Afghanite (original) (raw)

A valid IMA mineral species

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About AfghaniteHide

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Formula:

(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6

Colour:

White, light blue, dark blue

Name:

Named after the country of its discovery, Afghanistan.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:41:9

6f9e1a00-d7ad-4dfc-a023-919dec36009c

IMA Classification of AfghaniteHide

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IMA Formula:

(Na,K)22Ca10(Si24Al24)O96(SO4)6Cl6

Type description reference:

Classification of AfghaniteHide

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9.FB.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions

76.2.5.1

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species

17.10.12

17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Afg IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AfghaniteHide

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Colour:

White, light blue, dark blue

Comment:

Colourless in thin section

Density:

2.55 g/cm3 (Measured) 2.65 g/cm3 (Calculated)

Optical Data of AfghaniteHide

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RI values:

_n_ω = 1.523 _n_ε = 1.529

δ = 0.006

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of AfghaniteHide

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Mindat Formula:

(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6

Crystallography of AfghaniteHide

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Class (H-M):

3_m_ - Ditrigonal Pyramidal

Cell Parameters:

a = 12.8013(7) Å, c = 21.4119(18) Å

Unit Cell V:

3,038.74 ų (Calculated from Unit Cell)

Morphology:

As stout to slender, thin tabular laths and as rounded grains.

Comment:

Cell data from Ballirano et al. (1996). Previously assumed space group P63mc is incorrect.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0018843 Afghanite Ballirano P, Bosi F (2012) Thermal behavior of afghanite, an ABABACAC member of the cancrinite group American Mineralogist 97 630-640 2012 Case Collina, Latium, Italy 0 293
0006636 Afghanite Ballirano P, Bonaccorsi E, Maras A, Merlino S (1997) Crystal structure of afghanite, the eight-layer member of the cancrinite-group: evidence for long-range Si,Al ordering European Journal of Mineralogy 9 21-30 1997 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.688 Å (100)
3.298 Å (100)
4.82 Å (80)
3.997 Å (60)
2.865 Å (60)
2.130 Å (60)
1.792 Å (60)

Geological EnvironmentHide

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Geological Setting:

In silicified limestone xenoliths in pumice (Pitigliano quarry, Italy).

Type Occurrence of AfghaniteHide

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General Appearance of Type Material:

In thin veinlets cutting lazurite crystals.

Place of Conservation of Type Material:

Mineralogy-Crystallography Laboratory, University Pierre and Marie Curie, Paris;
National School of Mines, Paris, France;
The Natural History Museum, London, England, 1969,72.

Associated Minerals at Type Locality:

Reference:

Bariand,P., Cesbron, F., Giraud, R. (1968) Une nouvelle espèce minérale: l'afghanite de Sar-e-sang, Badakhshan, Afghanistan. Comparaison avec les minéraux du groupe de la cancrinite. Bulletin de la Société Francaise de Minéralogie et Christallographie: 91: 34-42.

Synonyms of AfghaniteHide

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Other Language Names for AfghaniteHide

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Relationship of Afghanite to other SpeciesHide

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Other Members of this group:

Alloriite (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 Trig. 3_m_ : P_31_c
Balliranoite (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) Hex. 6 : _P_63
Betzite Na6Ca2(Al6Si6O24)Cl4 Hex. 6 : _P_63
Biachellaite (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O Trig. 3 : _P_3
Bystrite (Na,K)7Ca(Al6Si6O24)(S5)Cl Trig. 3_m_ : P_31_c
Cancrinite (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O Hex. 6 : _P_63
Cancrisilite Na7(Al5Si7O24)(CO3) · 3H2O Hex. 6_m_ m : P_63_m c
Carbobystrite Na8(Al6Si6O24)(CO3) · 3.5H2O Trig. 3_m_ : P_31_c
Davyne (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 Hex. 6/m : _P_63/m
Depmeierite Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) Hex. 6 : _P_63
Fantappièite [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O Trig. 3 : _R_3
Farneseite (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O Hex. 6/m : _P_63/m
Franzinite (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O Hex.
Giuseppettite (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 Trig. 3_m_ : P_31_c
Hydroxycancrinite Na8(Al6Si6O24)(OH)2 · 2H2O Hex. 6 : _P_63
Kircherite Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O Trig. 32 : _R_32
Kyanoxalite Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5) Hex. 6 : _P_63
Liottite (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 Hex. 6 : _P_6
Marinellite (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O Trig. 3_m_ : P_31_c
Microsommite Na4K2Ca2(Al6Si6O24)(SO4)Cl2 Hex. 622 : _P_6322
Pitiglianoite Na6K2(Al6Si6O24)(SO4) · 2H2O Hex. 6 : _P_63
Quadridavyne (Na,K)6Ca2(Al6Si6O24)Cl4 Hex. 6/m : _P_63/m
Sacrofanite (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O Hex.
Steudelite Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O Hex. 6_m_2 : P_62_c
Sulfhydrylbystrite Na5K2Ca[Al6Si6O24](S5)2(SH) Trig. 3_m_ : P_31_c
Tounkite (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O Hex. 622 : _P_6222
UM2004-48-SiO:AlClCaNaS (Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3
UM2009-23-SiO:AlCCaClHKNaS (Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2O Trig. 3 : _P_3
Vishnevite (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O Hex. 6 : _P_63

