely perceptibly in longwave. The wollastonite associated with malayaite fluoresces a moderately bright creamy-yellow and is frequently confused as malayaite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2552:8

d193f63b-ddbe-4d01-8743-e5aaa81a7ea8

IMA Classification of MalayaiteHide

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Type description reference:

Classification of MalayaiteHide

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9.AG.15

9 : SILICATES (Germanates)
A : Nesosilicates
G : Nesosilicates with additional anions; cations in > [6] +- [6] coordination

52.4.3.2

52 : NESOSILICATES Insular SiO4 Groups and O,OH,F,H2O
4 : Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] and/or >[6] coordination

14.12.2

14 : Silicates not Containing Aluminum
12 : Silicates of Sn

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Mly IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of MalayaiteHide

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Pronunciation:

Play Recorded by Country
Sorry, your browser doesn't support HTML5 audio. Jolyon Ralph United Kingdom

Physical Properties of MalayaiteHide

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Transparency:

Translucent, Opaque

Colour:

Pale creamy-yellow, deep orange-yellow, white, colorless

Density:

4.3(2) g/cm3 (Measured) 4.55 g/cm3 (Calculated)

Optical Data of MalayaiteHide

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RI values:

_n_α = 1.764 - 1.765 _n_β = 1.783 - 1.786 _n_γ = 1.798 - 1.801

δ = 0.034 - 0.036

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of MalayaiteHide

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Mindat Formula:

CaSn(SiO4)O

Crystallography of MalayaiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 7.156(6) Å, b = 8.895(9) Å, c = 6.668(4) Å
β = 113.4(1)°

Ratio:

a:b:c = 0.804 : 1 : 0.75

Unit Cell V:

389.53 ų (Calculated from Unit Cell)

Morphology:

Crystals wedge-shaped, up to 3 cm; massive, as a coating on cassiterite

Comment:

Space Group: A2/a

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0000586 Malayaite Higgins J B, Ribbe P H (1977) The structure of malayaite, CaSnOSiO4, a tin analog of titanite American Mineralogist 62 801-806 1977 0 293
0002981 Malayaite Rath S, Kunz M, Miletich R (2003) Pressure-induced phase transition in malayaite, CaSnOSiO4 American Mineralogist 88 293-300 2003 0 293
0002982 Malayaite Rath S, Kunz M, Miletich R (2003) Pressure-induced phase transition in malayaite, CaSnOSiO4 American Mineralogist 88 293-300 2003 4.238 293
0002983 Malayaite Rath S, Kunz M, Miletich R (2003) Pressure-induced phase transition in malayaite, CaSnOSiO4 American Mineralogist 88 293-300 2003 4.505 293
0002984 Malayaite Rath S, Kunz M, Miletich R (2003) Pressure-induced phase transition in malayaite, CaSnOSiO4 American Mineralogist 88 293-300 2003 5.769 293
0002985 Malayaite Rath S, Kunz M, Miletich R (2003) Pressure-induced phase transition in malayaite, CaSnOSiO4 American Mineralogist 88 293-300 2003 7.33 293
0008233 Malayaite Zhang M, Meyer H W, Groat L A, Bismayer U, Salje E K H, Adiwidjaja G (1999) An infrared spectroscopic and single-crystal X-ray study of malayaite, CaSnSiO5 Physics and Chemistry of Minerals 26 546-553 1999 0 293
0008234 Malayaite Zhang M, Meyer H W, Groat L A, Bismayer U, Salje E K H, Adiwidjaja G (1999) An infrared spectroscopic and single-crystal X-ray study of malayaite, CaSnSiO5 Physics and Chemistry of Minerals 26 546-553 1999 0 293
0008235 Malayaite Zhang M, Meyer H W, Groat L A, Bismayer U, Salje E K H, Adiwidjaja G (1999) An infrared spectroscopic and single-crystal X-ray study of malayaite, CaSnSiO5 Physics and Chemistry of Minerals 26 546-553 1999 0 293
0008236 Malayaite Zhang M, Meyer H W, Groat L A, Bismayer U, Salje E K H, Adiwidjaja G (1999) An infrared spectroscopic and single-crystal X-ray study of malayaite, CaSnSiO5 Physics and Chemistry of Minerals 26 546-553 1999 0 293
0008237 Malayaite Zhang M, Meyer H W, Groat L A, Bismayer U, Salje E K H, Adiwidjaja G (1999) An infrared spectroscopic and single-crystal X-ray study of malayaite, CaSnSiO5 Physics and Chemistry of Minerals 26 546-553 1999 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.28 Å (100)
5.05 Å (50)
2.639 Å (45)
3.06 Å (35)
2.665 Å (30)
2.412 Å (20)
2.099 Å (20)

