Afghanite (original) (raw)
A valid IMA mineral species
About AfghaniteHide
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Formula:
(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6
Colour:
White, light blue, dark blue
Name:
Named after the country of its discovery, Afghanistan.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:41:9
6f9e1a00-d7ad-4dfc-a023-919dec36009c
IMA Classification of AfghaniteHide
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IMA Formula:
(Na,K)22Ca10(Si24Al24)O96(SO4)6Cl6
Type description reference:
Classification of AfghaniteHide
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9.FB.05
9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.5.1
76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
17.10.12
17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Afg | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of AfghaniteHide
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Colour:
White, light blue, dark blue
Comment:
Colourless in thin section
Density:
2.55 g/cm3 (Measured) 2.65 g/cm3 (Calculated)
Optical Data of AfghaniteHide
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RI values:
_n_ω = 1.523 _n_ε = 1.529
δ = 0.006
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Chemistry of AfghaniteHide
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Mindat Formula:
(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6
Crystallography of AfghaniteHide
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Class (H-M):
3_m_ - Ditrigonal Pyramidal
Cell Parameters:
a = 12.8013(7) Å, c = 21.4119(18) Å
Unit Cell V:
3,038.74 ų (Calculated from Unit Cell)
Morphology:
As stout to slender, thin tabular laths and as rounded grains.
Comment:
Cell data from Ballirano et al. (1996). Previously assumed space group P63mc is incorrect.
Crystal StructureHide
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ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0018843 | Afghanite | Ballirano P, Bosi F (2012) Thermal behavior of afghanite, an ABABACAC member of the cancrinite group American Mineralogist 97 630-640 | 2012 | Case Collina, Latium, Italy | 0 | 293 | |
0006636 | Afghanite | Ballirano P, Bonaccorsi E, Maras A, Merlino S (1997) Crystal structure of afghanite, the eight-layer member of the cancrinite-group: evidence for long-range Si,Al ordering European Journal of Mineralogy 9 21-30 | 1997 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.688 Å | (100) |
3.298 Å | (100) |
4.82 Å | (80) |
3.997 Å | (60) |
2.865 Å | (60) |
2.130 Å | (60) |
1.792 Å | (60) |
Geological EnvironmentHide
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Geological Setting:
In silicified limestone xenoliths in pumice (Pitigliano quarry, Italy).
Type Occurrence of AfghaniteHide
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General Appearance of Type Material:
In thin veinlets cutting lazurite crystals.
Place of Conservation of Type Material:
Mineralogy-Crystallography Laboratory, University Pierre and Marie Curie, Paris;
National School of Mines, Paris, France;
The Natural History Museum, London, England, 1969,72.
Associated Minerals at Type Locality:
Reference:
Bariand,P., Cesbron, F., Giraud, R. (1968) Une nouvelle espèce minérale: l'afghanite de Sar-e-sang, Badakhshan, Afghanistan. Comparaison avec les minéraux du groupe de la cancrinite. Bulletin de la Société Francaise de Minéralogie et Christallographie: 91: 34-42.
Synonyms of AfghaniteHide
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Other Language Names for AfghaniteHide
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Relationship of Afghanite to other SpeciesHide
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Other Members of this group:
Alloriite | (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 | Trig. 3_m_ : P_31_c |
---|---|---|
Balliranoite | (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) | Hex. 6 : _P_63 |
Betzite | Na6Ca2(Al6Si6O24)Cl4 | Hex. 6 : _P_63 |
Biachellaite | (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O | Trig. 3 : _P_3 |
Bystrite | (Na,K)7Ca(Al6Si6O24)(S5)Cl | Trig. 3_m_ : P_31_c |
Cancrinite | (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O | Hex. 6 : _P_63 |
Cancrisilite | Na7(Al5Si7O24)(CO3) · 3H2O | Hex. 6_m_ m : P_63_m c |
Carbobystrite | Na8(Al6Si6O24)(CO3) · 3.5H2O | Trig. 3_m_ : P_31_c |
Davyne | (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 | Hex. 6/m : _P_63/m |
Depmeierite | Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) | Hex. 6 : _P_63 |
Fantappièite | [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O | Trig. 3 : _R_3 |
Farneseite | (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O | Hex. 6/m : _P_63/m |
Franzinite | (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O | Hex. |
Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 | Trig. 3_m_ : P_31_c |
Hydroxycancrinite | Na8(Al6Si6O24)(OH)2 · 2H2O | Hex. 6 : _P_63 |
Kircherite | Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O | Trig. 32 : _R_32 |
Kyanoxalite | Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5) | Hex. 6 : _P_63 |
Liottite | (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 | Hex. 6 : _P_6 |
Marinellite | (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O | Trig. 3_m_ : P_31_c |