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.FB. Steudelite Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O Hex. 6_m_2 : P_62_c
9.FB. Sapozhnikovite Na8(Al6Si6O24)(HS)2 Iso. 43_m_ : P_43_n
9.FB. Betzite Na6Ca2(Al6Si6O24)Cl4 Hex. 6 : _P_63
9.FB. Slyudyankaite Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O Tric. 1 : _P_1
9.FB. Bolotinaite (Na7◻)(Al6Si6O24)F · 4H2O Iso. 43_m_ : I_43_m
9.FB. Wenlanzhangite-(Y) Y2V3+2V4+2(SiO4)2O4(OH)4 Tric. 1 : _P_1
9.FB.05 Bystrite (Na,K)7Ca(Al6Si6O24)(S5)Cl Trig. 3_m_ : P_31_c
9.FB.05 Cancrinite (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O Hex. 6 : _P_63
9.FB.05 Cancrisilite Na7(Al5Si7O24)(CO3) · 3H2O Hex. 6_m_ m : P_63_m c
9.FB.05 Davyne (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 Hex. 6/m : _P_63/m
9.FB.05 Franzinite (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O Hex.
9.FB.05 Giuseppettite (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 Trig. 3_m_ : P_31_c
9.FB.05 Hydroxycancrinite Na8(Al6Si6O24)(OH)2 · 2H2O Hex. 6 : _P_63
9.FB.05 Liottite (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 Hex. 6 : _P_6
9.FB.05 Microsommite Na4K2Ca2(Al6Si6O24)(SO4)Cl2 Hex. 622 : _P_6322
9.FB.05 Pitiglianoite Na6K2(Al6Si6O24)(SO4) · 2H2O Hex. 6 : _P_63
9.FB.05 Quadridavyne (Na,K)6Ca2(Al6Si6O24)Cl4 Hex. 6/m : _P_63/m
9.FB.05 Sacrofanite (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O Hex.
9.FB.05 Tounkite (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O Hex. 622 : _P_6222
9.FB.05 Vishnevite (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O Hex. 6 : _P_63
9.FB.05 Marinellite (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O Trig. 3_m_ : P_31_c
9.FB.05 Farneseite (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O Hex. 6/m : _P_63/m
9.FB.05 Alloriite (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 Trig. 3_m_ : P_31_c
9.FB.05 Biachellaite (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O Trig. 3 : _P_3
9.FB.05 Fantappièite [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O Trig. 3 : _R_3
9.FB.05 Kyanoxalite Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5) Hex. 6 : _P_63
9.FB.05 Balliranoite (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) Hex. 6 : _P_63
9.FB.05 Carbobystrite Na8(Al6Si6O24)(CO3) · 3.5H2O Trig. 3_m_ : P_31_c
9.FB.05 Depmeierite Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) Hex. 6 : _P_63
9.FB.05 Kircherite Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O Trig. 32 : _R_32
9.FB.05 Sulfhydrylbystrite Na5K2Ca[Al6Si6O24](S5)2(SH) Trig. 3_m_ : P_31_c
9.FB.10 Bicchulite Ca2(Al2SiO6)(OH)2 Iso. 43_m_ : I_43_m
9.FB.10 Danalite Be3Fe2+4(SiO4)3S Iso. 43_m_ : P_43_n
9.FB.10 Genthelvite Be3Zn4(SiO4)3S Iso. 43_m_ : P_43_n
9.FB.10 Haüyne Na3Ca(Si3Al3)O12(SO4) Iso. 43_m_ : P_43_n
9.FB.10 Helvine Be3Mn2+4(SiO4)3S Iso. 43_m_ : P_43_n
9.FB.10 Kamaishilite Ca2(Al2SiO6)(OH)2 Tet.
9.FB.10 Lazurite Na7Ca(Al6Si6O24)(SO4)(S3) · H2O Iso. 43_m_ : P_43_n
9.FB.10 Nosean Na8(Al6Si6O24)(SO4) · H2O Iso. 43_m_ : P_43_n
9.FB.10 Sodalite Na4(Si3Al3)O12Cl Iso. 43_m_ : P_43_n
9.FB.10 Tsaregorodtsevite (N(CH3)4)(AlSi5O12) Orth. 222 : _I_222
9.FB.10 Tugtupite Na4BeAlSi4O12Cl Tet. 4 : _I_4
9.FB.10 Vladimirivanovite Na6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2O Orth. m m m _(_2/_m_2/_m_2/m )
9.FB.15 Marialite Na4Al3Si9O24Cl Tet. 4/m : _I_4/m
9.FB.15 Meionite Ca4Al6Si6O24CO3 Tet. 4/m : _I_4/m
9.FB.15 Silvialite (Ca,Na)4(Al6Si6O24)(SO4,CO3) Tet. 4/m : _I_4/m

