Zeophyllite (original) (raw)

A valid IMA mineral species - grandfathered

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About ZeophylliteHide

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Formula:

Ca13Si10O28(OH)2F8 · 6H2O

Specific Gravity:

2.747 - 2.764

Name:

Named after the Greek "ζέω" (zeo), 'to boil', and "φύλλον" (phyllos), 'leaf', alluding to its occurrence in hemispheral foliated forms and intumescence (swelling) on heating.

This page provides mineralogical data about Zeophyllite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:4396:6

9ba2b2f7-8fcc-4d9f-b0d2-3f63840043f7

IMA Classification of ZeophylliteHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of ZeophylliteHide

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9.EE.70

9 : SILICATES (Germanates)
E : Phyllosilicates
E : Single tetrahedral nets of 6-membered rings connected by octahedral nets or octahedral bands

73.1.4.1

73 : PHYLLOSILICATES Condensed Tetrahedral Sheets
1 : Condensed Tetrahedral Sheets with double layers

17.1.17

17 : Silicates Containing other Anions
1 : Silicates with fluoride (not containing Al)

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Zp IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ZeophylliteHide

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Density:

2.747 - 2.764 g/cm3 (Measured) 2.75 g/cm3 (Calculated)

Optical Data of ZeophylliteHide

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RI values:

_n_ω = 1.565 - 1.577 _n_ε = 1.560 - 1.569

δ = 0.005 - 0.008

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

anomalously biaxial

Chemistry of ZeophylliteHide

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Mindat Formula:

Ca13Si10O28(OH)2F8 · 6H2O

Common Impurities:

Al,Fe,Mg,Na,K

Crystallography of ZeophylliteHide

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Class (H-M):

3 - Rhombohedral

Cell Parameters:

a = 9.36 Å, c = 34.48 Å

Unit Cell V:

2,616.07 ų (Calculated from Unit Cell)

Morphology:

(Pseudo-?)hexagonal. As platy crystals in radiating spherical aggregates.

Comment:

Chalmers et al. (1956) give a pseudhexagonal cell with 9.34, 9.34, 13.2 Å, 90, 110, 120°.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0009455 Zeophyllite Merlino S (1972) The crystal structure of zeophyllite Acta Crystallographica B28 2726-2732 1972 Radzein, Bohemia, Czech Republic 0 293
0014639 Zeophyllite Mikenda W, Pertlik F, Povondra P, Ulrych J (1997) On zeophyllite from Radejcin, Ceske stredohori Mts.: X-ray and IR-investigations Mineralogy and Petrology 61 199-209 1997 Alter Berg, Radzein 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Radiation - Copper Kα

Data Set:

Data courtesy of RRUFF project at University of Arizona, used with permission.

Powder Diffraction Data:

d-spacing Intensity
12.0 Å (100)
3.03 Å (80)
6.09 Å (60)
2.946 Å (60)
3.71 Å (50)
2.648 Å (50)
2.547 Å (50)

Geological EnvironmentHide

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Type Occurrence of ZeophylliteHide

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General Appearance of Type Material:

radiating platy crystals, to 1 cm

Place of Conservation of Type Material:

Harvard University, Cambridge, Massachusetts, USA, 86427.

Geological Setting of Type Material:

secondary mineral from hydrothermal alteration of basalt

Associated Minerals at Type Locality:

Reference:

Chalmers R A, Dent L S, Taylor H F W (1958) Zeophyllite. Mineralogical Magazine 31, 726-735

