Smithite (original) (raw)

A valid IMA mineral species - grandfathered

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About SmithiteHide

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Colour:

Pale red; red-orange or brownish orange on exposure to light

Crystal System:

Monoclinic

Name:

Named in honor of George Frederick Herbert Smith (26 May 1872, Edgbaston, England, UK - 20 April 1953), crystallographer and curator, British Museum of Natural History, London (England). The mineral herbertsmithite is also named after him.

This page provides mineralogical data about Smithite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:3687:6

cb4f00f2-84cd-4298-b286-fc4402f28102

IMA Classification of SmithiteHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of SmithiteHide

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2.GC.30

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
C : Poly-sulfarsenites

3.7.3.1

3 : SULFOSALTS
7 : ø = 2

5.2.1

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
2 : Sulpharsenites etc. of Ag

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Sth IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of SmithiteHide

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Colour:

Pale red; red-orange or brownish orange on exposure to light

Cleavage:

Perfect
{100} perfect

Density:

4.88 g/cm3 (Measured) 4.926 g/cm3 (Calculated)

Optical Data of SmithiteHide

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Dispersion:

marked to extreme

Optical Extinction:

Y = b; Z ∧ c = 6.5°.

Reflectivity:

Wavelength R1 R2
400nm 40.7% 44.0%
420nm 40.0% 43.2%
440nm 39.3% 42.4%
460nm 38.7% 41.5%
480nm 37.9% 40.4%
500nm 37.0% 39.2%
520nm 36.0% 38.0%
540nm 35.0% 36.6%
560nm 33.8% 35.4%
580nm 32.7% 34.7%
600nm 32.0% 34.0%
620nm 31.4% 33.4%
640nm 31.0% 32.9%
660nm 30.6% 32.4%
680nm 30.4% 31.8%
700nm 30.1% 31.4%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 44.0%.
R1 shown in black, R2 shown in red

Comments:

Slight in transmitted light.

Chemistry of SmithiteHide

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Crystallography of SmithiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 17.23 Å, b = 7.78 Å, c = 15.19 Å
β = 101.2°

Ratio:

a:b:c = 2.215 : 1 : 1.952

Unit Cell V:

1,997.43 ų (Calculated from Unit Cell)

Morphology:

Equant; tabular {100}. Tabular crystals appear hexagonal due to strong zonal developments nearly 60° apart.

Comment:

Space Group: A2/a.

Crystallographic forms of SmithiteHide

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Crystal Atlas:

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3d models and HTML5 code kindly provided bywww.smorf.nl.

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Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0014690 Smithite Hellner E, Burzlaff H (1964) Die struktur des smithits AgAsS2 Naturwissenschaften 51 35-36 1964 Lengenbach quarry, Binnatal, Switzerland 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
2.82 Å (100)
3.21 Å (80)
2.72 Å (60)
1.953 Å (50)
1.701 Å (40)
1.661 Å (40)
1.608 Å (40)

Geological EnvironmentHide

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Type Occurrence of SmithiteHide

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Place of Conservation of Type Material:

Associated Minerals at Type Locality:

Reference:

Solly, R.H. (1905) Some new minerals from the Binnenthal, Switzerland. Mineralogical Magazine: 14: 72-82.

Synonyms of SmithiteHide

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Other Language Names for SmithiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Other InformationHide

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Special Storage/
Display Requirements:

becoming opaque on exposure to light

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for SmithiteHide

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Localities for SmithiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Chile
Atacama Copiapó Province Tierra Amarilla Pampa Larga mining district Alacrán Alacrán Mine Maurizio Dini
France
Provence-Alpes-Côte d'Azur Hautes-Alpes Gap La Chapelle-en-Valgaudemar Jas Roux Nakai et al. (1983) +1 other reference
Germany
Baden-Württemberg Karlsruhe Region Rhein-Neckar-Kreis Wiesloch Segen Gottes Mine Weiß (1990)
Hesse Darmstadt Darmstadt-Dieburg Mühltal Nieder-Beerbach Glasberg quarry Weiß (1990)
Iran
West Azerbaijan Province Sardasht County Sardasht Barika ore deposit Topa et al. (2013)
Ireland
Munster Tipperary County Silvermines District Mogul Mine (Garryard Mine; International Mogul Mines) Gasparrini (1978) +4 other references
Japan
Tochigi Prefecture Nikko City Kuriyamamura Nishizawa mine Shimizu et al. (2007)
Peru
Lima Oyón Province Oyón District Uchucchacua Mine EDS Analysis Frank Keutsch
Poland
Podlaskie Voivodeship Suwałki County Suwałki Massif Krzemianka Kucha H. 1982: Haycockite and ...
Spain
Andalusia Almería Cuevas del Almanzora Las Herrerías Las Herrerías Mines Navarro et al. (2009)
Switzerland (TL)
Valais Goms Binn Fäld Lengenbach Quarry (TL) Solly (1905) +1 other reference
Reckibach 50. (in German) +2 other references