Zincaluminite (original) (raw)

A valid IMA mineral species - grandfathered - questionable

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About ZincaluminiteHide

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Formula:

(Zn1-xAlx)(SO4)x/2(OH)2 · nH2O

(x < 0.5, n > 3x/2)

Also given as Zn6Al6(SO4)2(OH)16 · 5H2O.

Colour:

White, bluish-white, pale blue; colourless in transmitted light.

Name:

From its composition, containing ZINC plus ALUM (aluminium sulfate) and its similarity to aluminite.

A questionable mineral with undetermined X-ray powder pattern and unknown crystallography. Compare also zincowoodwardite.

Note: a SEM-EDS analysis of a typical "zincaluminite" specimen from the Genna zinc smelter slag locality, Letmathe (there are several photos of similar looking specimens on Mindat) clearly conforms to brianyoungite (Christian Auer, written comm. to Uwe Kolitsch, July 2021).

As part of the recent re-evaluation of the nomenclature of the hydrotalcite supergroup (Mills et al., 2012), zincaluminite was confirmed to be a questionable species which needs further investigation.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:4409:3

f8e7ff27-23e4-42e7-99f0-c31cb8c44e8f

IMA Classification of ZincaluminiteHide

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Approved, 'Grandfathered' (first described prior to 1959), Questionable

IMA Formula:

(Zn1-xAlx)(SO4)x/2(OH)2 · nH2O (x 3x/2)

Classification of ZincaluminiteHide

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7.DD.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra

31.2.3.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
2 : (AB)6(XO4)Zq·xH2O

25.5.9

25 : Sulphates
5 : Sulphates of Zn and Hg

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Zna IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of ZincaluminiteHide

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Pronunciation:

Play Recorded by Country
Sorry, your browser doesn't support HTML5 audio. Jolyon Ralph United Kingdom

Physical Properties of ZincaluminiteHide

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Colour:

White, bluish-white, pale blue; colourless in transmitted light.

Density:

2.26 g/cm3 (Measured)

Optical Data of ZincaluminiteHide

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RI values:

_n_ω = 1.534 _n_ε = 1.514

δ = 0.020

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

Biaaxial + at times, with a small 2V.

Chemistry of ZincaluminiteHide

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Mindat Formula:

(Zn1-xAlx)(SO4)x/2(OH)2 · nH2O

(x < 0.5, n > 3x/2)

Also given as Zn6Al6(SO4)2(OH)16 · 5H2O.

Crystallography of ZincaluminiteHide

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Morphology:

Minute crystals as very thin hexagonal plates, forming crusts; tufts.

Comment:

Hexagonal or orthorhombic

Geological EnvironmentHide

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Type Occurrence of ZincaluminiteHide

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General Appearance of Type Material:

Minute thin hexagonal crystals, in tufts and crusts

Associated Minerals at Type Locality:

