Manjaka, Sahatany Valley, Ibity, Antsirabe II District, Vakinankaratra, Madagascar (original) (raw)

Albite

Formula: Na(AlSi3O8)

Béhierite (TL)

Formula: (Ta5+,Nb5+)(BO4)

Type Locality:

Habit: Octahedral crystals

Colour: Grayish-pink

Beryl

Formula: Be3Al2(Si6O18)

Bismuth

Formula: Bi

Bismutite ?

Formula: (BiO)2CO3

Description: As alteration product of bismuth

Bityite

Formula: CaLiAl2(AlBeSi2O10)(OH)2

Habit: xls up to 1mm in diameter and 2 mm in length

Colour: colorless

Description: Found in a cavity in microcline

Boralsilite

Formula: Al16B6O30(Si2O7)

References:

Novák, Milan, Cempírek, Jan, Gadas, Petr, Škoda, Radek, Vašinová Galiová, Michaela, Pezzotta, Federico, Groat, Lee A. (2015) Boralsilite and Li, Be-bearing "Boron Mullite" Al8B2Si2O19, Breakdown products of spodumene from the Manjaka pegmatite, Sahatany valley, Madagascar. The Canadian Mineralogist, 53 (2) 357-374 doi:10.3749/canmin.1400092

Calcite

Formula: CaCO3

Chrysoberyl

Formula: BeAl2O4

References:

Novák, Milan, Cempírek, Jan, Gadas, Petr, Škoda, Radek, Vašinová Galiová, Michaela, Pezzotta, Federico, Groat, Lee A. (2015) Boralsilite and Li, Be-bearing "Boron Mullite" Al8B2Si2O19, Breakdown products of spodumene from the Manjaka pegmatite, Sahatany valley, Madagascar. The Canadian Mineralogist, 53 (2) 357-374 doi:10.3749/canmin.1400092

Columbite-(Mn)

Formula: Mn2+Nb2O6

Description: A. Lacroix (1912,1922) described columbite-(Mn)(Manganocolumbite) from Manjaka,using only visual means for analysis. Later von Knorring and Fadipe (1981)analyzes columbite-(Mn) from Manjaka and find that it is a tungstenian variety. Also as partially alteration of behierite (Pezzotta 2007)

Danburite

Formula: CaB2Si2O8

References:

Novák, Milan, Cempírek, Jan, Gadas, Petr, Škoda, Radek, Vašinová Galiová, Michaela, Pezzotta, Federico, Groat, Lee A. (2015) Boralsilite and Li, Be-bearing "Boron Mullite" Al8B2Si2O19, Breakdown products of spodumene from the Manjaka pegmatite, Sahatany valley, Madagascar. The Canadian Mineralogist, 53 (2) 357-374 doi:10.3749/canmin.1400092

Darrellhenryite

Formula: Na(Al2Li)Al6(Si6O18)(BO3)3(OH)3O

References:

Gadas, P., Novák, M., Vašinová Galiová, M., Pezzotta, F. (2023) Chemical composition of tourmalines from the Manjaka pegmatite and its exocontact, Sahatany Valley, Madagascar. Journal of Geosciences, 68 (3) 185-202 doi:10.3190/jgeosci.374

Diopside

Formula: CaMgSi2O6

Description: Found in the exocontact zones of the pegmatite

References:

Gadas, P., Novák, M., Vašinová Galiová, M., Pezzotta, F. (2023) Chemical composition of tourmalines from the Manjaka pegmatite and its exocontact, Sahatany Valley, Madagascar. Journal of Geosciences, 68 (3) 185-202 doi:10.3190/jgeosci.374

Dolomite

Formula: CaMg(CO3)2

References:

Gadas, P., Novák, M., Vašinová Galiová, M., Pezzotta, F. (2023) Chemical composition of tourmalines from the Manjaka pegmatite and its exocontact, Sahatany Valley, Madagascar. Journal of Geosciences, 68 (3) 185-202 doi:10.3190/jgeosci.374

'Dravite-Uvite Series'

References:

Novák, Milan, Cempírek, Jan, Gadas, Petr, Škoda, Radek, Vašinová Galiová, Michaela, Pezzotta, Federico, Groat, Lee A. (2015) Boralsilite and Li, Be-bearing "Boron Mullite" Al8B2Si2O19, Breakdown products of spodumene from the Manjaka pegmatite, Sahatany valley, Madagascar. The Canadian Mineralogist, 53 (2) 357-374 doi:10.3749/canmin.1400092

Elbaite

Formula: Na(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)

Description: Described as a Mn-rich elbaite (elbaite manganésière) by Ranorosoa (1986)

Fluorapatite

Formula: Ca5(PO4)3F

Habit: Small, mostly mm-sized hexagonal prismes

Colour: prusse blue

Description: Called "apatite manganiésifère" or "manganapatite" in litterature.

