Rowleyite (original) (raw)
A valid IMA mineral species
About RowleyiteHide
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Formula:
[Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl]
Colour:
Very dark brownish green
Name:
Named for the Rowley Mine, Arizona, USA, the type locality.
New structure type. Unique combination of elements (compare another but still somewhat similar species from the same mine - davidbrownite-(NH4) - though); another ammonium-rich vanadate (or V-bearing) mineral after schindlerite, wernerbaurite, and rakovanite.
Awarded 'Mineral of the Year' by the IMA-CNMNC in 2017.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:50335:4
172c2374-f136-40f0-83c8-d3db4ad00dd2
IMA Classification of RowleyiteHide
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IMA Formula:
[Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl]
Type description reference:
Classification of RowleyiteHide
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8.DH.
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference |
|---|---|---|
| Rwl | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of RowleyiteHide
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Colour:
Very dark brownish green
Fracture:
Irregular/Uneven
Density:
2.23 g/cm3 (Measured)
Optical Data of RowleyiteHide
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Birefringence:
Isotropic minerals have no birefringence
Chemistry of RowleyiteHide
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Mindat Formula:
[Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl]
Crystallography of RowleyiteHide
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Cell Parameters:
a = 31.704(14) Å
Comment:
Spacegroup: Fd-3m
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 18.304 Å | (49) |
| 11.209 Å | (100) |
| 9.559 Å | (31) |
| 7.926 Å | (63) |
| 7.273 Å | (34) |
| 4.439 Å | (20) |
| 3.186 Å | (32) |
| 2.802 Å | (74) |
Geological EnvironmentHide
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Type Occurrence of RowleyiteHide
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General Appearance of Type Material:
Truncated octahedra up to about 50 μm in diameter.
Place of Conservation of Type Material:
Mineralogical collections of the Natural History Museum of Los Angeles County, Los Angeles, California, USA (catalogue numbers 66268, 66269, 66270, 66271, and 66272) (cotypes)
Geological Setting of Type Material:
Low-temperature, apparently post-mining
Associated Minerals at Type Locality:
Reference:
Kampf, A.R., Cooper, M.A., Nash, B.P., Cerling, T.E., Marty, J., Hummer, D.R., Celestian, A.J., Rose, T.P., Trebisky, T.J. (2017) Rowleyite, [Na(NH4,K)9Cl4][V5+,4+ 2(P,As)O8]6·n[H2O,Na,NH4,K,Cl], a new mineral with a microporous framework structure. American Mineralogist: 102: 1037-1044.
Synonyms of RowleyiteHide
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Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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| 8.DH. | Ferroberaunite | Fe2+Fe3+5(PO4)4(OH)5 · 6H2O | Mon. 2/m : _B_2/b |
|---|---|---|---|
| 8.DH. | Ammoniotinsleyite | (NH4)Al2(PO4)2(OH) · 2H2O | Mon. 2/m : _P_21/m |
| 8.DH. | Thebaite-(NH4) | (NH4)3Al(C2O4)(PO3OH)2(H2O) | Mon. 2/m : _P_21/b |
| 8.DH. | Dendoraite-(NH4) | (NH4)2NaAl(C2O4)(PO3OH)2(H2O)2 | Mon. 2/m |
| 8.DH. | Whiteite-(MnMnMn) | Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH. | Whiteite-(CaMnFe) | CaMnFe2Al2(PO4)4(OH)2 · 8H2O | Mon. 2/m |
| 8.DH. | Hochleitnerite | Mn2Ti3(PO4)4O2(H2O)2 · 14H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
| 8.DH. | Regerite | KFe6(PO4)4(OH)7(H2O)6 · 4H2O | Mon. 2/m : _P_21/b |
| 8.DH.05 | Minyulite | KAl2(PO4)2F · 4H2O | Orth. m _m_2 : P b _a_2 |
| 8.DH.10 | Leucophosphite | KFe3+2(PO4)2(OH) · 2H2O | Mon. 2/m : _P_21/b |
| 8.DH.10 | Spheniscidite | (NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2O | Mon. 2/m |
| 8.DH.10 | Tinsleyite | KAl2(PO4)2(OH) · 2H2O | Mon. |
| 8.DH.15 | Jahnsite-(CaMnFe) | {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Jahnsite-(CaMnMg) | {Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Jahnsite-(CaMnMn) | {Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Keckite | CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Rittmannite | {(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Whiteite-(CaFeMg) | {Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_21/b |
| 8.DH.15 | Whiteite-(CaMnMg) | {Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O | Mon. 2/m |
| 8.DH.15 | Whiteite-(MnFeMg) | {(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_21/b |
| 8.DH.15 | Jahnsite-(MnMnMn) | {Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_21/b |
| 8.DH.15 | Kaluginite | (Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2O | Orth. |
