Mössbauerite (original) (raw)
A valid IMA mineral species
About MössbaueriteHide
This section is currently hidden. Click the show button to view.
Formula:
Fe3+6O4(OH)8[CO3] · 3H2O
Specific Gravity:
2.950 (Calculated)
Name:
Named after Professor Rudolf Ludwig Mössbauer (31 January 1929 Munich – 14 September 2011 Grünwald, Germany) who discovered the resonance of γ rays that bears his name, for which he was awarded the 1961 Nobel Prize in physics. Without this technique, the very existence of this mineral in gleysols and the true nature of the ‘green rust’ compounds could not be understood
Hydrotalcite supergroup. It has a layered double hydroxide-type structure, in which brucite-like layers [Fe3+6O4(OH)8]2+ are intercalated with CO32- anions and water molecules.
The fully oxidized analogue of fougèrite and trébeurdenite, related to them chemically by the exchange of (Fe3+O2−) with (Fe2+OH−).
Synchrotron X-ray data indicate that the natural material is a nanoscale intergrowth of 2T and 3T polytypes; the latter probably has the 3T7 stacking sequence.
Unique IdentifiersHide
This section is currently hidden. Click the show button to view.
Long-form identifier:
mindat:1:1:43298:6
a0dd7617-fca0-418e-bd60-2cceb2214b71
IMA Classification of MössbaueriteHide
This section is currently hidden. Click the show button to view.
IMA Formula:
Fe3+6O4(OH)8(CO3) · 3H2O
Classification of MössbaueriteHide
This section is currently hidden. Click the show button to view.
4.FL.05
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
L : Hydroxides with H2O +- (OH); sheets of edge-sharing octahedra
Mineral SymbolsHide
This section is currently hidden. Click the show button to view.
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Msb | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Msb | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of MössbaueriteHide
This section is currently hidden. Click the show button to view.
Comment:
Pure synthetic mössbauerite is orange in colour
Cleavage:
Perfect
{0001} ideally
Density:
2.950 g/cm3 (Calculated)
Chemistry of MössbaueriteHide
This section is currently hidden. Click the show button to view.
Mindat Formula:
Fe3+6O4(OH)8[CO3] · 3H2O
Crystallography of MössbaueriteHide
This section is currently hidden. Click the show button to view.
Class (H-M):
3 - Rhombohedral
Cell Parameters:
a = 3.032(7) Å, b = 3.079 Å, c = 22.258(4) Å
Ratio:
a:b:c = 0.985 : 1 : 7.229
Unit Cell V:
177.20 ų (Calculated from Unit Cell)
Comment:
Possible space group: P3İm1 and P3m1
X-Ray Powder DiffractionHide
This section is currently hidden. Click the show button to view.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
7.372 Å | (60) |
3.691 Å | (20) |
2.646 Å | (100) |
2.588 Å | (70) |
2.406 Å | (40) |
1.928 Å | (30) |
1.855 Å | (50) |
Comments:
From Type Description.
Geological EnvironmentHide
This section is currently hidden. Click the show button to view.
Type Occurrence of MössbaueriteHide
This section is currently hidden. Click the show button to view.
General Appearance of Type Material:
As μm-scale platelets in gleys with restricted access to atmospheric O.
Place of Conservation of Type Material:
Museum Victoria, Melbourne, Australia, registration number M52078
Geological Setting of Type Material:
Intimately intergrown with trébeurdenite, was discovered in intertidal gleys from Mont Saint-Michel Bay, France.
Associated Minerals at Type Locality:
Synonyms of MössbaueriteHide
This section is currently hidden. Click the show button to view.
Relationship of Mössbauerite to other SpeciesHide
This section is currently hidden. Click the show button to view.
Other Members of this group:
Fougèrite | Fe2+4Fe3+2(OH)12[CO3] · 3H2O | Trig. 3_m_ _(_32/m ) : R_3_m |
---|---|---|
Liudongshengite | Zn4Cr2(OH)12(CO3) · 3H2O | Trig. 3_m_ _(_32/m ) : R_3_m |
Trébeurdenite | Fe2+2Fe3+4O2(OH)10CO3 · 3H2O | Trig. 3_m_ _(_32/m ) : R_3_m |
Common AssociatesHide
This section is currently hidden. Click the show button to view.
Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
This section is currently hidden. Click the show button to view.
