Tutton's salt (original) (raw)
Garam Tutton adalah sebuah keluarga garam dengan rumus M2M'(SO4)2(H2O)6 (sulfates) or M2M'(SeO4)2(H2O)6 (selenat). Material-material tersebut merupakan , yang artinya mereka terdiri dari dua kation berbeda, M+ dan M'2+ yang dikristalkan dalam kisi ionik reguler yang sama. Ion sodium atau lithium berukuran terlalu kecil. Kation divalen dapat menjadi magnesium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc atau cadmium. Selain sulfat dan selenat, anion divalen dapat menjadi (CrO42−), (BeF42−), (HPO42−) atau (PO3F2−). Seluruh garam Tutton membentuk kristal monoklinik dengan P21/a.
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| dbo:abstract | Garam Tutton adalah sebuah keluarga garam dengan rumus M2M'(SO4)2(H2O)6 (sulfates) or M2M'(SeO4)2(H2O)6 (selenat). Material-material tersebut merupakan , yang artinya mereka terdiri dari dua kation berbeda, M+ dan M'2+ yang dikristalkan dalam kisi ionik reguler yang sama. Ion sodium atau lithium berukuran terlalu kecil. Kation divalen dapat menjadi magnesium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc atau cadmium. Selain sulfat dan selenat, anion divalen dapat menjadi (CrO42−), (BeF42−), (HPO42−) atau (PO3F2−). Seluruh garam Tutton membentuk kristal monoklinik dengan P21/a. (in) Tutton's salts are a family of salts with the formula M2M'(SO4)2(H2O)6 (sulfates) or M2M'(SeO4)2(H2O)6 (selenates). These materials are double salts, which means that they contain two different cations, M+ and M'2+ crystallized in the same regular ionic lattice. The univalent cation can be potassium, rubidium, cesium, ammonium (NH4), deuterated ammonium (ND4) or thallium. Sodium or lithium ions are too small. The divalent cation can be magnesium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc or cadmium. In addition to sulfate and selenate, the divalent anion can be chromate (CrO42−), tetrafluoroberyllate (BeF42−), hydrogenphosphate (HPO42−) or monofluorophosphate (PO3F2−). Tutton's salts crystallize in the monoclinic space group P21/a. The robustness is the result of the complementary hydrogen-bonding between the tetrahedral anions and cations as well their interactions with the metal aquo complex [M(H2O)6]2+. (en) I sali di Tutton sono una famiglia di sali di formula MI2MII(SO4)2(H2O)6 (solfati) o MI2MII(SeO4)2(H2O)6 (selenati). Questi composti sono sali doppi, sono cioè costituiti da due differenti cationi, M+ e M2+ cristallizzati nello stesso reticolo cristallino. Il catione M+ può essere potassio, rubidio, cesio, ammonio (NH4+), ammonio deuterato (ND4+) o tallio. Gli ioni sodio e litio sono troppo piccoli per dare composti di questo tipo. Il catione M2+ può essere magnesio, vanadio, cromo, manganese, ferro, cobalto, nichel, rame, zinco o cadmio. Gli anioni solfato e selenato sono i più comuni, ma esistono esempi di analoghi composti contenenti cromato (CrO42−), (BeF42−), idrogenofosfato (HPO42−) o (PO3F2−). I sali di Tutton cristallizzano nel sistema monoclino, gruppo spaziale P21/a. I sali di Tutton prendono il nome dal chimico Alfred Tutton (1864-1938), che studiò la cristallografia di 91 di questi composti, pubblicando circa 50 articoli tra il 1890 e il 1929. Questi sali sono stati importanti in passato come standard analitici e spettroscopici, dato che è possibile ottenerli molto puri. (it) Соли Тутто́на (шени́ты) — двойные комплексные соли общей формулы M2I MII (SO4)2·6H2O. В качестве металла MI могут выступать Cs, K, NH4, Rb, Tl (катионы лития и натрия слишком малы). В качестве металла MII могут выступать Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, V, Zn. Название «шениты» произошло от минерала шенита, K2Mg(SO4)2·6H2O. Соли Туттона кристаллизуются в моноклинной решётке с пространственной группой P21/a. (ru) Солі Туттона (шеніту) — подвійні комплексні солі загальної формули M2I MII (SO4) 2·6H2O. Як метал MI можуть виступати Cs, K, NH4, Rb, Tl, як метал MII — Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, V, Zn. Назва «шеніту» відбулося від мінералу ,. (uk) |
