Cerchiaraite-(Al) (original) (raw)

A valid IMA mineral species

08455500015781238173573.jpg

09194230017056208289135.jpg

08455500015781238173573.jpg

09194230017056208289135.jpg

08455500015781238173573.jpg

09194230017056208289135.jpg

About Cerchiaraite-(Al)Hide

This section is currently hidden. Click the show button to view.

Formula:

Ba4Al4O3(OH)3(Si4O12)[Si2O3(OH)4]Cl

Colour:

Blue to bluish-green

Crystal System:

Tetragonal

Name:

in allusion to relation with "cerchiaraite" (now cerchiaraite-(Mn))

Co-Type Localities:

Esquire No. 7 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA
Esquire No. 8 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA
Esquire No. 1 claim, Rush Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA

The Al analogue of cerchiaraite-(Mn) (ex-cerchiaraite) and cerchiaraite-(Fe). Chemically related to meierite.

The structure details (1) corner-sharing silicate tetrahedra, forming 4-membered rings; (2) the rings share corners with an edge-sharing chain of AlO6 octahedra || c; (3) the rings alternate with Cl sites alternates along c; (4) large channels in the framework host Ba around their peripheries, statistically distributed Si2O3(OH)4 dimers, and Cl atoms.

Unique IdentifiersHide

This section is currently hidden. Click the show button to view.

Long-form identifier:

mindat:1:1:42782:3

6415d2c0-dee4-4e29-98eb-ccaa6fb9abdd

IMA Classification of Cerchiaraite-(Al)Hide

This section is currently hidden. Click the show button to view.

IMA Formula:

Ba4Al4(Si4O12)O2(OH)4Cl2[Si2O3(OH)4]

Classification of Cerchiaraite-(Al)Hide

This section is currently hidden. Click the show button to view.

9.CF.25

9 : SILICATES (Germanates)
C : Cyclosilicates
F : [Si4O12]8- 4-membered single rings, with insular complex anions

Mineral SymbolsHide

This section is currently hidden. Click the show button to view.

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Ccr-Al IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Cerchiaraite-(Al)Hide

This section is currently hidden. Click the show button to view.

Colour:

Blue to bluish-green

Fracture:

Irregular/Uneven

Density:

3.69(3) g/cm3 (Measured) 3.643 g/cm3 (Calculated)

Optical Data of Cerchiaraite-(Al)Hide

This section is currently hidden. Click the show button to view.

RI values:

_n_ω = 1.695(2) _n_ε = 1.677(2)

δ = 0.018

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

colorless (O), blue (E), O < E

Chemistry of Cerchiaraite-(Al)Hide

This section is currently hidden. Click the show button to view.

Mindat Formula:

Ba4Al4O3(OH)3(Si4O12)[Si2O3(OH)4]Cl

Common Impurities:

Fe(III),Mg,Fe(II),(Mn(II))

Crystallography of Cerchiaraite-(Al)Hide

This section is currently hidden. Click the show button to view.

Crystal System:

Tetragonal

Class (H-M):

4/m m m _(_4/_m_2/_m_2/m ) - Ditetragonal Dipyramidal

Cell Parameters:

a = 14.317(4) Å, c = 6.0037(18) Å

X-Ray Powder DiffractionHide

This section is currently hidden. Click the show button to view.

Powder Diffraction Data:

d-spacing Intensity
10.15 Å (39)
4.407 Å (39)
3.316 Å (74)
3.009 Å (100)
2.580 Å (93)
2.029 Å (43)
1.880 Å (68)
1.403 Å (54)

Geological EnvironmentHide

This section is currently hidden. Click the show button to view.

Geological Setting:

Esquire #7 and #8 claims

Type Occurrence of Cerchiaraite-(Al)Hide

This section is currently hidden. Click the show button to view.

Co-Type Localities:

Esquire No. 7 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA
Esquire No. 8 claim, Big Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA
Esquire No. 1 claim, Rush Creek, Big Creek-Rush Creek Mining District, Fresno County, California, USA

General Appearance of Type Material:

subparallel aggregates of irregular prisms, generally less than 1 mm across

Place of Conservation of Type Material:

Natural History Museum of Los Angeles County, Los Angeles, California, USA, catalogue numbers 63519, 63517 and 63518

Geological Setting of Type Material:

quartz-sanbomite vein assemblages resulting fromfluid interaction along the margin of the vein; associated minerals concert Esquire # 1 claim

Associated Minerals at Type Locality:

Synonyms of Cerchiaraite-(Al)Hide

This section is currently hidden. Click the show button to view.

Relationship of Cerchiaraite-(Al) to other SpeciesHide

This section is currently hidden. Click the show button to view.

Other Members of this group:

Cerchiaraite-(Fe) Ba4Fe3+4O3(OH)3(Si4O12)[Si2O3(OH)4]Cl Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m m m
Cerchiaraite-(Mn) Ba4Mn3+4(Si4O12)O2(OH)4Cl2[Si2O3(OH)4] Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m m m

Common AssociatesHide

This section is currently hidden. Click the show button to view.

Associated Minerals Based on Photo Data:

This section is currently hidden. Click the show button to view.

9.CF. Bobmeyerite Pb4(Al3Cu)(Si4O12)(S0.5Si0.5O4)(OH)7Cl(H2O)3 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
9.CF.05 Ashburtonite Pb4Cu4(Si4O12)(HCO3)4(OH)3Cl · H2O Tet.
9.CF.10 Kainosite-(Y) Ca2(Y,Ce)2(Si4O12)(CO3) · H2O Orth. m m m _(_2/_m_2/_m_2/m )
9.CF.15 Clinophosinaite Na12(Ca,Sr)4(Si4O12)(PO4)4 Mon. 2/m : _P_2/b
9.CF.15 Phosinaite-(Ce) Na13Ca2(Ce,La,Th,Nd,Pr)(Si4O12)(PO4)4 Orth. 222 : _P_21212
9.CF.20 Strakhovite NaBa3Mn2+2Mn3+2Si6O19(OH)3 Orth. m m m _(_2/_m_2/_m_2/m )
9.CF.25 Cerchiaraite-(Mn) Ba4Mn3+4(Si4O12)O2(OH)4Cl2[Si2O3(OH)4] Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m m m
9.CF.25 Cerchiaraite-(Fe) Ba4Fe3+4O3(OH)3(Si4O12)[Si2O3(OH)4]Cl Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m m m

Other InformationHide

This section is currently hidden. Click the show button to view.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

This section is currently hidden. Click the show button to view.

References for Cerchiaraite-(Al)Hide

This section is currently hidden. Click the show button to view.

Reference List:

Kampf, A. R., Roberts, A. C., Venance, K. E., Carbone, C., Belmonte, D., Dunning, G. E., Walstrom, R. E. (2013) Cerchiaraite-(Fe) and cerchiaraite-(Al), two new barium cyclosilicate chlorides from Italy and California, USA. Mineralogical Magazine, 77 (1) 69-80 doi:10.1180/minmag.2013.077.1.07

Localities for Cerchiaraite-(Al)Hide

This section is currently hidden. Click the show button to view.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

This section is currently hidden. Click the show button to view.