Polydicyclopentadiene (original) (raw)
Polydicyclopentadiene (PDCPD) is a polymer material which is formed through ring-opening metathesis polymerization (ROMP) of dicyclopentadiene (DCPD). PDCPD exhibits a high degree of crosslinking, which grants it properties such as high impact resistance, good chemical corrosion resistance, and high heat deflection temperature. PDCPD is frequently used in the automotive industry to make body panels, bumpers, and other components for trucks, buses, tractors, and construction equipment. Additionally, PDCPD is being investigated for use in the creation of porous materials for tissue engineering or gas storage applications, as well as for use in self-healing polymers.
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| dbo:abstract | Polydicyclopentadiene (PDCPD) is a polymer material which is formed through ring-opening metathesis polymerization (ROMP) of dicyclopentadiene (DCPD). PDCPD exhibits a high degree of crosslinking, which grants it properties such as high impact resistance, good chemical corrosion resistance, and high heat deflection temperature. PDCPD is frequently used in the automotive industry to make body panels, bumpers, and other components for trucks, buses, tractors, and construction equipment. Additionally, PDCPD is being investigated for use in the creation of porous materials for tissue engineering or gas storage applications, as well as for use in self-healing polymers. Polymerization can been achieved through the use of different transition metal catalysts like ruthenium, molybdenum, tungsten, and titanium, as well as under metal-free conditions through photoredox catalysis. The exact structure of the PDCPD polymer depends upon the reaction conditions used for the polymerization. While the crosslinked polymer may arise from the metathesis of both alkenes in the parent monomer, it has been suggested that many polymerization conditions result in only the strained norbornene ring in the monomer undergoing olefin metathesis while subsequent crosslinking steps result from thermal condensation of the remaining olefins in the linear polymer. Several new catalytic systems for the synthesis of linear PDCPD have been run successfully using tungsten hexachloride, tungsten(VI) oxytetrachloride, and organosilicon compounds. (en) |
| dbo:alternativeName | Poly(dicyclopentadiene); PDCPD (en) |
| dbo:thumbnail | wiki-commons:Special:FilePath/Polydicyclopentadiene.svg?width=300 |
| dbo:wikiPageExternalLink | http://www.matweb.com/search/datasheettext.aspx%3Fmatid=78164 http://www.pslc.ws/macrog/pdcpd.htm |
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| dbo:wikiPageRevisionID | 1119903954 (xsd:integer) |
| dbo:wikiPageWikiLink | dbr:Nitrogen dbc:Polymers dbr:Chemical_element dbr:Gasket dbr:Corrosion dbr:Cross-link dbr:Stoichiometric dbr:Polyurethane dbr:Materials_science dbr:Automotive_industry dbr:Three-dimensional_space dbr:Tungsten(VI)_oxytetrachloride dbr:Tungsten_hexachloride dbr:Heat_deflection_temperature dbr:Ring-opening_metathesis_polymerisation dbr:Aluminium dbr:Norbornene dbr:Truck dbr:Reaction_injection_molding dbr:Hydraulic_press dbr:Tractor dbr:Dicyclopentadiene dbr:Bus dbr:Plastic_recycling dbr:Polymer dbr:Olefin_metathesis dbr:Catalysis dbr:Self-healing_material dbr:Porous_medium dbr:Sheet_moulding_compound dbr:Photoredox_catalysis dbr:Tissue_engineering dbr:Thermoplastics dbr:Electrolyzer dbr:Construction_equipment dbr:Chlor-alkali dbr:Impact_resistance dbr:Thermoset_plastic |
| dbp:imagecaption | Linear form (en) |
| dbp:imagefile | Polydicyclopentadiene.svg (en) |
| dbp:imagesize | 200 (xsd:integer) |
| dbp:othernames | Poly; PDCPD (en) |
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| dct:subject | dbc:Polymers |
| gold:hypernym | dbr:Polymer |
| rdf:type | owl:Thing dul:ChemicalObject dbo:ChemicalSubstance wikidata:Q11173 yago:Abstraction100002137 yago:Chemical114806838 yago:Compound114818238 yago:Material114580897 yago:Matter100020827 yago:Part113809207 yago:PhysicalEntity100001930 yago:Polymer114994328 yago:Relation100031921 dbo:ChemicalCompound yago:Substance100019613 yago:WikicatPolymers |
| rdfs:comment | Polydicyclopentadiene (PDCPD) is a polymer material which is formed through ring-opening metathesis polymerization (ROMP) of dicyclopentadiene (DCPD). PDCPD exhibits a high degree of crosslinking, which grants it properties such as high impact resistance, good chemical corrosion resistance, and high heat deflection temperature. PDCPD is frequently used in the automotive industry to make body panels, bumpers, and other components for trucks, buses, tractors, and construction equipment. Additionally, PDCPD is being investigated for use in the creation of porous materials for tissue engineering or gas storage applications, as well as for use in self-healing polymers. (en) |
| rdfs:label | Polydicyclopentadiene (en) |
| owl:sameAs | freebase:Polydicyclopentadiene yago-res:Polydicyclopentadiene wikidata:Polydicyclopentadiene https://global.dbpedia.org/id/4tzxP |
| prov:wasDerivedFrom | wikipedia-en:Polydicyclopentadiene?oldid=1119903954&ns=0 |
| foaf:depiction | wiki-commons:Special:FilePath/Polydicyclopentadiene.svg |
| foaf:isPrimaryTopicOf | wikipedia-en:Polydicyclopentadiene |
| is dbo:wikiPageRedirects of | dbr:PDCPD |
| is dbo:wikiPageWikiLink of | dbr:Ring-opening_metathesis_polymerisation dbr:Dicyclopentadiene dbr:PDCPD |
| is foaf:primaryTopic of | wikipedia-en:Polydicyclopentadiene |
