Twinnite (original) (raw)

A valid IMA mineral species

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About TwinniteHide

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Formula:

Pb0.8Tl0.1Sb1.3As0.8S4

Specific Gravity:

5.323 (Calculated)

Crystal System:

Monoclinic

Name:

Named by John L. Jambor in 1967 in honor of Robert Mitchell Thompson (28 July 1918, Moose Jaw, Saskatchewan, Canada - 15 April 1967), professor of mineralogy, University of British Columbia, Vancouver, Canada. He had a special interest in ore minerals and deposits. Thompson means "son of Thomas"; the latter is Aramaic for "a twin". The name is doubly appropriate in alluding to the polysynthetic twinning present in the mineral.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:4067:5

462a0cd5-125a-40d9-b22d-2a37cc61393e

IMA Classification of TwinniteHide

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IMA Formula:

Pb(Sb0.63As0.37)2S4

Type description reference:

Classification of TwinniteHide

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2.HC.05a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
C : With only Pb

3.7.8.3

3 : SULFOSALTS
7 : ø = 2

5.6.19

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
6 : Sulpharsenites etc. of Pb alone

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Twi IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TwinniteHide

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Hardness:

VHN50=131 - 152 kg/mm2 - Vickers

Density:

5.323 g/cm3 (Calculated)

Optical Data of TwinniteHide

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Reflectivity:

Wavelength R1 R2
400nm 39.1% 45.2%
420nm 38.2% 44.7%
440nm 37.3% 44.2%
460nm 36.6% 43.7%
480nm 36.2% 43.2%
500nm 35.8% 42.9%
520nm 35.5% 42.5%
540nm 35.0% 42.0%
560nm 34.4% 41.4%
580nm 34.0% 40.8%
600nm 33.5% 40.0%
620nm 33.2% 39.4%
640nm 32.8% 38.7%
660nm 32.3% 38.1%
680nm 31.7% 37.5%
700nm 31.0% 37.0%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 45.2%.
R1 shown in black, R2 shown in red

Colour in reflected light:

white

Comments:

displays twin lamellae

Chemistry of TwinniteHide

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Mindat Formula:

Pb0.8Tl0.1Sb1.3As0.8S4

Simplified Pb(Sb,As)2S4.

Crystallography of TwinniteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 7.997(2) Å, b = 19.517(5) Å, c = 8.634(2) Å
β = 91.061(4)°

Ratio:

a:b:c = 0.41 : 1 : 0.442

Unit Cell V:

1,347.34 ų (Calculated from Unit Cell)

Twinning:

Polysynthetic, with composition plane parallel to {100}.

Comment:

Space group P21/n. Originally assumed to be triclinic, with the cell parameters 19.58, 7.98, 8.56 A, 89.77, 89.62 and 90.27°.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0019818 Twinnite Makovicky E, Topa D (2012) Twinnite, Pb0.8Tl0.1Sb1.3As0.8S4, the OD character and the question of its polytypism Zeitschrift fur Kristallographie 227 468-475 2012 Jas Roux, France 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.51 Å (100)
2.344 Å (80)
2.78 Å (70)
4.18 Å (50)
3.91 Å (50)
2.689 Å (50)
2.645 Å (50)

Geological EnvironmentHide

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Type Occurrence of TwinniteHide

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General Appearance of Type Material:

Two megascopic grains, the larger about 1.5 mm in diameter, and four microscopic grains.

Place of Conservation of Type Material:

Canadian Geological Survey, Ottawa, Canada, 12175.
Canadian Museum of Nature, Ottawa, Canada.

Reference:

Jambor, J.L. (1967) New lead sulfantimonides from Madoc, Ontario. 2. Mineral descriptions. The Canadian Mineralogist: 9: 191-213.