Microsommite | Na4K2Ca2(Al6Si6O24)(SO4)Cl2 | Hex. 622 : _P_6322 |
Pitiglianoite | Na6K2(Al6Si6O24)(SO4) · 2H2O | Hex. 6 : _P_63 |
Quadridavyne | (Na,K)6Ca2(Al6Si6O24)Cl4 | Hex. 6/m : _P_63/m |
Sacrofanite | (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O | Hex. |
Steudelite | Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O | Hex. 6_m_2 : P_62_c |
Sulfhydrylbystrite | Na5K2Ca[Al6Si6O24](S5)2(SH) | Trig. 3_m_ : P_31_c |
Tounkite | (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O | Hex. 622 : _P_6222 |
UM2004-48-SiO:AlClCaNaS | (Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3 | |
UM2009-23-SiO:AlCCaClHKNaS | (Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2O | Trig. 3 : _P_3 |
Vishnevite | (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O | Hex. 6 : _P_63 |
Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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9.FB. | Steudelite | Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O | Hex. 6_m_2 : P_62_c |
---|---|---|---|
9.FB. | Sapozhnikovite | Na8(Al6Si6O24)(HS)2 | Iso. 43_m_ : P_43_n |
9.FB. | Betzite | Na6Ca2(Al6Si6O24)Cl4 | Hex. 6 : _P_63 |
9.FB. | Slyudyankaite | Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O | Tric. 1 : _P_1 |
9.FB. | Bolotinaite | (Na7◻)(Al6Si6O24)F · 4H2O | Iso. 43_m_ : I_43_m |
9.FB. | Wenlanzhangite-(Y) | Y2V3+2V4+2(SiO4)2O4(OH)4 | Tric. 1 : _P_1 |
9.FB.05 | Bystrite | (Na,K)7Ca(Al6Si6O24)(S5)Cl | Trig. 3_m_ : P_31_c |
9.FB.05 | Cancrinite | (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Cancrisilite | Na7(Al5Si7O24)(CO3) · 3H2O | Hex. 6_m_ m : P_63_m c |
9.FB.05 | Davyne | (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 | Hex. 6/m : _P_63/m |
9.FB.05 | Franzinite | (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O | Hex. |
9.FB.05 | Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 | Trig. 3_m_ : P_31_c |
9.FB.05 | Hydroxycancrinite | Na8(Al6Si6O24)(OH)2 · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Liottite | (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 | Hex. 6 : _P_6 |
9.FB.05 | Microsommite | Na4K2Ca2(Al6Si6O24)(SO4)Cl2 | Hex. 622 : _P_6322 |
9.FB.05 | Pitiglianoite | Na6K2(Al6Si6O24)(SO4) · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Quadridavyne | (Na,K)6Ca2(Al6Si6O24)Cl4 | Hex. 6/m : _P_63/m |
9.FB.05 | Sacrofanite | (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O | Hex. |
9.FB.05 | Tounkite | (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O | Hex. 622 : _P_6222 |
9.FB.05 | Vishnevite | (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Marinellite | (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O | Trig. 3_m_ : P_31_c |
9.FB.05 | Farneseite | (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O | Hex. 6/m : _P_63/m |
9.FB.05 | Alloriite | (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 | Trig. 3_m_ : P_31_c |
9.FB.05 | Biachellaite | (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O | Trig. 3 : _P_3 |
9.FB.05 | Fantappièite | [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O | Trig. 3 : _R_3 |
9.FB.05 | Kyanoxalite | Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5) | Hex. 6 : _P_63 |
9.FB.05 | Balliranoite | (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) | Hex. 6 : _P_63 |
9.FB.05 | Carbobystrite | Na8(Al6Si6O24)(CO3) · 3.5H2O | Trig. 3_m_ : P_31_c |
9.FB.05 | Depmeierite | Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) | Hex. 6 : _P_63 |
9.FB.05 | Kircherite | Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O | Trig. 32 : _R_32 |
9.FB.05 | Sulfhydrylbystrite | Na5K2Ca[Al6Si6O24](S5)2(SH) | Trig. 3_m_ : P_31_c |
9.FB.10 | Bicchulite | Ca2(Al2SiO6)(OH)2 | Iso. 43_m_ : I_43_m |
9.FB.10 | Danalite | Be3Fe2+4(SiO4)3S | Iso. 43_m_ : P_43_n |
9.FB.10 | Genthelvite | Be3Zn4(SiO4)3S | Iso. 43_m_ : P_43_n |
9.FB.10 | Haüyne | Na3Ca(Si3Al3)O12(SO4) | Iso. 43_m_ : P_43_n |
9.FB.10 | Helvine | Be3Mn2+4(SiO4)3S | Iso. 43_m_ : P_43_n |
9.FB.10 | Kamaishilite | Ca2(Al2SiO6)(OH)2 | Tet. |
9.FB.10 | Lazurite | Na7Ca(Al6Si6O24)(SO4)(S3) · H2O | Iso. 43_m_ : P_43_n |
9.FB.10 | Nosean | Na8(Al6Si6O24)(SO4) · H2O | Iso. 43_m_ : P_43_n |
9.FB.10 | Sodalite | Na4(Si3Al3)O12Cl | Iso. 43_m_ : P_43_n |
9.FB.10 | Tsaregorodtsevite | (N(CH3)4)(AlSi5O12) | Orth. 222 : _I_222 |
9.FB.10 | Tugtupite | Na4BeAlSi4O12Cl | Tet. 4 : _I_4 |
9.FB.10 | Vladimirivanovite | Na6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2O | Orth. m m m _(_2/_m_2/_m_2/m ) |
9.FB.15 | Marialite | Na4Al3Si9O24Cl | Tet. 4/m : _I_4/m |
9.FB.15 | Meionite | Ca4Al6Si6O24CO3 | Tet. 4/m : _I_4/m |
9.FB.15 | Silvialite | (Ca,Na)4(Al6Si6O24)(SO4,CO3) | Tet. 4/m : _I_4/m |
Other InformationHide
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Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for AfghaniteHide
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References for AfghaniteHide
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Reference List:
Ballirano, Paolo, Bonaccorsi, Elena, Maras, Adriana, Merlino, Stefanο (1996) Crystal structure of afghanite, the eight-layer member of the cancrinite-group: evidence for long-range Si,Al ordering. European Journal of Mineralogy, 9 (1) 21-30 doi:10.1127/ejm/9/1/0021
Localities for AfghaniteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.