Geological EnvironmentHide

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Type Occurrence of MalayaiteHide

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General Appearance of Type Material:

Yellow coatings on cassiterite crystals.

Place of Conservation of Type Material:

Geological Setting of Type Material:

Hydrothermal alteration of a cassiterite-quartz assemblage.

Associated Minerals at Type Locality:

Reference:

Ingham, F.T. and Bradford, E.F. (1960) The geology and mineral resources of the Kinta Valley, Perak Federation of Malaya. Geological Survery District Memoir No.9: 1-347, esp.105.

Synonyms of MalayaiteHide

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Other Language Names for MalayaiteHide

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Relationship of Malayaite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Fluorescence of MalayaiteHide

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very pale to very dull orange-yellow or yellow-green under SW UV. May be associated with much brighter yellow-fluorescing species such as wollastonite.

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for MalayaiteHide

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Reference List:

Groat, Lee A., Kek, Stefan, Bismayer, Ulrich, Schmidt, Claudia, Krane, Hans Georg, Meyer, Hinrich, Nistor, Leona, van Tendeloo, Gustaaf (1996) A synchrotron radiation, HRTEM, X-ray powder diffraction, and Raman spectroscopic study of malayaite, CaSnSiO5. American Mineralogist, 81 (5) 595-602 doi:10.2138/am-1996-5-606

Malcherek, Thomas, Paulenz, Bianca, Fischer, Michael, Paulmann, Carsten (2020) The modulated low-temperature structure of malayaite, CaSnOSiO4. Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, 76 (3) 316-321 doi:10.1107/s2052520620003807

Malcherek, Thomas, Fischer, Michael, Mihailova, Boriana, Paulenz, Bianca, Paulmann, Carsten, Bismayer, Ulrich (2024) Incommensurate to normal phase transition in malayaite. American Mineralogist, 109 (8) 1419-1428 doi:10.2138/am-2023-9063

