1,1'-Ferrocenediisocyanate (original) (raw)
1,1'-Ferrocenediisocyanate (1,1'-diisocyanatoferrocene) is the organoiron compound with the formula Fe(C5H4NCO)2. It is the simplest diisocyanate derivative of ferrocene. It can be synthesized by the Curtius rearrangement of the diacyl azide, using several protocols starting from 1,1'-ferrocenedicarboxylic acid. The compound is useful as an intermediate in the synthesis of 1,1'-diaminoferrocene by hydrolysis of the isocyanates. Various poly(siloxane–urethane) crosslinked polymers can be formed by reaction with siloxane-diols. These compounds are of interest as electrochemically active polymers that might have good mechanical properties at low temperature.
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| dbo:abstract | 1,1'-Ferrocenediisocyanate (1,1'-diisocyanatoferrocene) is the organoiron compound with the formula Fe(C5H4NCO)2. It is the simplest diisocyanate derivative of ferrocene. It can be synthesized by the Curtius rearrangement of the diacyl azide, using several protocols starting from 1,1'-ferrocenedicarboxylic acid. The compound is useful as an intermediate in the synthesis of 1,1'-diaminoferrocene by hydrolysis of the isocyanates. Various poly(siloxane–urethane) crosslinked polymers can be formed by reaction with siloxane-diols. These compounds are of interest as electrochemically active polymers that might have good mechanical properties at low temperature. (en) |
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| dbo:wikiPageWikiLink | dbr:Electrochemical dbc:Cyclopentadienyl_complexes dbc:Ferrocenes dbc:Isocyanates dbr:Crosslink dbr:Acyl_azide dbr:Siloxane dbr:Curtius_rearrangement dbr:Ferrocene dbr:Carbamate dbr:Diol dbr:Isocyanate dbr:Hydrolysis dbr:Polymer dbr:Mechanical_properties dbr:Organoiron_compound dbr:1,1'-diaminoferrocene dbr:1,1'-ferrocenedicarboxylic_acid |
| dbp:imagefile | Fe2.svg (en) |
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| dcterms:subject | dbc:Cyclopentadienyl_complexes dbc:Ferrocenes dbc:Isocyanates |
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| rdfs:comment | 1,1'-Ferrocenediisocyanate (1,1'-diisocyanatoferrocene) is the organoiron compound with the formula Fe(C5H4NCO)2. It is the simplest diisocyanate derivative of ferrocene. It can be synthesized by the Curtius rearrangement of the diacyl azide, using several protocols starting from 1,1'-ferrocenedicarboxylic acid. The compound is useful as an intermediate in the synthesis of 1,1'-diaminoferrocene by hydrolysis of the isocyanates. Various poly(siloxane–urethane) crosslinked polymers can be formed by reaction with siloxane-diols. These compounds are of interest as electrochemically active polymers that might have good mechanical properties at low temperature. (en) |
| rdfs:label | 1,1'-Ferrocenediisocyanate (en) |
| owl:sameAs | wikidata:1,1'-Ferrocenediisocyanate https://global.dbpedia.org/id/GiHRv |
| prov:wasDerivedFrom | wikipedia-en:1,1'-Ferrocenediisocyanate?oldid=1117099541&ns=0 |
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| is dbo:wikiPageWikiLink of | dbr:1,1'-Diaminoferrocene dbr:1,1'-Ferrocenedicarboxylic_acid dbr:1,1'-Diisocyanatoferrocene dbr:1,1'-Ferrocene_diisocyanate dbr:1,1'-diisocyanatoferrocene dbr:1,1'-ferrocene_diisocyanate dbr:1,1'-ferrocenediisocyanate |
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