Mössbauerite (original) (raw)

A valid IMA mineral species

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02814450014947020578841.jpg

02814450014947020578841.jpg

About MössbaueriteHide

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Formula:

Fe3+6O4(OH)8[CO3] · 3H2O

Specific Gravity:

2.950 (Calculated)

Name:

Named after Professor Rudolf Ludwig Mössbauer (31 January 1929 Munich – 14 September 2011 Grünwald, Germany) who discovered the resonance of γ rays that bears his name, for which he was awarded the 1961 Nobel Prize in physics. Without this technique, the very existence of this mineral in gleysols and the true nature of the ‘green rust’ compounds could not be understood

Hydrotalcite supergroup. It has a layered double hydroxide-type structure, in which brucite-like layers [Fe3+6O4(OH)8]2+ are intercalated with CO32- anions and water molecules.

The fully oxidized analogue of fougèrite and trébeurdenite, related to them chemically by the exchange of (Fe3+O2−) with (Fe2+OH−).

Synchrotron X-ray data indicate that the natural material is a nanoscale intergrowth of 2T and 3T polytypes; the latter probably has the 3T7 stacking sequence.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:43298:6

a0dd7617-fca0-418e-bd60-2cceb2214b71

IMA Classification of MössbaueriteHide

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IMA Formula:

Fe3+6O4(OH)8(CO3) · 3H2O

Classification of MössbaueriteHide

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4.FL.05

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
L : Hydroxides with H2O +- (OH); sheets of edge-sharing octahedra

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol Source Reference
Msb IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Msb The Canadian Mineralogist (2019) The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of MössbaueriteHide

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Comment:

Pure synthetic mössbauerite is orange in colour

Cleavage:

Perfect
{0001} ideally

Density:

2.950 g/cm3 (Calculated)

Chemistry of MössbaueriteHide

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Mindat Formula:

Fe3+6O4(OH)8[CO3] · 3H2O

Crystallography of MössbaueriteHide

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Class (H-M):

3 - Rhombohedral

Cell Parameters:

a = 3.032(7) Å, b = 3.079 Å, c = 22.258(4) Å

Ratio:

a:b:c = 0.985 : 1 : 7.229

Unit Cell V:

177.20 ų (Calculated from Unit Cell)

Comment:

Possible space group: P3İm1 and P3m1

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
7.372 Å (60)
3.691 Å (20)
2.646 Å (100)
2.588 Å (70)
2.406 Å (40)
1.928 Å (30)
1.855 Å (50)

Comments:

From Type Description.

Geological EnvironmentHide

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Type Occurrence of MössbaueriteHide

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General Appearance of Type Material:

As μm-scale platelets in gleys with restricted access to atmospheric O.

Place of Conservation of Type Material:

Museum Victoria, Melbourne, Australia, registration number M52078

Geological Setting of Type Material:

Intimately intergrown with trébeurdenite, was discovered in intertidal gleys from Mont Saint-Michel Bay, France.

Associated Minerals at Type Locality:

Synonyms of MössbaueriteHide

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Relationship of Mössbauerite to other SpeciesHide

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Other Members of this group:

Fougèrite Fe2+4Fe3+2(OH)12[CO3] · 3H2O Trig. 3_m_ _(_32/m ) : R_3_m
Liudongshengite Zn4Cr2(OH)12(CO3) · 3H2O Trig. 3_m_ _(_32/m ) : R_3_m
Trébeurdenite Fe2+2Fe3+4O2(OH)10CO3 · 3H2O Trig. 3_m_ _(_32/m ) : R_3_m

