Cahnite (original) (raw)

A valid IMA mineral species - grandfathered

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About CahniteHide

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Formula:

Ca2[B(OH)4](AsO4)

Colour:

Colorless to white, golden brown

Lustre:

Vitreous, Sub-Vitreous, Resinous

Crystal System:

Tetragonal

Name:

Named in 1921 by Charles Palache, but not described until 1927 by Charles Palache and Lawson Henry Bauer in honor of Mr. Lazard Cahn [May 23, 1865 Saint Joseph, Missouri, USA - May 22, 1940 Colorado Springs, Colorado, USA] morphological crystallographer, mineral collector and mineral dealer, who first recognized the material.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:851:2

06c3f907-587f-4421-bbb9-824bb0c3f732

IMA Classification of CahniteHide

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Approved, 'Grandfathered' (first described prior to 1959)

IMA Formula:

Ca2B(AsO4)(OH)4

Type description reference:

Classification of CahniteHide

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6.AC.70

6 : BORATES
A : Monoborates
C : B(O,OH)4, without and with additional anions; 1(T), 1(T)+OH, etc

43.4.4.1

43 : COMPOUND PHOSPHATES, ETC.
4 : Anhydrous Compound Phosphates, etc·, Containing Hydroxyl or Halogen

10.2.2

10 : Borates with other anions
2 : Borates with phosphate or arsenate

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Cah IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of CahniteHide

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Pronunciation:

Play Recorded by Country
Sorry, your browser doesn't support HTML5 audio. Jolyon Ralph United Kingdom

Physical Properties of CahniteHide

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Vitreous, Sub-Vitreous, Resinous

Transparency:

Transparent, Translucent

Colour:

Colorless to white, golden brown

Comment:

Colourless in transmitted light.

Fracture:

Irregular/Uneven, Sub-Conchoidal

Density:

3.156 g/cm3 (Measured) 3.22 g/cm3 (Calculated)

Optical Data of CahniteHide

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RI values:

_n_ω = 1.655 - 1.662 _n_ε = 1.656 - 1.663

δ = 0.001

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

Strong; exhibits anomalous interference colors.

Pleochroism:

Non-pleochroic

Comments:

Exhibits abnormal interference colours that make the mineral easily recognizable under the microscope.

Chemistry of CahniteHide

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Mindat Formula:

Ca2[B(OH)4](AsO4)

Crystallography of CahniteHide

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Crystal System:

Tetragonal

Class (H-M):

4 - Disphenoidal

Cell Parameters:

a = 7.09 Å, c = 6.19 Å

Unit Cell V:

311.16 ų (Calculated from Unit Cell)

Morphology:

Single untwinned crystals rare, pseudo-tetrahedral habit.

Twinning:

Almost universal on {110}, with the individuals interpenetrating symmetrically. When the sphenoid faces are well-developed, the twins have a characteristic cruciform appearance.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0000097 Cahnite Prewitt C T, Buerger M J (1961) The crystal structure of cahnite, Ca2BAsO4(OH)4 American Mineralogist 46 1077-1085 1961 Franklin, New Jersey, USA 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
5.02 Å (20)
4.67 Å (20)
3.56 Å (100)
2.833 Å (19)
2.640 Å (48)
2.336 Å (17)
1.818 Å (52)

Geological EnvironmentHide

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Geological Setting:

cavities in boron-bearing and arsenate-bearing vugs in basalt, boron-bearing and arsenate-bearing hydrothermal veins

Type Occurrence of CahniteHide

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General Appearance of Type Material:

Tiny white glassy crystals, characteristically twinned with generally etched crystal faces.

Place of Conservation of Type Material:

Harvard University, Cambridge, Massachusetts, USA, numbers 90010, 90015, 90016, 90019.
National Museum of Natural History, Washington, D.C., USA, number 95568.

Geological Setting of Type Material:

Cavities in manganaxinite veinlets traversing Precambrian metamorphosed Zn-Mn-Fe orebody.

Associated Minerals at Type Locality:

Reference:

Palache, C., Bauer, L.H. (1927) Cahnite, a new boro-arsenate of calcium from Franklin, New Jersey. American Mineralogist: 12: 149-153.