4.FL. | Trébeurdenite | Fe2+2Fe3+4O2(OH)10CO3 · 3H2O | Trig. 3_m_ _(_32/m ) : R_3_m |
---|---|---|---|
4.FL. | Mariakrite | [Ca4Al2(OH)12(H2O)4][Fe2S4] | Tric. 1 : _P_1 |
4.FL.05 | Woodallite | Mg6Cr2(OH)16Cl2 · 4H2O | Trig. 3_m_ _(_32/m ) : R_3_m |
4.FL.05 | Iowaite | Mg6Fe3+2(OH)16Cl2 · 4H2O | Trig. 3_m_ _(_32/m ) : R_3_m |
4.FL.05 | Jamborite | Ni2+1-xCo3+x(OH)2-x(SO4)x · nH2O | Trig. 3_m_ _(_32/m ) : R_3_m |
4.FL.05 | Meixnerite | Mg6Al2(OH)16(OH)2 · 4H2O | Trig. 3_m_ _(_32/m ) : R_3_m |
4.FL.05 | Muskoxite | Mg7Fe4O13 · 10H2O | Trig. 3_m_ _(_32/m ) |
4.FL.05 | Fougèrite | Fe2+4Fe3+2(OH)12[CO3] · 3H2O | Trig. 3_m_ _(_32/m ) : R_3_m |
4.FL.05 | Dritsite | Li2Al4(OH)12Cl2 · 3H2O | Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m c m |
4.FL.10 | Hydrocalumite | Ca4Al2(OH)12(Cl,CO3,OH)2 · 4H2O | Mon. 2 : _P_21 |
4.FL.15 | Kuzelite | Ca4Al2(OH)12[SO4] · 6H2O | Trig. |
4.FL.20 | Aurorite | Mn2+Mn4+3O7 · 3H2O | Trig. 3 : _R_3 |
4.FL.20 | Chalcophanite | ZnMn4+3O7 · 3H2O | Trig. 3 : _R_3 |
4.FL.20 | Ernienickelite | NiMn3O7 · 3H2O | Trig. 3 : _R_3 |
4.FL.20 | Jianshuiite | (Mg,Mn,Ca)Mn3O7 · 3H2O | Trig. 3 : _R_3 |
4.FL.25 | Woodruffite | Zn2+x/2(Mn4+1-xMn3+x)O2 · yH2O | Mon. 2/m : _B_2/m |
4.FL.30 | Asbolane | (Ni,Co)2-xMn4+(O,OH)4 · nH2O | Hex. |
4.FL.30 va | Lampadite | Cu, Mn, O, H | |
4.FL.35 | Buserite | Na4Mn14O27 · 21H2O | |
4.FL.40 | Ranciéite | (Ca,Mn2+)0.2(Mn4+,Mn3+)O2 · 0.6H2O | Trig. 3 : _P_3 |
4.FL.40 | Takanelite | (Mn,Ca)Mn4O9 · H2O | Hex. |
4.FL.45 | Birnessite | (Na,Ca)0.5(Mn4+,Mn3+)2O4 · 1.5H2O | Mon. 2/m : _B_2/m |
4.FL.55 | Cianciulliite | Mn(Mg,Mn)2Zn2(OH)10 · 2-4H2O | Mon. 2/m : _B_2/m |
4.FL.60 | Jensenite | Cu3[TeO6] · 2H2O | Mon. 2/m : _P_21/m |
4.FL.65 | Leisingite | Cu2MgTe6+O6 · 6H2O | Trig. 3 : _P_3 |
4.FL.70 | Akdalaite | Al10O14(OH)2 | Hex. |
4.FL.75 | Cafetite | CaTi2O5 · H2O | Mon. 2/m : _P_21/b |
4.FL.80 | Mourite | UMo5O12(OH)10 | Mon. |
4.FL.85 | Deloryite | Cu4(UO2)(MoO4)2(OH)6 | Mon. 2/m : _B_2/m |
4.FL.90 | Lagalyite | Ca2xMn1-xO2 · 1.5-2H2O | Mon. |
4.FL.95 | Tunnerite (of Cornu) | ||
4.FL.100 | Carbocalumite | Ca4Al2(OH)12(CO3) · 6H2O | Trig. 3_m_ _(_32/m ) : R_3_c |
4.FL.100 | Mampsisite | Ca4Al2(CO3)(OH)12 · 5H2O | Tric. |
Other InformationHide
This section is currently hidden. Click the show button to view.
Special Storage/
Display Requirements:
Decomposes rapidly when exposed to air.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for MössbaueriteHide
This section is currently hidden. Click the show button to view.
References for MössbaueriteHide
This section is currently hidden. Click the show button to view.
Reference List:
Mills, S. J., Christy, A. G., Génin, J.-M. R., Kameda, T., Colombo, F. (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine, 76 (5) 1289-1336 doi:10.1180/minmag.2012.076.5.10
Génin, J.-M. R., Mills, S. J., Christy, A. G., Guérin, O., Herbillon, A. J., Kuzmann, E., Ona-Nguema, G., Ruby, C., Upadhyay, C. (2014) Mössbauerite, Fe63+O4(OH)8[CO3]·3H2O, the fully oxidized ‘green rust’ mineral from Mont Saint-Michel Bay, France. Mineralogical Magazine, 78 (2) 447-465 doi:10.1180/minmag.2014.078.2.14
Localities for MössbaueriteHide
This section is currently hidden. Click the show button to view.
This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
This section is currently hidden. Click the show button to view.
- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
France | |
---|---|
Brittany Côtes-d'Armor Dinan Lancieux ⓘ Salt marsh | Génin et al. (2014) |
Lannion Pleumeur-Bodou Penvern ⓘ Île Aval | Mills et al. (2012) |
Plougrescant ⓘ Salt marsh | Génin et al. (2014) |
Trébeurden ⓘ Penvern | Personal communication from geologist Odile Guérin to Erik Vercammen (August 2016) |
Trédrez-Locquémeau ⓘ Salt marsh | Génin et al. (2014) |
Ille-et-Vilaine Saint-Malo ⓘ Salt marsh | Génin et al. (2014) |
Normandy Manche Avranches Carolles ⓘ Mont Saint-Michel Bay | Génin et al. (2014) |
Le Mont-Saint-Michel ⓘ Mont Saint-Michel marshes (TL) | Williams et al. (2013) +2 other references |