Ferro-holmquistite (original) (raw)

A valid IMA mineral species

Formula:

◻{Li2}{Fe2+3Al2}(Si8O22)(OH)2

The holmquistite group comprises orthorhombic amphiboles in the lithium amphibole subgroup.

Holmquistite is defined with Fe2+Mg and Al>Fe3+ in the C position.
The type material is Mg-rich.

Colour:

Black, dark-violet, light sky-blue.

Specific Gravity:

3.145 (Calculated)

Crystal System:

Orthorhombic

Name:

For its relationship to holmquistite.

Ferro-holmquistite forms a series with holmquistite. Like holmquistite, ferro-holmquistite is almost exclusively formed in the reaction zone between Li-pegmatites and their host rock, predominantly as a metasomatic alteration product of pre-existing amphiboles. Quéméneur and Lagache(1994) show a significant variation of Fe content in holmquistite from different localities and they suggest that the holmquistite minerals retain their Fe/Mg ratio from the original amphibole.

Ferro-holmquistite is under-reported in the literature, as both ferro-holmquistite and holmquistite are often referred to as holmquistite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:8957:5

56c3a52e-3cc9-4c57-8689-f9322c4283ab

IMA Classification of Ferro-holmquistiteHide

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IMA status notes:

Redefined by the IMA

IMA Formula:

◻Li2(Fe2+3Al2)Si8O22(OH)2

Approval history:

Redefined IMA 2012 s.p.

Classification of Ferro-holmquistiteHide

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9.DD.05

9 : SILICATES (Germanates)
D : Inosilicates
D : Inosilicates with 2-periodic double chains, Si4O11; Orthoamphiboles

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Fhlm IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Ferro-holmquistiteHide

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Colour:

Black, dark-violet, light sky-blue.

Streak:

Light bluish-violet. White with a sky-blue tinge (?)

Density:

3.145 g/cm3 (Calculated)

Optical Data of Ferro-holmquistiteHide

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RI values:

_n_α = 1.628 _n_β = 1.646 _n_γ = 1.651

δ = 0.023

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

c = X, with the optic axial plane coinciding with (010).

Comments:

α = colorless, β = pale violet-blue, γ = blue to deep violet.

Chemistry of Ferro-holmquistiteHide

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Mindat Formula:

◻{Li2}{Fe2+3Al2}(Si8O22)(OH)2

The holmquistite group comprises orthorhombic amphiboles in the lithium amphibole subgroup.

Holmquistite is defined with Fe2+Mg and Al>Fe3+ in the C position.
The type material is Mg-rich.

Crystallography of Ferro-holmquistiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 18.287 Å, b = 17.68 Å, c = 5.278 Å

Ratio:

a:b:c = 1.034 : 1 : 0.299

Morphology:

Prismatic crystals.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0003812 Ferro-holmquistite Camara F, Oberti R (2005) The crystal-chemistry of holmquistites: Ferroholmquistite from Greenbushes (Western Australia) and hints for compositional constraints in B-Li amphiboles American Mineralogist 90 1167-1176 2005 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.1128 Å (100)
3.0047 Å (10)
1.5818 Å (7)
2.7095 Å (5)

Comments:

Greenbushes Mine, Western Australia, Australia. The data are from Camara and Oberti (2005).

Geological EnvironmentHide

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Type Occurrence of Ferro-holmquistiteHide

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General Appearance of Type Material:

Elongated black to bluish-violet prismatic crystals, typically in the range 0.2–0.5 mm.

Place of Conservation of Type Material:

Museum of the Dipartimento di Scienze della Terra, Universita di Pavia #2004-01

Empirical Formula of Type Material:

A(K0.01Na0.01)B(Li1.88Mg0.08Na0.03Fe2+ 0.01) C(Al1.89Fe2+ 1.70Mg1.39Mn2+ 0.02) TSi8.00O22(OH1.97F0.03)

Chemical Analysis of Type Material:

SiO2 59.37 %
TiO2 0.03 %
Al2O3 11.86 %
Cr2O3 0 %
MgO 7.32 %
CaO 0.03 %
MnO 0.18 %
Fe2O3 0 %
FeO 15.14 %
ZnO 0.02 %
Na2O 0.17 %
K2O 0.03 %
F 0.07 %
Cl 0.01 %
Li2O 3.46 %
H2O 2.19 %
Total: 99.88 %

Geological Setting of Type Material:

Lithium-rich granite pegmatite.

Associated Minerals at Type Locality:

Synonyms of Ferro-holmquistiteHide

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Other Language Names for Ferro-holmquistiteHide

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Relationship of Ferro-holmquistite to other SpeciesHide

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Other Members of this group:

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for Ferro-holmquistiteHide

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Reference List:

Hawthorne, F. C., Oberti, R., Harlow, G. E., Maresch, W. V., Martin, R. F., Schumacher, J. C., Welch, M. D. (2012) Nomenclature of the amphibole supergroup. American Mineralogist, 97 (11) 2031-2048 doi:10.2138/am.2012.4276

Localities for Ferro-holmquistiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia (TL)
Western Australia Bridgetown-Greenbushes Shire Greenbushes Tinfield Greenbushes Mine (TL) Camara (2005)
Brazil
Minas Gerais Nazareno Volta Grande mine (Mibra mine) Quéméneur et al. (1994)