Other Language Names for ZincaluminiteHide

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Relationship of Zincaluminite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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7.DD. Asagiite NiCu4(SO4)2(OH)6 · 6H2O Mon. 2/m : _P_21/b
7.DD.05 Felsőbányaite Al4(SO4)(OH)10 · 4H2O Mon. 2 : _P_21
7.DD.07 Llantenesite Cu6Al[SeO4](OH)12Cl · 3H2O Trig. 3_m_ : P_31_c
7.DD.10 Langite Cu4(SO4)(OH)6 · 2H2O Mon. m
7.DD.10 Posnjakite Cu4(SO4)(OH)6 · H2O Mon. m : P m
7.DD.10 Wroewolfeite Cu4(SO4)(OH)6 · 2H2O Mon. m : P m
7.DD.10 Gobelinite CoCu4(SO4)2(OH)6 · 6H2O Mon. 2/m : _P_21/m
7.DD.10 Fehrite MgCu4(SO4)2(OH)6 · 6H2O Mon. 2/m : _P_21/b
7.DD.15 Spangolite Cu6Al(SO4)(OH)12Cl · 3H2O Trig. 3_m_ : P_31_c
7.DD.15 Kobyashevite Cu5(SO4)2(OH)6 · 4H2O Tric. 1 : _P_1
7.DD.15 Unnamed (Dimorph of Devilline) CaCu4(SO4)2(OH)6 · 3H2O Mon. 2/m : _P_21/b
7.DD.20 Ktenasite ZnCu4(SO4)2(OH)6 · 6H2O Mon. 2/m : _P_21/b
7.DD.25 Christelite Cu2Zn3(SO4)2(OH)6 · 4H2O Tric. 1 : _P_1
7.DD.30 Campigliaite Mn2+Cu4(SO4)2(OH)6 · 4H2O Mon. 2 : _B_2
7.DD.30 Devilline CaCu4(SO4)2(OH)6 · 3H2O Mon. 2/m : _P_21/b
7.DD.30 Orthoserpierite Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O Orth. m _m_2 : P c _a_21
7.DD.30 Serpierite Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O Mon. 2/m : _B_2/b
7.DD.30 Niedermayrite CdCu4(SO4)2(OH)6 · 4H2O Mon. 2/m : _P_21/m
7.DD.30 Edwardsite Cu3Cd2(SO4)2(OH)6 · 4H2O Mon. 2/m : _P_21/b
7.DD.35 Carrboydite (Ni1-xAlx)(SO4)x/2(OH)2 · nH2O Hex.
7.DD.35 Glaucocerinite (Zn1-xAlx)(OH)2(SO4)x/2 · nH2O Hex.
7.DD.35 Honessite (Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2O Trig.
7.DD.35 Hydrohonessite (Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2O Hex.
7.DD.35 Motukoreaite Mg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O Trig. 3_m_ _(_32/m ) : R_3_m
7.DD.35 Mountkeithite [(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2O Hex.
7.DD.35 Shigaite Mn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O Trig. 3 : _R_3
7.DD.35 Wermlandite Mg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2O Trig. 3_m_ _(_32/m ) : _P_3_c_1
7.DD.35 Woodwardite Cu1-xAlx(OH)2(SO4)x/2 · nH2O Trig. 3_m_ _(_32/m ) : R_3_m
7.DD.35 Hydrowoodwardite (Cu1-xAlx)(OH)2[SO4]x/2 · nH2O Trig. 3_m_ _(_32/m ) : R_3_m
7.DD.35 Zincowoodwardite Zn1-xAlx(OH)2[SO4]x/2 · nH2O Trig.
7.DD.35 Natroglaucocerinite Zn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O Hex.
7.DD.35 Nikischerite Fe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O Trig. 3 : _R_3
7.DD.40 Isselite Cu6(SO4)(OH)10 · 5H2O Orth. m _m_2 : P m _n_21
7.DD.40 Lawsonbauerite (Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2O Mon. 2/m : _P_21/b
7.DD.40 Torreyite (Mg,Mn2+)7◻2Mn2+2Zn4(SO4)2(OH)22 · 8H2O Mon. 2/m : _P_21/b
7.DD.45 Mooreite Mg9◻2Mn2Zn4(SO4)2(OH)26 · 8H2O Mon. 2/m : _P_2/b
7.DD.45 Hodgesmithite (Cu,Zn)6Zn(SO4)2(OH)10 · 3H2O Trig. 3 : _P_3
7.DD.47 Lahnsteinite Zn4(SO4)(OH)6 · 3H2O Tric. 1 : _P_1
7.DD.50 Namuwite Zn4(SO4)(OH)6 · 4H2O Trig. 3 : _P_3
7.DD.50 Minohlite (Cu,Zn)7(SO4)2(OH)10 · 8H2O Hex.
7.DD.52 Lauraniite Cu6Cd2(SO4)2(OH)12 · 5H2O Mon. 2/m : _P_21/b
7.DD.55 Bechererite Zn7Cu(OH)13[(SiO(OH)3(SO4)] Trig. 3 : _P_3
7.DD.60 Ramsbeckite (Cu,Zn)15(SO4)4(OH)22 · 6H2O Mon. 2/m
7.DD.65 Vonbezingite Ca6Cu3(SO4)3(OH)12 · 2H2O Mon. 2/m : _P_21/b
7.DD.70 Redgillite Cu6(SO4)(OH)10 · H2O Mon. 2/m : _P_21/b
7.DD.75 Chalcoalumite CuAl4(SO4)(OH)12 · 3H2O Mon. 2 : _P_21
7.DD.75 Nickelalumite NiAl4(SO4)(OH)12(H2O)3 Mon. 2/m
7.DD.75 Kyrgyzstanite ZnAl4(SO4)(OH)12 · 3H2O Mon. 2/m
7.DD.80 Guarinoite Zn6(SO4)(OH)10 · 5H2O Hex.
7.DD.80 Schulenbergite (Cu,Zn)7(SO4)2(OH)10 · 3H2O Trig. 3
7.DD.80 Thérèsemagnanite NaCo4(SO4)(OH)6Cl · 6H2O Trig. 3 : _P_3
7.DD.80 UM1992-30-SO:CCuHZn (Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2O Trig. 3 : _P_3
7.DD.85 Montetrisaite Cu6(SO4)(OH)10 · 2H2O Orth. m _m_2 : C m _c_21

Other InformationHide

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Notes:

Soluble in acids and alkalies.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for ZincaluminiteHide

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Reference List:

**Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.**pp.579-580

Mills, S. J., Christy, A. G., Génin, J.-M. R., Kameda, T., Colombo, F. (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine, 76 (5) 1289-1336 doi:10.1180/minmag.2012.076.5.10

Localities for ZincaluminiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Germany
North Rhine-Westphalia Arnsberg Märkischer Kreis Iserlohn Letmathe Helmke quarry nature reserve Genna zinc smelter slag locality ? Verein der Hegauer Mineralienfreunde (1983) +3 other references
Cologne Aachen Stolberg Birkengang zinc smelter slag locality Neschen (n.d.)
Münsterbusch zinc smelter slag locality Neschen (n.d.)
Greece (TL)
Attica East Attica Lavreotiki Lavrion Mining District Agios Konstantinos (Kamariza) Kamariza Mines (Kamareza Mines) Hilarion Mine (TL) Bertrand and Damour (1881) +2 other references
Kamariza Dump LAPIS 24 (7/8) +1 other reference
Serpieri Mine Heymann (1982)
Mercati mines Christiana Mine No. 132 Fritz Schreiber collection
USA
Nevada Lyon County Wilson Mining District Desert Creek Ranch Jack Pot Mine (Jack Pot claim) Castor et al. (2004)