Synonyms of CahniteHide

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Other Language Names for CahniteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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6.AC.05 Sinhalite MgAl(BO4) Orth. m m m _(_2/_m_2/_m_2/m )
6.AC.10 Pseudosinhalite Mg2Al3(BO3)2(OH)O3 Mon. 2/m : _P_21/b
6.AC.15 Béhierite (Ta5+,Nb5+)(BO4) Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a m d
6.AC.15 Schiavinatoite (Nb,Ta)(BO4) Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a m d
6.AC.20 Frolovite Ca[B(OH)4]2 Tric. 1 : _P_1
6.AC.25 Hexahydroborite Ca[B(OH)4]2 · 2H2O or CaB2O4 · 6H2O Mon. 2/m : _B_2/b
6.AC.30 Henmilite Ca2Cu[B(OH)4]2(OH)4 Tric. 1 : _P_1
6.AC.35 Bandylite Cu[B(OH)4]Cl Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n m m
6.AC.40 Teepleite Na2[B(OH)4]Cl Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_4/n m m
6.AC.45 Moydite-(Y) Y[B(OH)4](CO3) Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
6.AC.50 Carboborite Ca2Mg[B(OH)4]2(CO3)2 · 4H2O Mon. 2/m
6.AC.55 Sulfoborite Mg3[B(OH)4]2(SO4)(OH,F)2 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
6.AC.60 Lüneburgite Mg3[B2(OH)6](PO4)2 · 6H2O Tric. 1 : _P_1
6.AC.65 Seamanite Mn2+3[B(OH)4](PO4)(OH)2 Orth. m m m _(_2/_m_2/_m_2/m )

Fluorescence of CahniteHide

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Fluoresces moderate creamy white in SW UV (Franklin).

Other InformationHide

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Notes:

Readily soluble in dilute HCl.

Fuses quietly at about 3 yielding the green flame of boron. In the closed tube, heated alone it yields water and becomes opaque but does not fuse; heated with potassium carbonate and carbon it yields an arsenic mirror.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for CahniteHide

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Reference List:

**Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.**pp.386-387

Shiraga, Kanako, Kusachi, Isao, Kobayashi, Shoichi, Takechi, Yasushi (2002) Cahnite from Fuka, Okayama Prefecture, Japan. Journal of Mineralogical and Petrological Sciences, 97 (2) 70-73 doi:10.2465/jmps.97.70

Localities for CahniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Brazil
Goiás Catalão Catalão I carbonatite complex Orris et al. (2002)
Chile
Antofagasta El Loa Province El Tatio geothermal field TESIS PARA OPTAR AL GRADO DE MAGÍSTER ...
China
Inner Mongolia Chifeng City (Ulanhad League; Chifeng Prefecture) Hexigten Banner (Keshiketeng Co.) Huanggang Fe-Sn deposit No. 3 Mine ? Ottens et al. (2012)
Shijiangshan mine (Dashishan mine) Ottens et al. (2014)
Italy
Lazio Metropolitan City of Rome Capital Rome Capo di Bove Embrey (1960)
Valleranello Vallerano Quarries Stoppani et al. (1982) +2 other references
Japan
Okayama Prefecture Takahashi City Bitchū Fuka Fuka mine Shiraga et al. (2002)
Mexico
San Luis Potosí Charcas Municipality Charcas Peter Megaw collection
Sonora Magdalena Municipality Unimin (Tinaja Del Oso) deposit stratigraphy et al. (4) +1 other reference
Namibia
Otjozondjupa Region Otavi Constituency Kombat Kombat Mine Bode Verlag GmbH et al. (in English) +2 other references
Norway
Agder Arendal Øyestad Klodeborg Mines Bugge (1951) +1 other reference
Russia
Buryatia Yeravninsky District Ozernoe ore cluster Solongo B deposit Doklady Acad. Nauk SSSR 166 (1966)
Turkey
Kütahya Province Emet District Emet Borate deposit Emet Eti Bor Mine ("Killik Mine"; "Kilik Mine"; Espey mine) American Mineralogist +7 other references
Hisarcik Mine American Mineralogist +4 other references
USA (TL)
New Jersey Sussex County Franklin Franklin Mine (TL) Palache et al. (1927) +3 other references