Minohlite (original) (raw)

A valid IMA mineral species

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About MinohliteHide

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Formula:

(Cu,Zn)7(SO4)2(OH)10 · 8H2O

Cu:Zn is somewhat variable.

Name:

Named after Minoh City, where it was discovered.

Chemically and structurally related to schulenbergite.
Minohlite and schulenbergite may be intimately intergrown (Orlandi, 2013).
If minohlite is heated >50°C, it turns into schulenbergite (Orlandi, 2013).

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:43349:9

98f849e9-6aca-4cc7-a548-ca3fa2502a0c

IMA Classification of MinohliteHide

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Type description reference:

Ohnishi, M., Shimobayashi, N., Nishio-Hamane, D., Shinoda, K., Momma, K., Ikeda, T. (2013) Minohlite, a new copper-zinc sulfate mineral from Minoh, Osaka, Japan. Mineralogical Magazine, 77 (3) 335-342 doi:10.1180/minmag.2013.077.3.07

Classification of MinohliteHide

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7.DD.50

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Mnh IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MinohliteHide

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Density:

3.39(2) g/cm3 (Measured) 3.28 g/cm3 (Calculated)

Optical Data of MinohliteHide

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Pleochroism:

Non-pleochroic

Chemistry of MinohliteHide

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Mindat Formula:

(Cu,Zn)7(SO4)2(OH)10 · 8H2O

Cu:Zn is somewhat variable.

Crystallography of MinohliteHide

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Cell Parameters:

a = 8.2535(11) Å, c = 8.1352(17) Å

Unit Cell V:

479.93 ų (Calculated from Unit Cell)

Comment:

Hexagonal (trigonal); space group uncertain (possibly: P6, P-6, P6/m, P622, P6mm, P-62m or P6/mmm (P3, P-3, P321, P3m1, P-3m1, P312, P31m or P-31m)).

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.138 Å (20)
4.128 Å (24)
2.702 Å (100)
2.564 Å (76)
1.560 Å (43)
1.532 Å (24)
1.351 Å (12)
1.333 Å (11)

Geological EnvironmentHide

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Type Occurrence of MinohliteHide

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General Appearance of Type Material:

Rosette aggregates up to 100 μm in diameter, composed of hexagonal platy crystals up to 50 μm in diameter and 10 μm in thickness.

Place of Conservation of Type Material:

Type material has been deposited in the collections of the National Museum of Nature and Science, Japan, catalogue numbers NSMM43670 and NSM-M43671, and the Kyoto University Museum, Japan, catalogue number KUM-M00001.

Geological Setting of Type Material:

A secondary mineral in the oxidation zone of a Zn-Cu deposit in shale.

Associated Minerals at Type Locality:

Reference:

Ohnishi, M., Shimobayashi, N., Nishio-Hamane, D., Shinoda, K., Momma, K., Ikeda, T. (2013) Minohlite, a new copper-zinc sulfate mineral from Minoh, Osaka, Japan. Mineralogical Magazine: 77: 335-342.

Synonyms of MinohliteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Other InformationHide

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Notes:

Easily soluble in dilute hydrochloric acid.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for MinohliteHide

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Reference List:

OHNISHI, Masayuki, KUSACHI, Isao, KOBAYASHI, Shoichi, YAMAKAWA, Junji (2007) Mineral chemistry of schulenbergite and its Zn-dominant analogue from the Hirao mine, Osaka, Japan. Journal of Mineralogical and Petrological Sciences, 102 (4) 233-239 doi:10.2465/jmps.061130

Ohnishi, M., Shimobayashi, N., Nishio-Hamane, D., Shinoda, K., Momma, K., Ikeda, T. (2013) Minohlite, a new copper-zinc sulfate mineral from Minoh, Osaka, Japan. Mineralogical Magazine, 77 (3) 335-342 doi:10.1180/minmag.2013.077.3.07

Ohnishi, M., Shimobayashi, N., Nishio-Hamane, D., Shinoda, K., Momma, K., Ikeda, T. (2013) Minohlite, a new copper-zinc sulfate mineral from Minoh, Osaka, Japan. Mineralogical Magazine, 77 (3) 335-342 doi:10.1180/minmag.2013.077.3.07

Localities for MinohliteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Germany
Rhineland-Palatinate Rhein-Lahn-Kreis Lahnstein Friedrichssegen Friedrichssegen Mine SEM-EDS by Günter Blaß +1 other reference
Greece
Attica East Attica Lavreotiki Lavrion Mining District Agios Konstantinos (Kamariza) Kamariza Mines (Kamareza Mines) Hilarion Mine Rieck et al. (2018)
Italy
Tuscany Livorno Province Campiglia Marittima Lanzi Mine (Cava del Piombo; Buca del Piombo) Biagioni et al. (2013)
Veneto Vicenza Province Torrebelvicino Mercanti Valley Monte Trisa Mines Orlandi (2013)
Gallery no. 2 Orlandi (2013)
Monte Naro Monte Naro - Riolo Valley side Contrada Trentini Trentini Mine Orlandi (2013)
Japan (TL)
Osaka Prefecture Minoh City Onsen-cho Hirao mine (TL) Williams et al. (2012) +2 other references
USA
Colorado San Juan County Eureka Mining District Gladstone Bonita Peak Sunnyside Mine group In the collection of Brent Thorne. ...