| dbo:abstract |
Decamethyldizincocene is an organozinc compound with the formula [Zn2(η5–C5Me5)2]. It is the first and an unusual example of a compound with a Zn-Zn bond. Decamethyldizincocene is a colorless crystalline solid that burns spontaneously in the presence of oxygen and reacts with water. It is stable at room temperature and especially soluble in diethyl ether, benzene, pentane, or tetrahydrofuran. (en) Le décaméthyldizincocène est un composé organozincique de formule chimique [(η5-C5(CH3)5)Zn]2. C'est le premier exemple connu d'un composé présentant une liaison Zn–Zn. Il s'agit d'un solide cristallisé incolore pyrophorique et hygroscopique. Il est stable à température ambiante et particulièrement soluble dans l'éther diéthylique, le benzène, le pentane et le tétrahydrofurane (THF). (fr) |
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dbr:Cadmium dbr:Calcium_hydride dbr:Potassium dbr:Potassium_hydride dbr:Pyridine dbr:Electron_density dbr:Molecular_orbital dbr:Benzene dbr:Pentane dbr:Periodic_table dbc:Organozinc_compounds dbr:Mass_spectrometry dbr:Reaction_intermediate dbr:NMR_spectroscopy dbc:Pentamethylcyclopentadienyl_complexes dbr:Chemical_reaction dbr:Homonuclear dbr:Lewis_base dbr:Steric_hindrance dbr:Zinc dbr:Halide dbc:Metallocenes dbr:Product_(chemistry) dbr:Redox dbr:Tetrahydrofuran dbr:Eclipsed_conformation dbr:X-ray_diffraction dbr:Diethyl_ether dbr:Diethylzinc dbr:Diphenylzinc dbr:Bond_length dbr:Sodium dbr:Mercury_(element) dbr:Organozinc_compound dbr:Radical_(chemistry) dbr:Reagent dbr:Reducing_agent dbr:Methyl_group dbr:Sigma_bond dbr:Fragment_Molecular_Orbital dbr:Heteronuclear dbr:Substituent dbr:Bond_dissociation_energy dbr:Hydrocarbyl dbr:Crystalline_solid dbr:File:DecamethyldizincoceneScheme.svg dbr:File:Structure_of_organometallic_zinc_complex_(C5Me5)Zn(Me).png |
| dbp:imagefilel |
Decamethyldizincocene.png (en) |
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Decamethyldizincocene_xtal.png (en) |
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| dct:subject |
dbc:Organozinc_compounds dbc:Pentamethylcyclopentadienyl_complexes dbc:Metallocenes |
| gold:hypernym |
dbr:Compound |
| rdf:type |
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| rdfs:comment |
Decamethyldizincocene is an organozinc compound with the formula [Zn2(η5–C5Me5)2]. It is the first and an unusual example of a compound with a Zn-Zn bond. Decamethyldizincocene is a colorless crystalline solid that burns spontaneously in the presence of oxygen and reacts with water. It is stable at room temperature and especially soluble in diethyl ether, benzene, pentane, or tetrahydrofuran. (en) Le décaméthyldizincocène est un composé organozincique de formule chimique [(η5-C5(CH3)5)Zn]2. C'est le premier exemple connu d'un composé présentant une liaison Zn–Zn. Il s'agit d'un solide cristallisé incolore pyrophorique et hygroscopique. Il est stable à température ambiante et particulièrement soluble dans l'éther diéthylique, le benzène, le pentane et le tétrahydrofurane (THF). (fr) |
| rdfs:label |
Decamethyldizincocene (en) Décaméthyldizincocène (fr) |
| owl:sameAs |
freebase:Decamethyldizincocene yago-res:Decamethyldizincocene wikidata:Decamethyldizincocene dbpedia-fa:Decamethyldizincocene dbpedia-fr:Decamethyldizincocene https://global.dbpedia.org/id/4ipB9 |
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