| 8.DH.15 | Jahnsite-(CaFeFe) | {Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. |
| 8.DH.15 | Jahnsite-(NaFeMg) | NaFe3+Mg2Fe3+2(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Jahnsite-(NaMnMg) | {(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Jahnsite-(CaMgMg) | {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O | |
| 8.DH.15 | Whiteite-(CaMnMn) | {Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Whiteite-(MnMnMg) | MnMnMg2Al2(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Jahnsite-(MnMnMg) | Mn2+Mn2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Jahnsite-(CaFeMg) | CaFe2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Jahnsite-(MnMnFe) | Mn2+Mn2+Fe2+2Fe3+2(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Whiteite-(CaMgMg) | CaMg3Al2(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Jahnsite-(MnMnZn) | Mn2+Mn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Jahnsite-(NaMnMn) | NaMn2+(Mn2+Fe3+)Σ2Fe3+2(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.15 | Jahnsite-(CaMnZn) | CaMn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O | Mon. 2/m : _P_2/b |
| 8.DH.20 | Lun'okite | (Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
| 8.DH.20 | Manganosegelerite | (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
| 8.DH.20 | Overite | CaMgAl(PO4)2(OH) · 4H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
| 8.DH.20 | Segelerite | Ca2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P c c a |
| 8.DH.20 | Wilhelmvierlingite | CaMnFe3+(PO4)2(OH) · 2H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
| 8.DH.20 | Juonniite | CaMgSc(PO4)2(OH) · 4H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
| 8.DH.25 | Calcioferrite | Ca2Fe3+2(PO4)3(OH) · 7H2O | Mon. 2/m : _B_2/b |
| 8.DH.25 | Kingsmountite | Ca3MnFeAl4(PO4)6(OH)4 · 12H2O | Tric. 1 : _P_1 |
| 8.DH.25 | Montgomeryite | Ca4MgAl4(PO4)6(OH)4 · 12H2O | Mon. 2 : _B_2 |
| 8.DH.25 | Zodacite | Ca4Mn2+Fe3+4(PO4)6(OH)4 · 12H2O | Mon. |
| 8.DH.25 | Fanfaniite | Ca4MnAl4(PO4)6(OH)4 · 12H2O | Mon. 2/m : _B_2/b |
| 8.DH.30 | Arseniosiderite | Ca2Fe3+3(AsO4)3O2 · 3H2O | Mon. 2/m : _B_2/b |
| 8.DH.30 | Kolfanite | Ca2Fe3+3O2(AsO4)3 · 2H2O | Mon. |
| 8.DH.30 | Mitridatite | Ca2Fe3+3(PO4)3O2 · 3H2O | Mon. 2/m : _B_2/b |
| 8.DH.30 | Pararobertsite | Ca2Mn3+3(PO4)3O2 · 3H2O | Mon. 2/m : _P_21/b |
| 8.DH.30 | Robertsite | Ca2Mn3+3(PO4)3O2 · 3H2O | Mon. m : B b |
| 8.DH.30 | Sailaufite | (Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2O | Mon. m : B m |
| 8.DH.35 | Mantienneite | KMg2Al2Ti(PO4)4(OH)3 · 15H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
| 8.DH.35 | Paulkerrite | K(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2O | Mon. m |
| 8.DH.35 | Benyacarite | (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
| 8.DH.35 | Hydroxylbenyacarite | (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 · 4H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
| 8.DH.35 | Macraeite | K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 · 4H2O | Mon. 2/m : _P_21/b |
| 8.DH.35 | Sperlingite | (H2O)K(Mn2+Fe3+)(Al2Ti)(PO4)4[O(OH)] [(H2O)9(OH)] · 4H2O | Mon. 2/m : _P_21/b |
| 8.DH.40 | Xanthoxenite | Ca4Fe3+2(PO4)4(OH)2 · 3H2O | Tric. 1 : _P_1 |
| 8.DH.45 | Mahnertite | NaCu3(AsO4)2Cl · 5H2O | Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m m m |
| 8.DH.50 | Andyrobertsite | KCdCu5(AsO4)4(H2AsO4) · 2H2O | Mon. 2/m : _P_21/m |
| 8.DH.50 | Calcioandyrobertsite | KCaCu5(AsO4)4(H2AsO4) · 2H2O | Mon. 2/m : _P_21/m |
| 8.DH.55 | Englishite | K3Na2Ca10Al15(PO4)21(OH)7 · 26H2O | Mon. 2/m |
| 8.DH.60 | Bouazzerite | Bi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2O | Mon. 2/m |
| 8.DH.65 | Galliskiite | Ca4Al2(PO4)2F8 · 5H2O | Tric. 1 : _P_1 |
| 8.DH.70 | Joteite | Ca2CuAl(AsO4)[AsO3(OH)]2(OH)2 · 5H2O | Tric. 1 : _P_1 |
| 8.DH.75 | Kampelite | Ba6Mg3Sc8(PO4)12(OH)6 · 7H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a |
| 8.DH.80 | Kapundaite | NaCaFe4(PO4)4(OH)3 · 5H2O | Tric. 1 : _P_1 |
| 8.DH.85 | Vaniniite | Ca2Mn2+3Mn3+2O2(AsO4)4 · 2H2O | Mon. 2/m : _P_21/b |
Other InformationHide
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Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for RowleyiteHide
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References for RowleyiteHide
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Reference List:
Localities for RowleyiteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the 
symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. 
- Good crystals or important locality for species. 
- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
| USA (TL) | |
|---|---|
| Arizona Maricopa County Painted Rock Mountains Painted Rock Mining District Theba ⓘ Rowley Mine (TL) | Mineralogical Magazine: 80: 1135–1144 +1 other reference |
| ⓘ 125 foot level | Kampf et al. (2019) |