Fluorapatite var. Manganese-bearing Fluorapatite

Formula: (Ca,Mn2+)5(PO4)3(F,Cl,OH) or Ca5([P,Mn5+]O4)3(F,Cl,OH)

Habit: Small, mostly mm-sized hexagonal prismes

Colour: prusse blue

Description: Called "apatite manganiésifère" or "manganapatite" in litterature.

Fluor-dravite

Formula: NaMg3Al6(Si6O18)(BO3)3(OH)3F

References:

Gadas, P., Novák, M., Vašinová Galiová, M., Pezzotta, F. (2023) Chemical composition of tourmalines from the Manjaka pegmatite and its exocontact, Sahatany Valley, Madagascar. Journal of Geosciences, 68 (3) 185-202 doi:10.3190/jgeosci.374

Fluor-elbaite

Formula: Na(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3F

References:

Gadas, P., Novák, M., Vašinová Galiová, M., Pezzotta, F. (2023) Chemical composition of tourmalines from the Manjaka pegmatite and its exocontact, Sahatany Valley, Madagascar. Journal of Geosciences, 68 (3) 185-202 doi:10.3190/jgeosci.374

Fluor-uvite

Formula: CaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3F

References:

Gadas, P., Novák, M., Vašinová Galiová, M., Pezzotta, F. (2023) Chemical composition of tourmalines from the Manjaka pegmatite and its exocontact, Sahatany Valley, Madagascar. Journal of Geosciences, 68 (3) 185-202 doi:10.3190/jgeosci.374

'Ixiolite-(Mn2+)-Ixiolite-(Fe2+) Series'

Description: (Mn1,63Ta1,10W0,79Nb0,50)4,02 O8 (Ranorosoa 1986)

'Ixiolite-(Mn2+)-Ixiolite-(Fe2+) Series var. Wolframoixiolite'

Formula: (Nb,W,Ta,Fe,Mn)2O4

Description: (Mn1,63Ta1,10W0,79Nb0,50)4,02 O8 (Ranorosoa 1986)

'K Feldspar'

References:

Novák, Milan, Cempírek, Jan, Gadas, Petr, Škoda, Radek, Vašinová Galiová, Michaela, Pezzotta, Federico, Groat, Lee A. (2015) Boralsilite and Li, Be-bearing "Boron Mullite" Al8B2Si2O19, Breakdown products of spodumene from the Manjaka pegmatite, Sahatany valley, Madagascar. The Canadian Mineralogist, 53 (2) 357-374 doi:10.3749/canmin.1400092

Lithiophilite

Formula: LiMn2+PO4

Description: Pink, translucent, prismatic crystals (rare) or masses in albite. Often with an aureole of manganese oxides.

Londonite

Formula: (Cs,K,Rb)Al4Be4(B,Be)12O28

'Londonite-Rhodizite Series'

References:

Novák, Milan, Cempírek, Jan, Gadas, Petr, Škoda, Radek, Vašinová Galiová, Michaela, Pezzotta, Federico, Groat, Lee A. (2015) Boralsilite and Li, Be-bearing "Boron Mullite" Al8B2Si2O19, Breakdown products of spodumene from the Manjaka pegmatite, Sahatany valley, Madagascar. The Canadian Mineralogist, 53 (2) 357-374 doi:10.3749/canmin.1400092

Magnesio-lucchesiite

Formula: CaMg3Al6(Si6O18)(BO3)3(OH)3O

References:

Gadas, P., Novák, M., Vašinová Galiová, M., Pezzotta, F. (2023) Chemical composition of tourmalines from the Manjaka pegmatite and its exocontact, Sahatany Valley, Madagascar. Journal of Geosciences, 68 (3) 185-202 doi:10.3190/jgeosci.374

Magnetite

Formula: Fe2+Fe3+2O4

Manandonite

Formula: Li2Al4(Si2AlB)O10(OH)8

Microcline

Formula: K(AlSi3O8)

'Microlite Group'

Formula: A2-mTa2X6-wZ-n

Description: As partially alteration of behierite

Monazite-(Ce)