Localities for MalayaiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia
New South Wales Ashburnham Co. Gumble Gumble Mine Mulholland (1984)
Cowper Co. Doradilla 3KEL prospect Byrnes (1993)
Bobs Tank prospect Byrnes (1993)
Doradilla DMK prospect (Doradilla-Midway prospect) Byrnes (1993)
East Midway prospect Byrnes (1993)
Midway prospect Burton et al. (2007)
Tasmania Burnie City Hampshire mining district Kara Mines Kara No. 1 Pit ? www.homestead.com (n.d.)
Canada
British Columbia Atlin Mining Division Tuya Range Ash Mountain King et al. (1993)
Yukon Watson Lake mining district Cassiar Mountains Screw Creek MW claim Rocks & Min.: 60 (1)
JC tin skarn deposit Layne et al. (1988)
Mindy prospect Liverton et al. (eds.)
Seagull Batholith JC deposit Layne et al. (1988)
China
Fujian Longyan Xinluo District Zhongjia Mine Da Zhang et al. (1999)
Guangxi Hechi Nandan County Dachang Sn-polymetallic ore field Hosking et al. (CaSnO2SiO2)
Hunan Chenzhou Beihu District Qitianling complex Furong Sn-polymetallic ore field Yan Shuang et al. (2009) +1 other reference
Jiangxi Jiujiang De'an Co. Jianfengpo Mine Wenxue Zhou and Wenliang Gao (1987) +1 other reference
Pengshan Sn-Pb-Zn ore field Poxi Mine Shudong Lu et al. (2004)
Zengjialong Sn-polymetallic deposit (Zhengjialong Sn-polymetallic deposit) Hansheng Cao (1982) +2 other references
Tibet Shannan Prefecture (Lhokha Prefecture; Lhoka Prefecture) Lhünzê Co. (Longzi Co.) Cuonadong dome Cuonadong Sn-W-Be deposit He et al. (2022)
Czech Republic
Hradec Králové Region Trutnov District Pec pod Sněžkou Obří důl Šrein +1 other reference
South Moravian Region Brno-Country District Nedvědice Houzar
Vysočina Region Havlíčkův Brod District Prosíčka Nezdín Horní Nezdín Unnamed skarn occurrence Švestka J. (Česká republika)
Žďár nad Sázavou District Bystřice nad Pernštejnem Kozlov Houzar et al. (2009) +1 other reference
Germany
Saxony Erzgebirgskreis Ehrenfriedersdorf Sauberg Mine Wittern (2001)
Grünhain-Beierfeld Waschleithe Fürstenberg hill Frisch Glück Mine (Herkules-Frisch Glück Mine) www.mineralienatlas.de (n.d.)
India
West Bengal Purulia District Balam Pahar ? Baidya (1981)
Italy
Piedmont Verbano-Cusio-Ossola Province Druogno Orcesco Alpe Rosso Guelfi F. et al. (1985)
Japan
Miyazaki Prefecture Nishiusuki District Hinokage Mitate mine Takenouchi (1971) +1 other reference
Takachiho Toroku Mine Miyahisa et al (1975) +2 other references
Oita Prefecture Bungo-Ono City Hoei mine (Hooei mine; Houei mine) Takenouchi (1971) +1 other reference
Okayama Prefecture Takahashi City Bitchū Shitouyouze Sampo mine Imai (1978) +1 other reference
Shimane Prefecture Masuda City Tsumo mine USGS Bulletin 1930 +1 other reference
Maruyama mine SOEDA et al. (1982)
Yamaguchi Prefecture Iwakuni City Kiwada mine Alfredo Petrov collection
Kuga mine (Kuka mine) Takenouchi (1971) +1 other reference
Ideno-oku orebody Imai (1978)
Shikada orebody Imai (1978)
Mine city Ofuku mine (Yamato mine) Nagashima et al. (2016)
Malaysia (TL)
Perak Batang Padang District Chenderiang Sungei Lah (Sungei Loh) /Sungei Chenderiang (TL) [Mineralogical Magazine (1965) +1 other reference
Morocco
Rabat-Salé-Kénitra Region Khémisset Province Khémisset Cercle Ait Mimoune Caïdat El Hammam El Hammam Mine Econ Geol (1989)
Oulmès Cercle Wadi Beht (Ouedi Beht; Beht River) Ph. M. Sonnet : "Burtite
Poland
Lower Silesian Voivodeship Kamienna Góra County Gmina Kamienna Góra Rędziny Dolomitic marble quarry Pieczka A. et al. (2006) +1 other reference
Kłodzko County Gmina Bystrzyca Kłodzka Marcinków ? Ł. Kruszewski PXRD & pXRF data (paper in preparation)
Russia
Magadan Oblast Canyonsk Sn deposit Политов В.К. (1983)
Republic of Karelia Pitkyarantsky District Pitkyaranta mining district Ivashchenko et al. (2006) +1 other reference
Thailand
Yala Province Pinyok Mine Charusiri et al. (1990)
UK
England Cornwall St Just Botallack Cliff outcrops Crowns Rock Golley et al. (1995)
Devon West Devon Okehampton Hamlets Meldon Aplite Quarry Michael S. Rumsey (2011)
Meldon Mine el-Sharkawi et al. (1961) +4 other references