Kuzelite (original) (raw)

A valid IMA mineral species

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About KuzeliteHide

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Formula:

Ca4Al2(OH)12[SO4] · 6H2O

Name:

For Prof. Hans Jürgen Kuzel (1932–1997), University of Erlangen, Germany, who first synthesized the compound.

This page provides mineralogical data about Kuzelite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:7147:1

086aeeff-35c9-4a9c-b2cb-ede8871ff7ae

IMA Classification of KuzeliteHide

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IMA Formula:

Ca4Al2(OH)12(SO4) · 6H2O

Type description reference:

Classification of KuzeliteHide

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4.FL.15

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
L : Hydroxides with H2O +- (OH); sheets of edge-sharing octahedra

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Kuz IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KuzeliteHide

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Fracture:

Irregular/Uneven

Density:

1.99(5) g/cm3 (Measured) 2.014 g/cm3 (Calculated)

Optical Data of KuzeliteHide

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RI values:

_n_ω = 1.504(5) _n_ε = 1.485(5)

δ = 0.019

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of KuzeliteHide

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Mindat Formula:

Ca4Al2(OH)12[SO4] · 6H2O

Crystallography of KuzeliteHide

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Cell Parameters:

a = 5.76(1) Å, c = 53.66(2) Å

Unit Cell V:

1,541.79 ų (Calculated from Unit Cell)

Morphology:

Platy hexagonal to rhomboidal crystals, to 2 mm

Comment:

Point Group: 3 or 3.; Space Group: R3 or R3.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0014757 Kuzelite Allmann R (1977) Refinement of the hybrid layer structure [Ca2Al(OH)6]+*[1/2SO4*3H2O]- Neues Jahrbuch fur Mineralogie, Monatshefte 1977 136-144 1977 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.972 Å (100)
4.476 Å (70)
2.362 Å (40)
2.190 Å (40)
2.071 Å (35)
4.004 Å (30)
2.882 Å (30)

Geological EnvironmentHide

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Type Occurrence of KuzeliteHide

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Place of Conservation of Type Material:

Martin Luther University, Halle, Germany.

Geological Setting of Type Material:

carbonaceous xenoliths in basalt

Associated Minerals at Type Locality:

Reference:

Pöllmann, H., Witzke, T. & Kohler, H. (1997): Kuzelite, [Ca4Al2(OH)12][(SO4).6H2O], a new mineral from Maroldsweisach/Bavaria, Germany. Neues Jahrbuch für Mineralogie, Monatshefte (1997): 423-432.

Synonyms of KuzeliteHide

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Other Language Names for KuzeliteHide

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Relationship of Kuzelite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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4.FL. Trébeurdenite Fe2+2Fe3+4O2(OH)10CO3 · 3H2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL. Mariakrite [Ca4Al2(OH)12(H2O)4][Fe2S4] Tric. 1 : _P_1
4.FL.05 Woodallite Mg6Cr2(OH)16Cl2 · 4H2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL.05 Iowaite Mg6Fe3+2(OH)16Cl2 · 4H2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL.05 Jamborite Ni2+1-xCo3+x(OH)2-x(SO4)x · nH2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL.05 Meixnerite Mg6Al2(OH)16(OH)2 · 4H2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL.05 Muskoxite Mg7Fe4O13 · 10H2O Trig. 3_m_ _(_32/m )
4.FL.05 Fougèrite Fe2+4Fe3+2(OH)12[CO3] · 3H2O Trig. 3_m_ _(_32/m ) : R_3_m
4.FL.05 Mössbauerite Fe3+6O4(OH)8[CO3] · 3H2O Trig. 3
4.FL.05 Dritsite Li2Al4(OH)12Cl2 · 3H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m c m
4.FL.10 Hydrocalumite Ca4Al2(OH)12(Cl,CO3,OH)2 · 4H2O Mon. 2 : _P_21
4.FL.20 Aurorite Mn2+Mn4+3O7 · 3H2O Trig. 3 : _R_3
4.FL.20 Chalcophanite ZnMn4+3O7 · 3H2O Trig. 3 : _R_3
4.FL.20 Ernienickelite NiMn3O7 · 3H2O Trig. 3 : _R_3
4.FL.20 Jianshuiite (Mg,Mn,Ca)Mn3O7 · 3H2O Trig. 3 : _R_3
4.FL.25 Woodruffite Zn2+x/2(Mn4+1-xMn3+x)O2 · yH2O Mon. 2/m : _B_2/m
4.FL.30 Asbolane (Ni,Co)2-xMn4+(O,OH)4 · nH2O Hex.
4.FL.30 va Lampadite Cu, Mn, O, H
4.FL.35 Buserite Na4Mn14O27 · 21H2O
4.FL.40 Ranciéite (Ca,Mn2+)0.2(Mn4+,Mn3+)O2 · 0.6H2O Trig. 3 : _P_3
4.FL.40 Takanelite (Mn,Ca)Mn4O9 · H2O Hex.
4.FL.45 Birnessite (Na,Ca)0.5(Mn4+,Mn3+)2O4 · 1.5H2O Mon. 2/m : _B_2/m
4.FL.55 Cianciulliite Mn(Mg,Mn)2Zn2(OH)10 · 2-4H2O Mon. 2/m : _B_2/m
4.FL.60 Jensenite Cu3[TeO6] · 2H2O Mon. 2/m : _P_21/m
4.FL.65 Leisingite Cu2MgTe6+O6 · 6H2O Trig. 3 : _P_3
4.FL.70 Akdalaite Al10O14(OH)2 Hex.
4.FL.75 Cafetite CaTi2O5 · H2O Mon. 2/m : _P_21/b
4.FL.80 Mourite UMo5O12(OH)10 Mon.
4.FL.85 Deloryite Cu4(UO2)(MoO4)2(OH)6 Mon. 2/m : _B_2/m
4.FL.90 Lagalyite Ca2xMn1-xO2 · 1.5-2H2O Mon.
4.FL.95 Tunnerite (of Cornu)
4.FL.100 Carbocalumite Ca4Al2(OH)12(CO3) · 6H2O Trig. 3_m_ _(_32/m ) : R_3_c
4.FL.100 Mampsisite Ca4Al2(CO3)(OH)12 · 5H2O Tric.

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for KuzeliteHide

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Reference List:

Mesbah, A., François, M., Cau-Dit-Coumes, C., Frizon, F., Filinchuk, Y., Leroux, F., Ravaux, J., Renaudin, G. (2011): Crystal structure of Kuzel's salt 3CaO•Al2O3•1/2CaSO4•1/2CaCl2•11H 2O determined by synchrotron powder diffraction. Cement and Concrete Research 41, 504-509.

Mills, S. J., Christy, A. G., Génin, J.-M. R., Kameda, T., Colombo, F. (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine, 76 (5) 1289-1336 doi:10.1180/minmag.2012.076.5.10

Localities for KuzeliteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Germany (TL)
Bavaria Lower Franconia Haßberge District Maroldsweisach Zeilberg Quarry (TL) Pöllmann et al. (1997)
Rhineland-Palatinate Mayen-Koblenz Mayen Seekante Blass
Mendig Bell Rothenberg Quarry Blass
Vordereifel Ettringen Caspar quarry Marko Burkhardt