Formula: Ce(PO4)

References:

Novák, Milan, Cempírek, Jan, Gadas, Petr, Škoda, Radek, Vašinová Galiová, Michaela, Pezzotta, Federico, Groat, Lee A. (2015) Boralsilite and Li, Be-bearing "Boron Mullite" Al8B2Si2O19, Breakdown products of spodumene from the Manjaka pegmatite, Sahatany valley, Madagascar. The Canadian Mineralogist, 53 (2) 357-374 doi:10.3749/canmin.1400092

Opal

Formula: SiO2 · nH2O

Opal var. Opal-AN

Formula: SiO2 · nH2O

Oxy-dravite

Formula: Na(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3O

References:

Gadas, P., Novák, M., Vašinová Galiová, M., Pezzotta, F. (2023) Chemical composition of tourmalines from the Manjaka pegmatite and its exocontact, Sahatany Valley, Madagascar. Journal of Geosciences, 68 (3) 185-202 doi:10.3190/jgeosci.374

Phenakite

Formula: Be2SiO4

References:

Novák, Milan, Cempírek, Jan, Gadas, Petr, Škoda, Radek, Vašinová Galiová, Michaela, Pezzotta, Federico, Groat, Lee A. (2015) Boralsilite and Li, Be-bearing "Boron Mullite" Al8B2Si2O19, Breakdown products of spodumene from the Manjaka pegmatite, Sahatany valley, Madagascar. The Canadian Mineralogist, 53 (2) 357-374 doi:10.3749/canmin.1400092

Phlogopite

Formula: KMg3(AlSi3O10)(OH)2

Description: A Di+Tr+Tur±Kfs±Qz±Cs-rich phlogopite in variable proportions are found in small bands in the exocontact of the pegmatite with the host rock.

References:

Novák, M.,Gadas, P.,Galiová Vašínová, M. & Pezzotta, F. (2013): Compositional variations in Cs,Li,Mg-rich beryl from exocontact of the complex Manjaka pegmatite, Sahatany Valley, Madagascar. GAG-MAC Winnipeg 2013, SY2-P3, p. 152-153

Novák, Milan, Cempírek, Jan, Gadas, Petr, Škoda, Radek, Vašinová Galiová, Michaela, Pezzotta, Federico, Groat, Lee A. (2015) Boralsilite and Li, Be-bearing "Boron Mullite" Al8B2Si2O19, Breakdown products of spodumene from the Manjaka pegmatite, Sahatany valley, Madagascar. The Canadian Mineralogist, 53 (2) 357-374 doi:10.3749/canmin.1400092

Pollucite

Formula: (Cs,Na)2(Al2Si4O12) · 2H2O

Description: corroded

'Polylithionite-Trilithionite Series'

'Psilomelane'

Description: alteration of spessartine and perhaps also of columbite-(Mn) (Behier 1953)

'Pyrochlore Supergroup'

Formula: A2-mD2X6-wZ1-n

'Pyrochlore Supergroup var. Betafite (of Hogarth 1977)'

Formula: (Ca,Na,U)2(Ti, Nb,Ta)2O6Z(OH)

Description: Behier (1953) describes small brown strongly refrigent crystals as "blomstrandite". Visual examination of the specimens collected by J. Behier and labelled blomstrandite, Manjaka in the Musée National de la Géologie in Ampandrianomby in Antananarivo, Madagascar is very similar to what later has been proved to be a hafnian zircon (per. com. Knut Edvard Larsen, 1999)

Quartz

Formula: SiO2

Rhodizite

Formula: (K,Cs)Al4Be4(B,Be)12O28

Habit: Up to 2 cm large well developed dodecahedral crystals modified by tetrahedron {111} faces

Colour: Pale to honey yellow; colorless. Transparent to translucent

Description: Occurs in saccharoidal albite close to the contact with the hosting marble, and in miarolitic cavities.

Rhodochrosite

Formula: MnCO3

Description: Anhedral grains of pink lithiophilite may locally been replaced by rhodochrosite.

References:

Novák, Milan, Cempírek, Jan, Gadas, Petr, Škoda, Radek, Vašinová Galiová, Michaela, Pezzotta, Federico, Groat, Lee A. (2015) Boralsilite and Li, Be-bearing "Boron Mullite" Al8B2Si2O19, Breakdown products of spodumene from the Manjaka pegmatite, Sahatany valley, Madagascar. The Canadian Mineralogist, 53 (2) 357-374 doi:10.3749/canmin.1400092

Rutile

Formula: TiO2

Description: Found in small bands at the exocontact of the pegmatite with the host rock.