Synonyms of ZeophylliteHide

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Other Language Names for ZeophylliteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.EE. Cairncrossite Sr2Ca7-xNa2x(Si4O10)4(OH)2(H2O)15-x Tric. 1 : _P_1
9.EE.05 Bementite Mn7Si6O15(OH)8 Mon.
9.EE.07 Innsbruckite Mn33(Si2O5)14(OH)38 Mon. m : B m
9.EE.10 Brokenhillite Mn8Si6O15(OH)10 Hex. 6_m_ m : P_63_m c
9.EE.10 Pyrosmalite-(Fe) Fe2+8Si6O15(OH,Cl)10 Trig. 3_m_ _(_32/m ) : _P_3_m_1
9.EE.10 Friedelite Mn2+8Si6O15(OH,Cl)10 Mon. 2/m : _B_2/m
9.EE.10 Pyrosmalite-(Mn) Mn2+8Si6O15(OH,Cl)10 Trig. 3_m_ _(_32/m ) : _P_3_m_1
9.EE.10 Mcgillite (Mn,Fe)8Si6O15(OH)8Cl2 Mon. 2/m : _B_2/m
9.EE.15 Nelenite (Mn,Fe)16(Si12O30)(OH)14[As3+3O6(OH)3] Trig. 3_m_ _(_32/m ) : R_3_m
9.EE.15 Schallerite Mn2+16As3Si12O36(OH)17 Trig. 3_m_ : _P_3_m_1
9.EE.20 Palygorskite ◻Al2Mg2◻2Si8O20(OH)2(H2O)4 · 4H2O Mon. 2/m : _B_2/m
9.EE.20 Tuperssuatsiaite Fe3+Fe3+2(Na◻)◻2Si8O20(OH)2(H2O)4 · 2H2O Mon. 2/m : _B_2/m
9.EE.20 Yofortierite Mn2+Mn2+2Mn2+2◻2Si8O20(OH)2(H2O)4 · 4H2O Mon. 2/m : _B_2/m
9.EE.20 Windhoekite Fe3+(Fe3+1.67◻0.33)Ca2◻2Si8O20(OH)2(H2O)4(OH)2 · 6H2O Mon. 2/m : _B_2/m
9.EE.20 Unnamed (Na-Ca-Fe-Silicate-Hydrate) NaCa(Fe2+,Al,Mn)5[Si8O19(OH)](OH)7 · 5H2O Tric. 1 : _P_1
9.EE.20 Windmountainite ◻Fe3+2Mg2◻2Si8O20(OH)2(H2O)4 · 4H2O Mon. 2/m : _B_2/m
9.EE.20 Ikorskyite KMn3+(Si4O10) · 3H2O Mon. 2/m : _P_21/b
9.EE.25 Falcondoite (Ni,Mg)4Si6O15(OH)2 · 6H2O Orth.
9.EE.25 Loughlinite Na2Mg3Si6O16 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m )
9.EE.25 Sepiolite Mg4(Si6O15)(OH)2 · 6H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n n a
9.EE.25 Kalifersite (K,Na)5Fe3+7Si20O50(OH)6 · 12H2O Tric. 1 : _P_1
9.EE.30 Gyrolite NaCa16Si23AlO60(OH)8 · 14H2O Tric. 1 : _P_1
9.EE.30 Orlymanite Ca4Mn3Si8O20(OH)6 · 2H2O Hex.
9.EE.30 Tungusite Ca4Fe2Si6O15(OH)6 Tric. 1 : _P_1
9.EE.35 Reyerite (Na,K)2Ca14(Si,Al)24O58(OH)8 · 6H2O Trig. 3 : _P_3
9.EE.35 Truscottite (Ca,Mn)14Si24O58(OH)8 · 2H2O Trig.
9.EE.35 Kodamaite Na3(Ca5Na)Si16O36(OH)4F2 · (14-x)H2O Tric. 1 : _P_1
9.EE.40 Natrosilite Na2Si2O5 Mon. 2/m : _P_21/b
9.EE.45 Makatite Na2Si4O8(OH)2 · 4H2O Mon. 2/m : _P_21/b
9.EE.50 Varennesite Na8Mn2Si10O25(OH,Cl)2 · 12H2O Orth. m m m _(_2/_m_2/_m_2/m ) : C m c m
9.EE.55 Raite Mn2+Mn2+2Na2(◻1.75Ti0.25)Si8O20(OH)2(H2O)4 · Na(H2O)6 Orth. 222 : _C_222
9.EE.60 Intersilite Na6Mn2+Ti[Si10O24(OH)](OH)3 · 4H2O Mon.
9.EE.65 Shafranovskite Na3K2(Mn,Fe,Na)4[Si9(O,OH)27](OH)2 · nH2O Trig. 3_m_ : P_31_c
9.EE.65 Zakharovite Na4Mn5Si10O24(OH)6 · 6H2O Trig. 3_m_
9.EE.75 Minehillite (K,Na)2-3Ca28Zn4Al4Si40O112(OH)16 Hex.
9.EE.80 Fedorite (Na,K)2-3(Ca4Na3)Si16O38(OH,F)2 · 3.5H2O Tric. 1 : _P_1
9.EE.80 Martinite (Na,◻,Ca)12Ca4(Si,S,B)14B2O38(OH,Cl)2F2 · 4H2O Tric. 1 : _P_1
9.EE.80 Ellingsenite Na5Ca6Si18O38(OH)13 · 6H2O Tric. 1 : _P_1
9.EE.85 Lalondeite (Na,Ca)6(Ca,Na)3Si16O38(F,OH)2 · 3H2O Tric. 1 : _P_1

