Calkinsite-(Ce) (original) (raw)

A valid IMA mineral species - grandfathered

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About Calkinsite-(Ce)Hide

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Formula:

(Ce,La)2(CO3)3 · 4H2O

Crystal System:

Orthorhombic

Name:

Named calkinsite by W.T. Pecora and J.H. Kerr in honor of Frank Cathcart Calkins (7 June 1878, East Rockport, Ohio, USA – 1974), geologist with the U.S. Geological Survey. The suffix "-(Ce)" designates the dominant rare earth element in the composition and was added to the name in 1987.

This page provides mineralogical data about Calkinsite-(Ce).

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:867:3

b8a13ecd-8d98-4027-a283-6a1b7645629a

IMA Classification of Calkinsite-(Ce)Hide

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Approved, 'Grandfathered' (first described prior to 1959)

IMA Formula:

Ce2(CO3)3 · 4H2O

Type description reference:

Classification of Calkinsite-(Ce)Hide

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5.CC.25

5 : CARBONATES (NITRATES)
C : Carbonates without additional anions, with H2O
C : With rare earth elements (REE)

15.4.1.1

15 : HYDRATED NORMAL CARBONATES
4 : AmBn(XO3)p·xH2O, with (m+n):p < 1:1

11.8.1

11 : Carbonates
8 : Carbonates of the rare earths

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Clk-Ce IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Calkinsite-(Ce)Hide

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Cleavage:

Perfect
{010} perfect, {101} distinct

Density:

3.28(1) g/cm3 (Measured)

Optical Data of Calkinsite-(Ce)Hide

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RI values:

_n_α = 1.569 _n_β = 1.657 _n_γ = 1.686

2V:

Measured: 54° , Calculated: 56°

δ = 0.117

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

r > v or r < v

Optical Extinction:

X = b; Y = c; Z = a.

Comments:

X:b (yellow), Y:c (colorless), Z:a (colorless)

Chemistry of Calkinsite-(Ce)Hide

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Mindat Formula:

(Ce,La)2(CO3)3 · 4H2O

Crystallography of Calkinsite-(Ce)Hide

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Crystal System:

Orthorhombic

Cell Parameters:

a = 9.57(2) Å, b = 12.65(8) Å, c = 8.94(2) Å

Ratio:

a:b:c = 0.757 : 1 : 0.707

Unit Cell V:

1,082.28 ų (Calculated from Unit Cell)

Comment:

space group P21 221 or D32. class P2/m 2/m 2/m

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
6.54 Å (100b)
3.27 Å (50)
4.78 Å (40)
4.49 Å (40)
2.931 Å (30b)
2.128 Å (30)
2.115 Å (30)

Geological EnvironmentHide

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Type Occurrence of Calkinsite-(Ce)Hide

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General Appearance of Type Material:

platy habit parallel to {010 }

Place of Conservation of Type Material:

U. S. National Museum, Washington, D. C.

Geological Setting of Type Material:

occur in shonkinite, mafic monzonite, and syenite

Associated Minerals at Type Locality:

Reference:

Pecora, W.T., Kerr, J.H. (1953) Burbankite and calkinsite, two new carbonate minerals from Montana. American Mineralogist: 38: 1169-1183.

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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5.CC. Alicewilsonite-(YCe) Na2Sr2YCe(CO3)6 · 3H2O Tric. 1 : _P_1
5.CC. Yuchuanite-(Y) Y2(CO3)3 · H2O Tric. 1 : _P_1
5.CC. Bainbridgeite-(NdCe) Na2Ba2NdCe(CO3)6 · 3H2O Tric. 1 : _P_1
5.CC.05 Donnayite-(Y) NaCaSr3Y(CO3)6 · 3H2O Tric. 1 : _P_1
5.CC.05 Ewaldite Ba(Na,Ca,Y,Ce,K)(CO3)2 · 2.6H2O Hex. 6_m_ m : P_63_m c
5.CC.05 Mckelveyite-(Nd) NaCaBa3Nd(CO3)6 · 3H2O Mon. m : B b
5.CC.05 Mckelveyite-(Y) NaCaBa3Y(CO3)6 · 3H2O Tric. 1 : _P_1
5.CC.05 Weloganite Na2Sr3Zr(CO3)6 · 3H2O Tric. 1 : _P_1
5.CC.05 Unnamed (MSH UK-37A) Sr3NaCaY(CO3)6 · 3H2O Hex. 6_m_ m : P_63_m c
5.CC.05 UM1992-05-CO:CaCeLaNaSr (Sr,Na,Y,REE,Ca,Ba)2(CO3)2 · H2O Trig. 3_m_ : R_3_m
5.CC.05 Mckelveyite Group A3B3(CO3)6 · 3H2O
5.CC.05 Bainbridgeite-(YCe) Na2Ba2YCe(CO3)6 · 3H2O Tric. 1 : _P_1
5.CC.05 Alicewilsonite-(YLa) Na2Sr2YLa(CO3)6 · 3H2O Tric. 1 : _P_1
5.CC.10 Tengerite-(Y) Y2(CO3)3 · 2-3H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
5.CC.15 Kimuraite-(Y) Ca(Y,Nd)2(CO3)4 · 6H2O Orth.
5.CC.15 Lokkaite-(Y) Ca(Y,Gd,Nd,Dy)4(CO3)7 · 9H2O Orth.
5.CC.15 Hizenite-(Y) Ca2Y6(CO3)11 · 14H2O Orth.
5.CC.20 Shomiokite-(Y) Na3Y[CO3]3 · 3H2O Orth. m _m_2
5.CC.25 Lanthanite-(Ce) (Ce,La,Nd)2(CO3)3 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m )
5.CC.25 Lanthanite-(La) (La,Ce)2(CO3)3 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m )
5.CC.25 Lanthanite-(Nd) (Nd,La)2(CO3)3 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m )
5.CC.30 Adamsite-(Y) NaY[CO3]2 · 6H2O Tric. 1 : _P_1
5.CC.35 Decrespignyite-(Y) Cu(Y,REE)4(CO3)4(OH)5Cl · 2H2O Mon.
5.CC.40 Galgenbergite-(Ce) Ca(Ce,La,Nd)2(CO3)4 · H2O Tric. 1 : _P_1
5.CC.45 Lecoqite-(Y) Na3Y(CO3)3 · 6H2O Hex. 6 : _P_63

Other InformationHide

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Notes:

Effervesces strongly in cold dilute (1:5) HCl.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for Calkinsite-(Ce)Hide

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Localities for Calkinsite-(Ce)Hide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Afghanistan
Helmand Reg District Khanneshin complex Central Khanneshin deposit Yeremenko et al. (1982) +2 other references
Czech Republic
Liberec Region North Bohemian Uranium District Scharm +7 other references
Olomouc Region Olomouc District Domašov nad Bystřicí (Domstadtl) Domašov nad Bystřicí quarry (Domstadtl quarry) ? Zimák et al. (2005)
Plzeň Region Klatovy District Malý Bor Vrbík W deposit Černý P.
Italy
Tuscany Grosseto Province Montieri Boccheggiano mines Bazzoni C. et al.
Japan
Kagawa Prefecture Kanayama Minakawa (1985)
Russia
Murmansk Oblast Northern Karelia Vuoriyarvi alkaline-ultrabasic massif Mineralogical Society of America - ...
USA (TL)
Montana Hill County Bearpaw Mountains Big Sandy Creek Vermiculite prospect No. 6 (TL) Pecora et al. (1953)
Rocky Boy Stock Occurrence Belovitskaya et al. (2004)