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| rdfs:comment | Garam Tutton adalah sebuah keluarga garam dengan rumus M2M'(SO4)2(H2O)6 (sulfates) or M2M'(SeO4)2(H2O)6 (selenat). Material-material tersebut merupakan , yang artinya mereka terdiri dari dua kation berbeda, M+ dan M'2+ yang dikristalkan dalam kisi ionik reguler yang sama. Ion sodium atau lithium berukuran terlalu kecil. Kation divalen dapat menjadi magnesium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc atau cadmium. Selain sulfat dan selenat, anion divalen dapat menjadi (CrO42−), (BeF42−), (HPO42−) atau (PO3F2−). Seluruh garam Tutton membentuk kristal monoklinik dengan P21/a. (in) Соли Тутто́на (шени́ты) — двойные комплексные соли общей формулы M2I MII (SO4)2·6H2O. В качестве металла MI могут выступать Cs, K, NH4, Rb, Tl (катионы лития и натрия слишком малы). В качестве металла MII могут выступать Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, V, Zn. Название «шениты» произошло от минерала шенита, K2Mg(SO4)2·6H2O. Соли Туттона кристаллизуются в моноклинной решётке с пространственной группой P21/a. (ru) Солі Туттона (шеніту) — подвійні комплексні солі загальної формули M2I MII (SO4) 2·6H2O. Як метал MI можуть виступати Cs, K, NH4, Rb, Tl, як метал MII — Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, V, Zn. Назва «шеніту» відбулося від мінералу ,. (uk) Tutton's salts are a family of salts with the formula M2M'(SO4)2(H2O)6 (sulfates) or M2M'(SeO4)2(H2O)6 (selenates). These materials are double salts, which means that they contain two different cations, M+ and M'2+ crystallized in the same regular ionic lattice. The univalent cation can be potassium, rubidium, cesium, ammonium (NH4), deuterated ammonium (ND4) or thallium. Sodium or lithium ions are too small. The divalent cation can be magnesium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc or cadmium. In addition to sulfate and selenate, the divalent anion can be chromate (CrO42−), tetrafluoroberyllate (BeF42−), hydrogenphosphate (HPO42−) or monofluorophosphate (PO3F2−). Tutton's salts crystallize in the monoclinic space group P21/a. The robustness is the result of th (en) I sali di Tutton sono una famiglia di sali di formula MI2MII(SO4)2(H2O)6 (solfati) o MI2MII(SeO4)2(H2O)6 (selenati). Questi composti sono sali doppi, sono cioè costituiti da due differenti cationi, M+ e M2+ cristallizzati nello stesso reticolo cristallino. Il catione M+ può essere potassio, rubidio, cesio, ammonio (NH4+), ammonio deuterato (ND4+) o tallio. Gli ioni sodio e litio sono troppo piccoli per dare composti di questo tipo. Il catione M2+ può essere magnesio, vanadio, cromo, manganese, ferro, cobalto, nichel, rame, zinco o cadmio. Gli anioni solfato e selenato sono i più comuni, ma esistono esempi di analoghi composti contenenti cromato (CrO42−), (BeF42−), idrogenofosfato (HPO42−) o (PO3F2−). I sali di Tutton cristallizzano nel sistema monoclino, gruppo spaziale P21/a. (it) |
| rdfs:label | Garam Tutton (in) Sali di Tutton (it) Соли Туттона (ru) Tutton's salt (en) Солі Туттона (uk) |
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