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for AfghaniteHide

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Reference List:

Ballirano, Paolo, Bonaccorsi, Elena, Maras, Adriana, Merlino, Stefanο (1996) Crystal structure of afghanite, the eight-layer member of the cancrinite-group: evidence for long-range Si,Al ordering. European Journal of Mineralogy, 9 (1) 21-30 doi:10.1127/ejm/9/1/0021

Localities for AfghaniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Afghanistan
Badakhshan Hogarth (1979)
Kuran wa Munjan District Robate Payan Dudley Blauwet priv. comm. (2008)
Sar-e-Sang Ladjuar Medam (TL) Bariand et al. (1968) +1 other reference
Dar-e-Zu mine Woodside et al. (2014)
Sar-e-Sang River Fernando Camara (2013)
Canada
Nunavut Qikiqtaaluk Region Baffin Island Kimmirut (Lake Harbour) Hogarth (1979)
Germany
Rhineland-Palatinate Mayen-Koblenz Vordereifel Bellerberg volcano Blaß et al. (2003)
Ettringen Caspar quarry Blaß et al. (2001)
Italy
Campania Metropolitan City of Naples Mount Somma ... +5 other references
Latera volcanic complex in the collection of Luigi Mattei
Lazio Metropolitan City of Rome Capital Magliano Romano Fosso Attici Stoppani et al. (1982)
Sacrofano Parodi et al. (1996)
Stracciacappe caldera Gresta et al. (2002)
Viterbo Province Bassano Romano Stoppani et al. (1982) +1 other reference
Farnese Di Domenico Dario
Gradoli Poggio Pinzo (Gradoli pozzolana quarry) Signoretti et al. (2001)
Onano Montenero Quarry Cresta et al. (2002)
Valentano Mt Saliette Burli et al. (2007)
Vetralla Pian di San Martino Signoretti et al. (2004) +1 other reference
Tre Croci American Mineralogist
Villa San Giovanni in Tuscia Carlini
Viterbo Castellaccio di Petrignano Bill Henderson specimens
Le Carcarelle www.gminromano.it (2005) +1 other reference
San Martino al Cimino Stoppani et al. (1982)
Tuscany Grosseto Province Pitigliano Case Collina Liotti L. (Grosseto)
Russia
Lake Baikal area Slyudyanka Malaya Bystraya River Valley Malo-Bystrinskoe lazurite deposit Hogarth (1979) +1 other reference
Tultui lazurite deposit Pavel.M. Kartashov (n.d.) +2 other references
Tajikistan
Gorno-Badakhshan Shughnon Shakhdara range Badom-Dara Lyadzhvardara deposit (Lyadzhvar Dara; Lyajvardara; Luadzhvardara) Hogarth (1979)
USA
New York St. Lawrence County Edwards Edwards Mine (St. Joe Lead) Hogarth (1979)