Ammoniotinsleyite (original) (raw)

A valid IMA mineral species

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About AmmoniotinsleyiteHide

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Formula:

(NH4)Al2(PO4)2(OH) · 2H2O

Colour:

Pink to pale violet

Crystal System:

Monoclinic

Name:

Ammoniotinsleyite is named as the ammonium analogue of tinsleyite.

Unique combination of elements. The NH4 analogue of tinsleyite. The Al analogue of spheniscidite. Described from a guano deposit.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:54627:0

3784e816-9e60-4e71-9737-cc4a5cc769fb

IMA Classification of AmmoniotinsleyiteHide

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Classification of AmmoniotinsleyiteHide

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8.DH.

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Atin IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AmmoniotinsleyiteHide

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Transparency:

Transparent, Translucent

Colour:

Pink to pale violet

Density:

2.42(2) g/cm3 (Measured) 2.451 g/cm3 (Calculated)

Optical Data of AmmoniotinsleyiteHide

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RI values:

_n_α = 1.557(2) _n_β = 1.559 _n_γ = 1.563(2)

δ = 0.006

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of AmmoniotinsleyiteHide

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Mindat Formula:

(NH4)Al2(PO4)2(OH) · 2H2O

Crystallography of AmmoniotinsleyiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 9.5871(1) Å, b = 9.6089(1) Å, c = 9.6467(1) Å
β = 103.4461(8)°

Ratio:

a:b:c = 0.998 : 1 : 1.004

Unit Cell V:

864.31 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
7.56 Å (23)
6.71 Å (79)
5.947 Å (100)
4.676 Å (36)
3.032 Å (28)
2.958 Å (25)
2.635 Å (29)

Geological EnvironmentHide

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Type Occurrence of AmmoniotinsleyiteHide

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General Appearance of Type Material:

Globular aggregates, up to 3 mm across, with individual crystals ca. 10 – 15 microns in diameter.

Place of Conservation of Type Material:

Collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5510/1.

Geological Setting of Type Material:

Associated Minerals at Type Locality:

Synonyms of AmmoniotinsleyiteHide

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Relationship of Ammoniotinsleyite to other SpeciesHide

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Other Members of this group:

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8.DH. Ferroberaunite Fe2+Fe3+5(PO4)4(OH)5 · 6H2O Mon. 2/m : _B_2/b
8.DH. Rowleyite [Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl] Iso.
8.DH. Thebaite-(NH4) (NH4)3Al(C2O4)(PO3OH)2(H2O) Mon. 2/m : _P_21/b
8.DH. Dendoraite-(NH4) (NH4)2NaAl(C2O4)(PO3OH)2(H2O)2 Mon. 2/m
8.DH. Whiteite-(MnMnMn) Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH. Whiteite-(CaMnFe) CaMnFe2Al2(PO4)4(OH)2 · 8H2O Mon. 2/m
8.DH. Hochleitnerite Mn2Ti3(PO4)4O2(H2O)2 · 14H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH. Regerite KFe6(PO4)4(OH)7(H2O)6 · 4H2O Mon. 2/m : _P_21/b
8.DH.05 Minyulite KAl2(PO4)2F · 4H2O Orth. m _m_2 : P b _a_2
8.DH.10 Leucophosphite KFe3+2(PO4)2(OH) · 2H2O Mon. 2/m : _P_21/b
8.DH.10 Spheniscidite (NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2O Mon. 2/m
8.DH.10 Tinsleyite KAl2(PO4)2(OH) · 2H2O Mon.
8.DH.15 Jahnsite-(CaMnFe) {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(CaMnMg) {Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(CaMnMn) {Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Keckite CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O Mon. 2/m : _P_2/b
8.DH.15 Rittmannite {(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Whiteite-(CaFeMg) {Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DH.15 Whiteite-(CaMnMg) {Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O Mon. 2/m
8.DH.15 Whiteite-(MnFeMg) {(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DH.15 Jahnsite-(MnMnMn) {Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_21/b
8.DH.15 Kaluginite (Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2O Orth.
8.DH.15 Jahnsite-(CaFeFe) {Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon.
8.DH.15 Jahnsite-(NaFeMg) NaFe3+Mg2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(NaMnMg) {(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(CaMgMg) {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O
8.DH.15 Whiteite-(CaMnMn) {Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Whiteite-(MnMnMg) MnMnMg2Al2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(MnMnMg) Mn2+Mn2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(CaFeMg) CaFe2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(MnMnFe) Mn2+Mn2+Fe2+2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Whiteite-(CaMgMg) CaMg3Al2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(MnMnZn) Mn2+Mn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(NaMnMn) NaMn2+(Mn2+Fe3+)Σ2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.15 Jahnsite-(CaMnZn) CaMn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O Mon. 2/m : _P_2/b
8.DH.20 Lun'okite (Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.20 Manganosegelerite (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.20 Overite CaMgAl(PO4)2(OH) · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.20 Segelerite Ca2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P c c a
8.DH.20 Wilhelmvierlingite CaMnFe3+(PO4)2(OH) · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.20 Juonniite CaMgSc(PO4)2(OH) · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.25 Calcioferrite Ca2Fe3+2(PO4)3(OH) · 7H2O Mon. 2/m : _B_2/b
8.DH.25 Kingsmountite Ca3MnFeAl4(PO4)6(OH)4 · 12H2O Tric. 1 : _P_1
8.DH.25 Montgomeryite Ca4MgAl4(PO4)6(OH)4 · 12H2O Mon. 2 : _B_2
8.DH.25 Zodacite Ca4Mn2+Fe3+4(PO4)6(OH)4 · 12H2O Mon.
8.DH.25 Fanfaniite Ca4MnAl4(PO4)6(OH)4 · 12H2O Mon. 2/m : _B_2/b
8.DH.30 Arseniosiderite Ca2Fe3+3(AsO4)3O2 · 3H2O Mon. 2/m : _B_2/b
8.DH.30 Kolfanite Ca2Fe3+3O2(AsO4)3 · 2H2O Mon.
8.DH.30 Mitridatite Ca2Fe3+3(PO4)3O2 · 3H2O Mon. 2/m : _B_2/b
8.DH.30 Pararobertsite Ca2Mn3+3(PO4)3O2 · 3H2O Mon. 2/m : _P_21/b
8.DH.30 Robertsite Ca2Mn3+3(PO4)3O2 · 3H2O Mon. m : B b
8.DH.30 Sailaufite (Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2O Mon. m : B m
8.DH.35 Mantienneite KMg2Al2Ti(PO4)4(OH)3 · 15H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.35 Paulkerrite K(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2O Mon. m
8.DH.35 Benyacarite (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.35 Hydroxylbenyacarite (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.DH.35 Macraeite K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 · 4H2O Mon. 2/m : _P_21/b
8.DH.35 Sperlingite (H2O)K(Mn2+Fe3+)(Al2Ti)(PO4)4[O(OH)] [(H2O)9(OH)] · 4H2O Mon. 2/m : _P_21/b
8.DH.40 Xanthoxenite Ca4Fe3+2(PO4)4(OH)2 · 3H2O Tric. 1 : _P_1
8.DH.45 Mahnertite NaCu3(AsO4)2Cl · 5H2O Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_4/m m m
8.DH.50 Andyrobertsite KCdCu5(AsO4)4(H2AsO4) · 2H2O Mon. 2/m : _P_21/m
8.DH.50 Calcioandyrobertsite KCaCu5(AsO4)4(H2AsO4) · 2H2O Mon. 2/m : _P_21/m
8.DH.55 Englishite K3Na2Ca10Al15(PO4)21(OH)7 · 26H2O Mon. 2/m
8.DH.60 Bouazzerite Bi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2O Mon. 2/m
8.DH.65 Galliskiite Ca4Al2(PO4)2F8 · 5H2O Tric. 1 : _P_1
8.DH.70 Joteite Ca2CuAl(AsO4)[AsO3(OH)]2(OH)2 · 5H2O Tric. 1 : _P_1
8.DH.75 Kampelite Ba6Mg3Sc8(PO4)12(OH)6 · 7H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.DH.80 Kapundaite NaCaFe4(PO4)4(OH)3 · 5H2O Tric. 1 : _P_1
8.DH.85 Vaniniite Ca2Mn2+3Mn3+2O2(AsO4)4 · 2H2O Mon. 2/m : _P_21/b

Other InformationHide

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IR Spectrum:

confirms the presence of NH4+, PO43–, and H2O

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for AmmoniotinsleyiteHide

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Reference List:

Chukanov, Nikita V., Möhn, Gerhard, Pekov, Igor V., Zubkova, Natalia V., Ksenofontov, Dmitry A., Belakovskiy, Dmitry I., Vozchikova, Svetlana A., Britvin, Sergey N., Desor, Joy (2020) Ammoniotinsleyite, (NH4)Al2(PO4)2(OH)⋅2H2O, a new mineral species from the guano deposit at Pabellón de Pica, Iquique Province, Chile. Mineralogical Magazine, 84 (5) 705-711 doi:10.1180/mgm.2020.45

Localities for AmmoniotinsleyiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Chile (TL)
Tarapacá Iquique Province Iquique Chanabaya Pabellón de Pica (TL) Chukanov et al. (2020)
Punta de Lobos - (2020, April 17th)