Marokite (original) (raw)

A valid IMA mineral species

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About MarokiteHide

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Crystal System:

Orthorhombic

Name:

For the first occurrence in Morocco, Maroc in French.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2578:8

73d17d3b-e650-46aa-935f-3e0e49f19f30

IMA Classification of MarokiteHide

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Type description reference:

Classification of MarokiteHide

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4.BC.05

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
B : Metal: Oxygen = 3:4 and similar
C : With medium-sized and large cations

7.2.10.1

7 : MULTIPLE OXIDES
2 : AB2X4

7.4.15

7 : Oxides and Hydroxides
4 : Oxides of Be, Mg and the alkaline earths

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Mro IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MarokiteHide

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Hardness:

VHN100=800 - Vickers

Cleavage:

Perfect
{100} Perfect, {001} Good

Density:

4.64 g/cm3 (Measured) 4.63 g/cm3 (Calculated)

Optical Data of MarokiteHide

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Anisotropism:

Strong: yellowish green to greenish yellow

Bireflectance:

Yellowish gray to gray-brown

Reflectivity:

Wavelength R
400nm 20.2–22.9%
420nm 19.3–21.9%
440nm 18.4–20.9%
460nm 17.7–20.0%
480nm 17.0–19.3%
500nm 16.5–18.7%
520nm 16.2–18.3%
540nm 16.0–18.2%
560nm 16.0–18.4%
580nm 16.0–18.7%
600nm 15.9–18.6%
620nm 15.7–18.3%
640nm 15.5–18.0%
660nm 15.4–17.8%
680nm 15.2–17.5%
700nm 15.1–17.3%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 20.2–22.9%.

Colour in reflected light:

Gray to brown

Internal Reflections:

Dark red, carmine red

Comments:

X = c = safflower-red; Y and Z = opaque (very dark red in very thin sections)

Chemistry of MarokiteHide

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Crystallography of MarokiteHide

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Crystal System:

Orthorhombic

Cell Parameters:

a = 9.71(2) Å, b = 10.03(2) Å, c = 3.162(5) Å

Ratio:

a:b:c = 0.968 : 1 : 0.315

Unit Cell V:

307.95 ų (Calculated from Unit Cell)

Morphology:

Prismatic, flattened on {010}, with {120}, {110}, {201}, and {011}.

Comment:

Point Group: 2/m 2/m 2/m or mm2.; Space Group: Pmab or P21ab.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0012829 Marokite Zouari S, Ranno L, Cheikh-Rouhou A, Isnard O, Pernet M, Wolfers P, Strobel P (2003) New model for the magnetic structure of the marokite-type oxide CaMn2O4 Journal of Alloys and Compounds 353 5-11 2003 synthetic 0 293
0012830 Marokite Zouari S, Ranno L, Cheikh-Rouhou A, Isnard O, Pernet M, Wolfers P, Strobel P (2003) New model for the magnetic structure of the marokite-type oxide CaMn2O4 Journal of Alloys and Compounds 353 5-11 2003 synthetic 0 293
0014005 Marokite Ling C D, Neumeier J J, Argyriou D N (2001) Observation of antiferromagnetism in marokite CaMn2O4 Journal of Solid State Chemistry 160 167-173 2001 synthetic 0 293
0014006 Marokite Ling C D, Neumeier J J, Argyriou D N (2001) Observation of antiferromagnetism in marokite CaMn2O4 Journal of Solid State Chemistry 160 167-173 2001 synthetic 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
2.71 Å (vs)
2.22 Å (vs)
2.29 Å (s)
2.07 Å (s)
2.87 Å (m)
2.56 Å (m)
1.63 Å (m)

Geological EnvironmentHide

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Type Occurrence of MarokiteHide

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General Appearance of Type Material:

Prismatic crystals to 5 cm.

Place of Conservation of Type Material:

Geological Survey, Rabat, Morocco.
National School of Mines, Paris, France.

Geological Setting of Type Material:

Associated Minerals at Type Locality:

Reference:

Gaudefroy, C., Jouravsky, G., Permingeat, F. (1963) La marokite, CaMn2O4 une nouvelle éspèce minérale. Bulletin de la Société française de Minéralogie et de Cristallographie: 86: 359-67.

Synonyms of MarokiteHide

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Other Language Names for MarokiteHide

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Relationship of Marokite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for MarokiteHide

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Reference List:

Zouari, S., Ranno, L., Cheikh-Rouhou, A., Isnard, O., Pernet, M., Wolfers, P., Strobel, P. (2003) New model for the magnetic structure of the marokite-type oxide CaMn2O4. Journal of Alloys and Compounds: 353: 5-11.

Localities for MarokiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Germany
Rhineland-Palatinate Mayen-Koblenz Vordereifel Ettringen Caspar quarry Schäfer (2016)
Vulkaneifel Gerolstein Hohenfels-Essingen Feuerberg Blaß (2020)
India
Odisha Anugul District Mahanadi riverbank Mallick et al. (2005, March)
Morocco (TL)
Drâa-Tafilalet Region Zagora Province Agdz Cercle Tansifte Caïdat Tachgagalt Mine (TL) Gaudefroy et al. (1963)
Russia
Chelyabinsk Oblast Miass Lake Maloye Miassovo Palchik et al. (2014)
South Africa
Northern Cape John Taolo Gaetsewe District Municipality Joe Morolong Local Municipality Black Rock Black Rock Mine de Villiers et al. (1968)
N'Chwaning Mines N'Chwaning II Mine Cairncross et al. (1995)
Wessels Mine Pohl et al. (1991) +1 other reference
Spain
Canary Islands Santa Cruz de Tenerife Province Tenerife Los Blanquitos Dill et al. (2023)
USA
Nevada Mineral County Candelaria Mining District Candelaria Silver Mine Castor et al. (2004)