Neptunite (original) (raw)

A valid IMA mineral species - grandfathered

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About NeptuniteHide

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Formula:

KNa2Li(Fe2+)2Ti2[Si4O12]2

Specific Gravity:

3.19 - 3.23

Crystal System:

Monoclinic

Name:

For Neptune, Roman god of the sea, for close association at type locality with aegirine (named after Aegir, a Scandinavian sea god).

The Fe(II) analogue of manganoneptunite.
Minor rock forming mineral. Probably best know as an associated mineral with benitoite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2883:3

23c829e5-ba32-4149-9b99-57692bef1ce8

IMA Classification of NeptuniteHide

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Approved, 'Grandfathered' (first described prior to 1959)

IMA Formula:

KNa2LiFe2+2Ti2Si8O24

Type description reference:

Classification of NeptuniteHide

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9.EH.05

9 : SILICATES (Germanates)
E : Phyllosilicates
H : Transitional structures between phyllosilicate and other silicate units

70.4.1.1

70 : INOSILICATES Column or Tube Structures
4 : Column or Tube Structures with linked chains forming cages

14.9.26

14 : Silicates not Containing Aluminum
9 : Silicates of Ti

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Npt IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of NeptuniteHide

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Comment:

Deep blood-red in splinters

Density:

3.19 - 3.23 g/cm3 (Measured) 3.24 g/cm3 (Calculated)

Optical Data of NeptuniteHide

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RI values:

_n_α = 1.690 - 1.691 _n_β = 1.693 - 1.700 _n_γ = 1.719 - 1.736

2V:

Measured: 36° to 49°, Calculated: 36° to 56°

δ = 0.029 - 0.045

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

X= pale yellow
Y= yellow-orange
Z= red-orange to red-brown

Chemistry of NeptuniteHide

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Mindat Formula:

KNa2Li(Fe2+)2Ti2[Si4O12]2

Chemical AnalysisHide

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Sample references:

ID Type Locality Reference Notes
1 Type Specimen Narssârssuk pegmatite, Narsaarsuk Plateau, Igaliku, Kujalleq, Greenland Flink, Gust. (1893) Om några mineral från Grönland. Geologiska Föreningen i Stockholm Förhandlingar, 15 (4) 195-208 doi:10.1080/11035899309442185 Wet-chemical analysis (Flink), analysis incomplete, Li not analyzed
2 California State Gem Mine, Santa Rita Peak, San Benito County, California, USA Laird, Jo, Albee, Arden L. (1972) Chemical composition and physical, optical, and structural properties of benitoite, neptunite, and joaquinite. American Mineralogist, 57 (1-2) 85-102 Microprobe

Crystallography of NeptuniteHide

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Crystal System:

Monoclinic

Cell Parameters:

a = 16.427(2) Å, b = 12.478(2) Å, c = 9.975(1) Å
β = 115.56(1)°

Ratio:

a:b:c = 1.316 : 1 : 0.799

Unit Cell V:

1,844.54 ų (Calculated from Unit Cell)

Morphology:

Prismatic crystals

Twinning:

Interpenetrant on {301}

Crystallographic forms of NeptuniteHide

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Crystal Atlas:

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3d models and HTML5 code kindly provided bywww.smorf.nl.

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Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0018847 Neptunite Cannillo E, Mazzi F, Rossi G (1966) The crystal structure of neptunite Acta Crystallographica 21 200-208 1966 San Benito, California, USA 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.186 Å (100)
9.6 Å (60)
3.517 Å (45)
3.308 Å (35)
2.942 Å (32)
2.837 Å (32)
2.480 Å (32)

Geological EnvironmentHide

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Geological Setting:

alkaline rocks

Type Occurrence of NeptuniteHide

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General Appearance of Type Material:

Crystals from mm-sized up to 3-4 cm large, on aegirine or embedded in feldspar

Place of Conservation of Type Material:

University of Copenhagen, Copenhagen, Denmark.

