Metaköttigite (original) (raw)

A valid IMA mineral species

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About MetaköttigiteHide

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Formula:

(Zn,Fe,Fe)3(AsO4)2 · 8(H2O,OH)

Name:

For the relation to köttigite.

Formed by both oxidation and dehydrogenization of ferroan kottigite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2678:5

30837e0a-9b01-4535-868a-e01fa2b0f548

IMA Classification of MetaköttigiteHide

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IMA Formula:

(Zn,Fe3+)3(AsO4)2 · 8(H2O,OH)

Type description reference:

Schmetzer, K., Amthauer, G., Stähle, V., Medenbach, O. (1982) Metaköttigit, (Zn,Fe3+)(Zn,Fe3+,Fe2+)2(AsO4)2·8(H2O,OH), ein neues mineral aus Mapimi, Mexiko. Neues Jahrbuch für Mineralogie - Monatshefte, 1982. 506-518

Classification of MetaköttigiteHide

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8.CE.85

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
E : With only medium-sized cations, RO4:H2O about 1:2.5

40.3.8.2

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
3 : A3(XO4)2·xH2O

20.3.19

20 : Arsenates (also arsenates with phosphate, but without other anions)
3 : Arsenates of Zn, Cd or Hg

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Mköt IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MetaköttigiteHide

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Optical Data of MetaköttigiteHide

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RI values:

_n_α = 1.648(3) _n_β = 1.680(1) _n_γ = 1.716(2)

2V:

Measured: 93° , Calculated: 90°

δ = 0.068

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

X = dark blue, Y = yellow, Z = pale yellow.

Chemistry of MetaköttigiteHide

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Mindat Formula:

(Zn,Fe,Fe)3(AsO4)2 · 8(H2O,OH)

Crystallography of MetaköttigiteHide

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Class (H-M):

1 - Pinacoidal

Cell Parameters:

a = 7.96(2) Å, b = 9.44(2) Å, c = 4.72(1) Å
α = 95.6(2)°, β = 97.0(2)°, γ = 107.8(2)°

Ratio:

a:b:c = 0.843 : 1 : 0.5

Unit Cell V:

331.75 ų (Calculated from Unit Cell)

Twinning:

Universal on {110}.

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.90 Å (40)
6.91 Å (100)
4.99 Å (20)
3.93 Å (30)
3.11 Å (25)
3.00 Å (30)
2.83 Å (25)

Comments:

Very similar to the data of symplesite.

Geological EnvironmentHide

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Type Occurrence of MetaköttigiteHide

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General Appearance of Type Material:

Minute, bluish-gray crystals in oriented intergrowth with kottigite.

Place of Conservation of Type Material:

National Museum of Natural History, Washington, D.C., USA, 160541.

Geological Setting of Type Material:

Oxide zone of an arsenic-rich polymetallic mineral deposit.

Associated Minerals at Type Locality:

Reference:

Schmetzer, K., Amthauer, G., Stähle, V., Medenbach, O. (1982) Metaköttigit, (Zn,Fe3+)(Zn,Fe3+,Fe2+)2(AsO4)2·8(H2O,OH), ein neues mineral aus Mapimi, Mexiko. Neues Jahrbuch für Mineralogie, Monatshefte: 1982: 506-518.

Synonyms of MetaköttigiteHide

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Other Language Names for MetaköttigiteHide

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Relationship of Metaköttigite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for MetaköttigiteHide

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Reference List:

Schmetzer, K., Amthauer, G., Stähle, V., Medenbach, O. (1982) Metaköttigit, (Zn,Fe3+)(Zn,Fe3+,Fe2+)2(AsO4)2·8(H2O,OH), ein neues mineral aus Mapimi, Mexiko. Neues Jahrbuch für Mineralogie - Monatshefte, 1982. 506-518

Localities for MetaköttigiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Mexico (TL)
Durango Mapimí Municipality Mapimí Ojuela Mine (TL) Schmetzer et al. (1982) +1 other reference