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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4.FL. Trébeurdenite Fe2+2Fe3+4O2(OH)10CO3 · 3H2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL. Mariakrite [Ca4Al2(OH)12(H2O)4][Fe2S4] Tric. 1 : _P_1
4.FL.05 Woodallite Mg6Cr2(OH)16Cl2 · 4H2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL.05 Iowaite Mg6Fe3+2(OH)16Cl2 · 4H2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL.05 Jamborite Ni2+1-xCo3+x(OH)2-x(SO4)x · nH2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL.05 Meixnerite Mg6Al2(OH)16(OH)2 · 4H2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL.05 Muskoxite Mg7Fe4O13 · 10H2O Trig. 3_m_ _(_32/m )
4.FL.05 Fougèrite Fe2+4Fe3+2(OH)12[CO3] · 3H2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL.05 Dritsite Li2Al4(OH)12Cl2 · 3H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m c m
4.FL.10 Hydrocalumite Ca4Al2(OH)12(Cl,CO3,OH)2 · 4H2O Mon. 2 : _P_21
4.FL.15 Kuzelite Ca4Al2(OH)12[SO4] · 6H2O Trig.
4.FL.20 Aurorite Mn2+Mn4+3O7 · 3H2O Trig. 3 : _R_3
4.FL.20 Chalcophanite ZnMn4+3O7 · 3H2O Trig. 3 : _R_3
4.FL.20 Ernienickelite NiMn3O7 · 3H2O Trig. 3 : _R_3
4.FL.20 Jianshuiite (Mg,Mn,Ca)Mn3O7 · 3H2O Trig. 3 : _R_3
4.FL.25 Woodruffite Zn2+x/2(Mn4+1-xMn3+x)O2 · yH2O Mon. 2/m : _B_2/m
4.FL.30 Asbolane (Ni,Co)2-xMn4+(O,OH)4 · nH2O Hex.
4.FL.30 va Lampadite Cu, Mn, O, H
4.FL.35 Buserite Na4Mn14O27 · 21H2O
4.FL.40 Ranciéite (Ca,Mn2+)0.2(Mn4+,Mn3+)O2 · 0.6H2O Trig. 3 : _P_3
4.FL.40 Takanelite (Mn,Ca)Mn4O9 · H2O Hex.
4.FL.45 Birnessite (Na,Ca)0.5(Mn4+,Mn3+)2O4 · 1.5H2O Mon. 2/m : _B_2/m
4.FL.55 Cianciulliite Mn(Mg,Mn)2Zn2(OH)10 · 2-4H2O Mon. 2/m : _B_2/m
4.FL.60 Jensenite Cu3[TeO6] · 2H2O Mon. 2/m : _P_21/m
4.FL.65 Leisingite Cu2MgTe6+O6 · 6H2O Trig. 3 : _P_3
4.FL.70 Akdalaite Al10O14(OH)2 Hex.
4.FL.75 Cafetite CaTi2O5 · H2O Mon. 2/m : _P_21/b
4.FL.80 Mourite UMo5O12(OH)10 Mon.
4.FL.85 Deloryite Cu4(UO2)(MoO4)2(OH)6 Mon. 2/m : _B_2/m
4.FL.90 Lagalyite Ca2xMn1-xO2 · 1.5-2H2O Mon.
4.FL.95 Tunnerite (of Cornu)
4.FL.100 Carbocalumite Ca4Al2(OH)12(CO3) · 6H2O Trig. 3_m_ _(_32/m ) : R_3_c
4.FL.100 Mampsisite Ca4Al2(CO3)(OH)12 · 5H2O Tric.

Other InformationHide

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Special Storage/
Display Requirements:

Decomposes rapidly when exposed to air.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for MössbaueriteHide

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Reference List:

Mills, S. J., Christy, A. G., Génin, J.-M. R., Kameda, T., Colombo, F. (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine, 76 (5) 1289-1336 doi:10.1180/minmag.2012.076.5.10

Génin, J.-M. R., Mills, S. J., Christy, A. G., Guérin, O., Herbillon, A. J., Kuzmann, E., Ona-Nguema, G., Ruby, C., Upadhyay, C. (2014) Mössbauerite, Fe63+O4(OH)8[CO3]·3H2O, the fully oxidized ‘green rust’ mineral from Mont Saint-Michel Bay, France. Mineralogical Magazine, 78 (2) 447-465 doi:10.1180/minmag.2014.078.2.14

Localities for MössbaueriteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

France
Brittany Côtes-d'Armor Dinan Lancieux Salt marsh Génin et al. (2014)
Lannion Pleumeur-Bodou Penvern Île Aval Mills et al. (2012)
Plougrescant Salt marsh Génin et al. (2014)
Trébeurden Penvern Personal communication from geologist Odile Guérin to Erik Vercammen (August 2016)
Trédrez-Locquémeau Salt marsh Génin et al. (2014)
Ille-et-Vilaine Saint-Malo Salt marsh Génin et al. (2014)
Normandy Manche Avranches Carolles Mont Saint-Michel Bay Génin et al. (2014)
Le Mont-Saint-Michel Mont Saint-Michel marshes (TL) Williams et al. (2013) +2 other references