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for ZeophylliteHide

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Localities for ZeophylliteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Austria
Styria Südoststeiermark District Feldbach Mühldorf bei Feldbach Steinberg Postl et al. (1996) +1 other reference
Canada
Québec Montérégie La Vallée-du-Richelieu RCM Mont Saint-Hilaire Poudrette quarry (De-Mix quarry; Demix quarry; Uni-Mix quarry; Carrière Mont Saint-Hilaire; MSH) Grice (1989) +1 other reference
Czech Republic
Liberec Region Česká Lípa District Cvikov Křížový vrch Pauliš et al. (2023)
Ústí nad Labem Region Děčín District Malá Veleň Soutěsky (Zautig) Soutěsky quarry (Zautig quarry) Slavíček
Ústí nad Labem District Řehlovice Radejčín (Radzein) Starý hill (Alter Berg) Mikenda +4 other references
Velké Březno (TL) Pelikan A (1902)
Kočičí hlava Hill (Katzenkoppe) Pelikan (1902)
Germany
North Rhine-Westphalia Cologne Rhein-Sieg-Kreis Königswinter Weilberg (Großer Weilberg) Brauns et al. (1922)
Rhineland-Palatinate Ahrweiler Brohltal Brenk Schellkopf Brauns +1 other reference
Mayen-Koblenz Vordereifel Ettringen Caspar quarry Blaß et al. (1992) +1 other reference
Hungary
Veszprém County Tapolca District Uzsa Láz Hill mine Vezzalini
Italy
Campania Metropolitan City of Naples Pollena Trocchia Passaglia et al. (1983)
Japan
Fukushima Prefecture Koriyama City Matsuyama (2001)
Okayama Prefecture Takahashi City Bitchū Shitouyouze Sampo mine Matsueda (1983)
Romania
Harghita County Ditrău Complex Hirtopanu (2006)
Jolotca (Orotva) Szakáll et al. (2010)
Russia
Kabardino-Balkaria Chegemsky District Upper Chegem volcanic caldera (Verkhnechegemskaya caldera) Lakargi Mountain A. E. Zadov data
Murmansk Oblast Khibiny Massif Kukisvumchorr Mt Pekov et al. (2004)
Yukspor Mt Hackman Valley [World of Stones 95:5-6
Sweden
Skåne County Hässleholm Häglinge Ynglingarum The Swedish Museum of Natural History ...
USA
Michigan Ontonagon Co. Mass City Algomah Mine ? Heinrich et al. (2004)
Texas Culberson County Apache Peak area Marble Canyon Mine (Texas Agricultural Aggregates Quarry) Bridge (1966)