References:

Novák, M.,Gadas, P.,Galiová Vašínová, M. & Pezzotta, F. (2013): Compositional variations in Cs,Li,Mg-rich beryl from exocontact of the complex Manjaka pegmatite, Sahatany Valley, Madagascar. GAG-MAC Winnipeg 2013, SY2-P3, p. 152-153

Rutile var. Niobium-bearing Rutile

Formula: (Ti,Nb)O2

Description: Found in small bands at the exocontact of the pegmatite with the host rock.

References:

Novák, M.,Gadas, P.,Galiová Vašínová, M. & Pezzotta, F. (2013): Compositional variations in Cs,Li,Mg-rich beryl from exocontact of the complex Manjaka pegmatite, Sahatany Valley, Madagascar. GAG-MAC Winnipeg 2013, SY2-P3, p. 152-153

'Scapolite'

Description: Found in small bands at the exocontact of the pegmatite with the host rock.

References:

Novák, M.,Gadas, P.,Galiová Vašínová, M. & Pezzotta, F. (2013): Compositional variations in Cs,Li,Mg-rich beryl from exocontact of the complex Manjaka pegmatite, Sahatany Valley, Madagascar. GAG-MAC Winnipeg 2013, SY2-P3, p. 152-153

Spessartine

Formula: Mn2+3Al2(SiO4)3

Spodumene

Formula: LiAlSi2O6

Titanite

Formula: CaTi(SiO4)O

Description: Ta- rich titanite is found in small bands at the exocontact of the pegmatite with the host rock.

References:

Novák, M.,Gadas, P.,Galiová Vašínová, M. & Pezzotta, F. (2013): Compositional variations in Cs,Li,Mg-rich beryl from exocontact of the complex Manjaka pegmatite, Sahatany Valley, Madagascar. GAG-MAC Winnipeg 2013, SY2-P3, p. 152-153

Novák, Milan, Cempírek, Jan, Gadas, Petr, Škoda, Radek, Vašinová Galiová, Michaela, Pezzotta, Federico, Groat, Lee A. (2015) Boralsilite and Li, Be-bearing "Boron Mullite" Al8B2Si2O19, Breakdown products of spodumene from the Manjaka pegmatite, Sahatany valley, Madagascar. The Canadian Mineralogist, 53 (2) 357-374 doi:10.3749/canmin.1400092

'Tourmaline'

Formula: A D3G6 (T6O18)(BO3)3X3Z

'Tourmaline var. Rubellite'

Formula: A(D3)G6(T6O18)(BO3)3X3Z

Tremolite

Formula: ◻Ca2Mg5(Si8O22)(OH)2

Description: Found in the exocontact zones of the pegmatite

References:

Gadas, P., Novák, M., Vašinová Galiová, M., Pezzotta, F. (2023) Chemical composition of tourmalines from the Manjaka pegmatite and its exocontact, Sahatany Valley, Madagascar. Journal of Geosciences, 68 (3) 185-202 doi:10.3190/jgeosci.374

Uvite

Formula: CaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)

References:

Gadas, P., Novák, M., Vašinová Galiová, M., Pezzotta, F. (2023) Chemical composition of tourmalines from the Manjaka pegmatite and its exocontact, Sahatany Valley, Madagascar. Journal of Geosciences, 68 (3) 185-202 doi:10.3190/jgeosci.374

Vránaite (TL)

Formula: Al16B4Si4O38

Type Locality:

Habit: As aggregates of subparallel prisms up to 100 μm long.

Description: Occurs as a breakdown product of spodumene.

References:

Cempírek, Jan, Grew, Edward S., Kampf, Anthony R., Ma, Chi, Novák, Milan, Gadas, Petr, Škoda, Radek, Vašinová-Galiová, Michaela, Pezzotta, Federico, Groat, Lee A., Krivovichev, Sergey V. (2016) Vránaite, ideally Al16B4Si4O38, a new mineral related to boralsilite, Al16B6Si2O37, from the Manjaka pegmatite, Sahatany Valley, Madagascar. American Mineralogist, 101 (9) 2108-2117 doi:10.2138/am-2016-5686

Zircon

Formula: Zr(SiO4)

Zircon var. Hafnian Zircon

Formula: (Zr,Hf)SiO4