Associated Minerals at Type Locality:

Reference:

Flink, G. (1893): Om några mineral från Grönland. Geologiska Föreningen i Stockholms Förhandlingar. 15, 195-208

Synonyms of NeptuniteHide

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Other Language Names for NeptuniteHide

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Simplified Chinese:柱星叶石

Traditional Chinese:柱星葉石

Relationship of Neptunite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.EH.05 Manganoneptunite KNa2Li(Mn2+)2Ti2[Si4O12]2 Mon. m : B b
9.EH.05 Watatsumiite KNa2Li(Mn2+)2V4+2[Si4O12]2 Mon. m : B b
9.EH.05 Magnesioneptunite KNa2Li(Mg)2Ti2[Si4O12]2 Mon. 2/m : _B_2/b
9.EH.05 Rotherkopfite KNa2Fe2+(Fe2+)2(Ti1.5Fe2+0.5)[Si4O12]2 Mon. 2/m : _B_2/b
9.EH.10 Grumantite Na(HSi2O5) · H2O Orth. m _m_2 : F d _d_2
9.EH.15 Sarcolite Na4Ca12Al8Si12O46(SiO4,PO4)(OH,H2O)4(CO3,Cl) Tet. 4/m : _I_4/m
9.EH.20 Ussingite Na2AlSi3O8OH Tric. 1 : _P_1
9.EH.25 Leifite (Na,H2O)Na6[Be2Al2(Al,Si)Si15O39]F2 Trig. 3_m_ : _P_3_m_1
9.EH.25 Telyushenkoite (Cs,Na,K)Na6[Be2Al3Si15O39]F2 Trig. 3_m_ _(_32/m ) : P_31_m
9.EH.25 Eirikite KNa6Be2(Si15Al3)O39F2 Trig. 3_m_ _(_32/m ) : _P_3_m_1
9.EH.30 Nafertisite Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2 Mon. 2/m
9.EH.35 Veblenite KNa(Fe2+5Fe3+4Mn7)Nb4(Si2O7)2(Si8O22)2O6(OH)10(H2O)3 Tric. 1 : _P_1

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for NeptuniteHide

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Reference List:

Kunz, M., Armbruster, T., Lager, G.A., Schulz, A.J., Goyette, R.J., Lottermoses, W., Amthauer, G. (1991) Fe, Ti ordering and octahedral distortions in acentric neptunite: Temperature dependent X-ray and neutron structure refinements and Mossbauer spectroscopy. Physics and Chemistry of Minerals: 18: 199-213.