Synonyms of TwinniteHide

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Other Language Names for TwinniteHide

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Relationship of Twinnite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Other InformationHide

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Notes:

KOH rapidly tarnishes twinnite iridescent and leaves a characteristic flat brownish grey colour when the reagent is rubbed off. 1:1 HNO3, rapidly tarnishes the mineral black. Other reagents test negative.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for TwinniteHide

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Reference List:

Makovicky, E., Topa, D., Tajjedin, H., Rastad, E., Yaghubpur, A. (2012) The crystal structure of guettardite, PbAsSbS4, and the twinnite-guettardite problem. The Canadian Mineralogist, 50 (2) 253-265 doi:10.3749/canmin.50.2.253

Localities for TwinniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Armenia
Syunik Province Sisian Mardzhan deposit Kukulyan (1987)
Australia
Western Australia Laverton Shire Mount Weld Station Sunrise Dam Gold Mine (Sunrise pit; Cleo pit) Brown et al. (2003)
Bolivia
Oruro Cercado Province Oruro San José Mine Sidki Rius (2017)
Bosnia and Herzegovina
Republika Srpska Srebrenica Čumavići deposit Slobodan A. Radosavljević et al. (2016)
Canada
British Columbia Omineca Mining Division Stardust deposit BC Minfile data +1 other reference
Ontario Hastings County Centre Hastings Municipality Huntingdon Township Taylor Pit (TL) Jambor (1967) +3 other references
Thunder Bay District Bomby Township Hemlo gold deposit Harris et al. (1988) +1 other reference
David Bell Mine Sabina (1991)
Québec Mauricie Mékinac RCM Montauban deposit Mineral. Deposita 42 (2007)
Chile
Atacama Chañaral Province Potrerillos Jerónimo Mine ? Thompson et al. (2004)
China
Gansu Gannan Hezuo Co. Dewulu Au-Cu ore field Laodoucun Au deposit Guo et al. (2023)
Guangxi Hechi Jinchengjiang District Beixiang - Furongchang ore field Sanpaidong Pb-Zn-Sb deposit Jing et al. (2018)
France
Provence-Alpes-Côte d'Azur Hautes-Alpes Gap La Chapelle-en-Valgaudemar Jas Roux Johan et al. (2000) +1 other reference
India
Rajasthan Udaipur Division Udaipur District Rajpura-Dariba deposit Chaudhuri et al. (1980) +1 other reference
Iran
West Azerbaijan Province Sardasht County Sardasht Barika ore deposit Yar Mohammadi et al. (2008)
Takab County Agh-Darreh Mine Daliran (2008)
Zareh Shuran Mine Asadi +3 other references
Italy
Piedmont Metropolitan City of Turin Ceresole Reale Chiapili di sotto Maletto et al. (2013)
Kyrgyzstan
Batken Region Kadamjay District Chauvai (Chauvay) Sb-Hg Deposit Kolesar et al. (1993)
Khaidarkan Sb-Hg deposit Kolesar et al. (1993)
Mexico
Mexico Temascaltepec Municipality Temascaltepec de González (Temascaltepec) La Guitarra mine (La Guitarra deposit) Camprubi
Poland
Lower Silesian Voivodeship Ząbkowice Śląskie County Gmina Bardo Dębowina Reiche Silber Glück adit Nejbert et al. (2014)
Romania
Maramureș County Baia Mare Herja Mine ? Cook et al. (1997) +1 other reference
Russia
Sverdlovsk Oblast Serovsky District Turya river Tur'insk Vorontsovskoe deposit (Vorontsovsk gold deposit; Vorontsovka deposit) Kasatkin et al. (2020)
Serbia
Boranja orefield Slobodan A. Radosavljević et al. (2013) +1 other reference
Krupanj Rujevac Sb-Zn-Pb Deposit Moelo +8 other references
Spain
Andalusia Almería Pechina Baños de Alhamilla Mina Casualidad Rewitzer et al. (4)
Sweden
Västmanland County Sala Municipality Sala Sala Silver Mine Holmgren (2002)
USA
Nevada Mineral County Gabbs Valley Range Santa Fe District Santa Fe Mine (Homestake-Santa Fe mine) - (2005)