Parabutlerite (original) (raw)

A valid IMA mineral species - grandfathered

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About ParabutleriteHide

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Formula:

Fe3+(SO4)(OH) · 2H2O

Colour:

Pale orange to pale orange-brown; light yellow in transmitted light.

Crystal System:

Orthorhombic

Name:

Named in 1938 by Mark Chance Bandy for its resemblance to Butlerite.

This page provides mineralogical data about Parabutlerite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:3081:2

f8b044a0-ecea-453d-940d-66d9307aab0b

IMA Classification of ParabutleriteHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of ParabutleriteHide

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7.DC.10

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
C : With only medium-sized cations; chains of edge-sharing octahedra

31.9.2.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
9 : (AB)(XO4)Zq·xH2O

25.10.16

25 : Sulphates
10 : Sulphates of Fe alone

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Pbtl IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ParabutleriteHide

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Colour:

Pale orange to pale orange-brown; light yellow in transmitted light.

Cleavage:

Poor/Indistinct
On {110}, poor.

Density:

2.55 g/cm3 (Measured)

Optical Data of ParabutleriteHide

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RI values:

_n_α = 1.598 _n_β = 1.663 _n_γ = 1.737

2V:

Measured: 87° , Calculated: 90°

δ = 0.139

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

Alcaparrosa material:
X = b = Light yellow
Y = c = Greenish yellow
Z = a = Brownish yellow

Argentinian material:
X = b = Colourless
Y = c = Faint yellow
Z = a = Light yellow

Comments:

NOTE: 2V value for Argentinian material = 43°30'.

Chemistry of ParabutleriteHide

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Mindat Formula:

Fe3+(SO4)(OH) · 2H2O

Crystallography of ParabutleriteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 20.0789(8) Å, b = 7.4024(7) Å, c = 7.2294(15) Å

Ratio:

a:b:c = 2.712 : 1 : 0.977

Unit Cell V:

1,074.52 ų (Calculated from Unit Cell)

Morphology:

Crystals prismatic [001]. The prism zone is striated [001].

Comment:

Space group Pnma(0β0)​s0s; the structure is commensurately modulated, with a = 20.0789 (8), b = 7.4024 (7), c = 7.2294 (15) Å and q = 0.4b* (Plášil et al., 2017).

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0012131 Parabutlerite Borene J (1970) Structure cristalline de la parabutlerite Bulletin de la Societe Francaise de Mineralogie et de Cristallographie 93 185-189 1970 0 293

CIF Raw Data - click here to close

Epitaxial Relationships of ParabutleriteHide

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Epitaxy Comments:

Intergrowths, with {011} of parabutlerite nearly parallel to {001} and {100} of butlerite.

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
4.99 Å (very very strong)
3.11 Å (very very strong)
5.83 Å (strong)
3.60 Å (moderately strong)
2.499 Å (moderately strong)
4.07 Å (moderate)

Comments:

Alcaparrosa, Chile. The data are from Cesbron

Geological EnvironmentHide

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Type Occurrence of ParabutleriteHide

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Reference:

Bandy, M.C. (1938) Mineralogy of three sulphate deposits of Northern Chile. American Mineralogist: 23: 669-760 (742-745).

Other Language Names for ParabutleriteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Other InformationHide

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Notes:

Insoluble in cold or hot water; soluble in dilute acids.

Observed as pseudomorphs after copiapite.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for ParabutleriteHide

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Reference List:

**Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.**pp.610-611

Localities for ParabutleriteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Argentina
San Juan Province Calingasta Department Calingasta Quebrada Alcaparrosa Santa Elena Mine Palache et al. (1951)
Atlantic Ocean
Mid-Atlantic Ridge complex Pobeda-1 hydrothermal field Gablina et al. (2018)
Canada
Newfoundland and Labrador Newfoundland Baie Verte Peninsula Tilt Cove Tilt Cove Slag Locality Norman Wilson collection
Chile
Antofagasta Antofagasta Province Mejillones Mejillones peninsula Barranca del Sulfato XRD by Joachim Lorenz
Coronel Manuel Rodríguez mine SEM-EDS and XRD by Igor V. Pekov
Unnamed Cu mine [1] XRD by Joachim Lorenz
Sierra Gorda Alcaparrosa Mine (TL) Kampf +6 other references
El Loa Province Calama Chuquicamata District Chuquicamata Mine (TL) Bandy (1938) +1 other reference
Toki Cu deposit (Toki Cluster) Queténa Mine (Queténa Prospect) Palache et al. (1951)
Atacama Copiapó Province Tierra Amarilla
Tarapacá Tamarugal Province Cerros Pintados Peter G. Seroka collection
China
Xinjiang Hami Prefecture (Kumul Prefecture; Qumul Prefecture) Yizhou District Hongshan Au-Cu deposit Xu Ying-xia et al. (2006)
Cyprus
Nicosia District Mitsero Agrokipia mine ...
Greece
Attica East Attica Lavreotiki Lavrion Mining District Km 3 Kaminiza mines Esperanza Mine Fritz Schreiber collection
Sounion Cato Sounio mines Sounion Sulfate Locality Rieck et al. (2018)
Hungary
Fejér County Székesfehérvár District Gánt ACTA MIN. PETR. Suppl. Tomus XXXVIII.
Veszprém County Ajka District Nyirád Nyirád Mine ACTA MIN. PETR. Suppl. Tomus XXXVIII.
Iran
Yazd Province Ardakan County Kharanaq District Rabatat Rural District Saghand Kavir-e-Sagand Bariand et al. (1973) +1 other reference
Spain
Andalusia Huelva Minas de Riotinto Rio Tinto Mines Garcia (1996)
USA
California Inyo County Coso Hot Springs Coso Hot Springs deposit Coso Mine (Devil's Kitchen; Atlas; Lynch & Lynch; Nicol; Walley-Mickey & Wheeler) www.mineralsocal.org
New Mexico Santa Fe County La Bajada Mining District Northrop et al. (1996)
Lone Star Mine (La Bajada Mine) Northrop et al. (1996)
Utah Emery County Calf Mesa Mining District Dexter group Bullock (1981)
Dexter No. 7 Mine Rosenzweig et al. (1955)
Mars
Aeolis quadrangle Gusev Crater Columbia Hills Husband Hill Cumberland Ridge Paso Robles site ? Lane et al. (2008)