Localities for NeptuniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia
New South Wales Darling Co. Barraba Woodsreef Mine (Wood's Reef Mine; Woodsreef Asbestos Mine; Wood'sreef asbestos deposit) Slansky et al. (1981) +1 other reference
Brazil
Minas Gerais Poços de Caldas Bortolan quarry Atencio et al. (1999)
Poços de Caldas alkaline complex Azzi (2019) +1 other reference
Paraná Tijucas do Sul Morro Redondo complex Papanduva pluton Vilalva et al. (2010)
Santa Catarina Lages G Traversa et al (1994)
Canada
Newfoundland and Labrador Labrador Red Wine Alkaline Complex Curtis et al. (1977)
Seal Lake alkaline complex (Letitia Lake) Heinrich et al. (1963) +1 other reference
Mann 1 (Letitia Lake) GSC database locality No. 4100 +1 other reference
Mann 2 (Ten Mile Lake) GSC database +2 other references
Québec Montérégie La Vallée-du-Richelieu RCM Mont Saint-Hilaire Poudrette quarry (De-Mix quarry; Demix quarry; Uni-Mix quarry; Carrière Mont Saint-Hilaire; MSH) Horváth et al. (2019)
Germany
Baden-Württemberg Freiburg Region Breisgau-Hochschwarzwald Bötzingen Fohberg Quarry (Hauri Quarry) Uwe Kolitsch (SXRD- and EDS-analysis on material collected by Bernd Gassmann, to be published)
Greenland (TL)
Kujalleq Igaliku Narsaarsuk Plateau Narssârssuk pegmatite (TL) Flink (1893) +1 other reference
Ilímaussaq complex Petersen (2001) +1 other reference
Kangerluarsuk Fjord Head of Kangerluarsuk Lilleelv Lilleelv pegmatite Danø et al. (1959)
Qeqertaussaq Island South Coast Pegmatite Soerensen (1962)
Kuannersuit Plateau (Kvanefjeld) Friis et al. (2004)
Rohaite occurrence Petersen et al. (2005)
Slope between Kvanefjeld Mt and Steenstrups Mt Metcalf-Johansen (1977)
Tugtupite-bearing albitites Petersen et al. (2002)
Mount Nakkaalaaq Semenov E I et al. (1965)
Taseq Slope found by Frank de Wit 2008
Tunulliarfik Fjord Igdlunguaq Bøggild (1953) +2 other references
Tugtup Agtakôrfia Bøggild (1953)
Tuperssuatsiat Bay Bøggild (1953)
Hungary
Baranya County Pécs District Hosszúhetény Köves Hill collector: Csaba Papp
Phonolite quarry www.geomania.hu
Ireland
Leinster Louth County Carlingford Barnavave Nockolds et al. (1947) +1 other reference
Libya
Jabal al Gharbi District Gharyan Volcanic Field Kaf El Khalef Lustrino et al. (2012)
Mongolia
Khovd Province Myangad District Khaldzan Buragtag massif Khalzan Buregte Zr–Nb–REE deposit Kempe et al. (1999) +2 other references
Ömnögovi Province Khanbogd District Khan Bogd Peralkaline Granite J Kynický et al. (2009)
Dorozhnyi pegmatite Jindrich Kynicky
Namibia
Khomas Region Windhoek Rural Aris Aris Quarries Blass et al. (2014) +2 other references
Russia
Buryatia Mama River Basin Maigunda River Burpala alkaline massif Bailey +1 other reference
Kabardino-Balkaria Chegemsky District Upper Chegem volcanic caldera (Verkhnechegemskaya caldera) Lakargi Mountain Xenolith no. 5 Zadov et al. (2011)
Murmansk Oblast Khibiny Massif Koashva Mt PEKOV et al. (2013)
Kukisvumchorr Mt
Takhtarvumchorr Mt
Lovozersky District Alluaiv Mountain Pekov (1998) +1 other reference
Apuaiv Mountain Sorokhtina N.V. et al. (2004)
Karnasurt Mountain Pekov (1998)
Kitknyun Mountain
Kuftnyun Mountain
Mannepakhk Mountain
Seidozero Lake Lepkhe-Nel'm Mt Pekov (2003)
Pegmatite No. 45 Pavel.M. Kartashov (n.d.) +1 other reference
Niva alkaline intrusion Arzamastseva et al. (1999) +1 other reference
Sakha Aldan Inagli Massif Inagli chrome diopside deposit N.V. Chukanov et al.: Zap. Vses. Mineral. Obshch. 133 (1)
Slovakia
Banská Bystrica Region Lučenec District Bulhary Huraiová et al. (2017)
Spain
Canary Islands Santa Cruz de Tenerife Province Tenerife Alcala Dill et al. (2023)
Candelaria Barranco Hondo Lava flow Dill et al. (2023)
La Mareta Dill et al. (2023)
Tajikistan
Districts of Republican Subordination Dara-i-Pioz Massif Agakhanov et al. (2024) +4 other references
USA
California San Benito County Picacho Peak Mina Numero Uno www.mineralsocal.org +2 other references
Victor claim (Victor Mine) Joseph F. Cooper Jr. et al. (2003) +1 other reference
Santa Rita Peak California State Gem Mine Louderback (1907) +8 other references
Clear Creek area benitoite occurrence Van Nostrand Reinholt Press: 467. +1 other reference
Junnila Mine (Junnila claim) www.benitoitemine.com +1 other reference
Montana Meagher County Gordon Butte Chakhmouradian et al. (2002)
New Mexico Colfax County Springer Point of Rocks Mesa (Pecks Mesa) Point of Rocks Quarry Rocks & Min.:60:229.
North Carolina Alexander County Hiddenite Collected & identified by Michael ...