Jarosewichite (original) (raw)

A valid IMA mineral species

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About JarosewichiteHide

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Formula:

Mn2+3Mn3+(AsO4)(OH)6

Lustre:

Sub-Vitreous, Resinous, Greasy

Crystal System:

Orthorhombic

Name:

Named in 1982 by Pete J. Dunn, Donald R. Peacor, Peter B. Leavens, and William B. Simmons in honor of Eugene Jarosewich [January 6, 1926 - April 30, 2007 Washington, District of Columbia, USA] mineral and meteorite chemist, Department of Mineral Sciences, Smithsonian Institution. Jarosewich established analytical standard materials for microprobe analysis and established analytical standard materials for meteorites.

Dark brown tightly intergrown cushion-like to divergent clusters of crystals.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2077:6

e5ad9ad7-0c1e-47e7-8119-b40ec7787850

IMA Classification of JarosewichiteHide

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IMA Formula:

Mn3+Mn2+3(AsO4)(OH)6

Type description reference:

Classification of JarosewichiteHide

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8.BE.70

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
E : With only medium-sized cations, (OH, etc.):RO4 > 2:1

41.1.1.3

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p > 4:1

20.8.5

20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Jrw IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of JarosewichiteHide

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Sub-Vitreous, Resinous, Greasy

Comment:

Subvitreous on fractured surfaces

Fracture:

Irregular/Uneven

Density:

3.66(4) g/cm3 (Measured) 3.70 g/cm3 (Calculated)

Optical Data of JarosewichiteHide

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RI values:

_n_α = 1.780(5) _n_β = 1.795(5) _n_γ = 1.805(5)

2V:

Measured: 78° , Calculated: 78°

δ = 0.025

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

r > v distinct

Optical Extinction:

Parallel. X = a, Y = b, Z = c.

Comments:

X = medium brownish red; Z = dark brownish red.

Comments:

Reactive with some Refractive index liquids.
Absorption: Z > X.

Chemistry of JarosewichiteHide

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Mindat Formula:

Mn2+3Mn3+(AsO4)(OH)6

Crystallography of JarosewichiteHide

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Crystal System:

Orthorhombic

Class (H-M):

222 - Disphenoidal

Cell Parameters:

a = 6.563 Å, b = 25.201 Å, c = 10.005 Å

Ratio:

a:b:c = 0.26 : 1 : 0.397

Unit Cell V:

1,654.77 ų (Calculated from Unit Cell)

Morphology:

Rarely in rod-like crystals with crude "hexagonal" cross-section, also in tabular to flattened crystals, usually in slightly divergent groups.

Comment:

Point Group: 2/m 2/m 2/m, 222, or mm2.; Space Group: Cmmm, Cmm2 or C222.

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
6.29 Å (20)
5.30 Å (5)
3.91 Å (60)
3.21 Å (5)
3.17 Å (5)
2.669 Å (100)
2.612 Å (2)
2.573 Å (2)
2.503 Å (30)
2.451 Å (10)
2.289 Å (5)
2.256 Å (5)
1.873 Å (1)
1.788 Å (50)
1.738 Å (1)
1.567 Å (20)
1.558 Å (30)
1.501 Å (20)
1.468 Å (2)
1.385 Å (1)
1.126 Å (2)

Geological EnvironmentHide

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Type Occurrence of JarosewichiteHide

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General Appearance of Type Material:

Etched and vuggy granular dark olive green andradite and franklinite.

Place of Conservation of Type Material:

Harvard University, Cambridge, Massachusetts, USA, 109463.
National Museum of Natural History, Washington, D.C., USA, 148972.

Associated Minerals at Type Locality:

Reference:

Dunn, P.J., Peacor, D.R. Leavens, P.B., Simmons, W.B. (1982) Jarosewichite and a related phase: basic manganese arsenates of the chlorophoenicite group from Franklin, New Jersey. American Mineralogist: 67: 1043-1047.

Synonyms of JarosewichiteHide

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Other Language Names for JarosewichiteHide

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Relationship of Jarosewichite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.BE.05 Augelite Al2(PO4)(OH)3 Mon. 2/m : _B_2/m
8.BE.10 Grattarolaite Fe3+3(PO4)O3 Trig. 3_m_ : R_3_m
8.BE.15 Cornetite Cu3(PO4)(OH)3 Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.BE.20 Clinoclase Cu3(AsO4)(OH)3 Mon. 2/m : _P_21/b
8.BE.25 Arhbarite Cu2Mg(AsO4)(OH)3 Tric. 1 : _P_1
8.BE.25 Gilmarite Cu3(AsO4)(OH)3 Tric. 1 : _P_1
8.BE.30 Allactite Mn2+7(AsO4)2(OH)8 Mon. 2/m : _P_21/b
8.BE.30 Flinkite Mn2+2Mn3+(AsO4)(OH)4 Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BE.30 Raadeite Mg7(PO4)2(OH)8 Mon. 2/m
8.BE.30 Argandite Mn7(VO4)2(OH)8 Mon. 2/m : _P_21/m
8.BE.35 Chlorophoenicite (Mn,Mg)3Zn2(AsO4)(OH,O)6 Mon. 2/m : _B_2/m
8.BE.35 Magnesiochlorophoenicite (Mg,Mn)3Zn2(AsO4)(OH,O)6 Mon. 2/m : _B_2/m
8.BE.35 Mineral E (of Dunn, et. al., 1982) Orth. m m m _(_2/_m_2/_m_2/m )
8.BE.40 Gerdtremmelite (Zn,Fe)(Al,Fe)2(AsO4)(OH)5 Tric.
8.BE.45 Dixenite CuMn2+14Fe2+(SiO4)2(As5+O4)(As3+O3)5(OH)6 Trig. 3 : _R_3
8.BE.45 Hematolite (Mn,Mg,Al,Fe3+)15(As5+O4)2(As3+O3)(OH)23 Trig. 3 : _R_3
8.BE.45 Kraisslite Zn3(Mn,Mg)25(Fe3+,Al)(As3+O3)2[(Si,As5+)O4]10(OH)16 Orth. 222 : _C_2221
8.BE.45 Mcgovernite Mn19Zn3(AsO4)3(AsO3)(SiO4)3(OH)21 Trig. 3_m_ _(_32/m )
8.BE.45 Arakiite (Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As5+O4)2(As3+O3)(OH)23 Mon. m : B b
8.BE.45 Turtmannite (Mn,Mg)22.5Mg3-3x((V5+,As5+)O4)3(As3+O3)x(SiO4)3O5-5x(OH)20+x Trig.
8.BE.45 Carlfrancisite Mn2+3(Mn2+,Mg,Fe3+,Al)42[As3+O3]2(As5+O4)4[(Si,As5+)O4]6[(As5+,Si)O4]2(OH)42 Trig. 3_m_ _(_32/m ) : R_3_c
8.BE.50 Synadelphite Mn2+9(As5+O4)2(As3+O3)(OH)9 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BE.55 Holdenite (Mn2+,Mg)6Zn3(AsO4)2(SiO4)(OH)8 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c a
8.BE.60 Kolicite Mn2+7Zn4(AsO4)2(SiO4)2(OH)8 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a
8.BE.65 Sabelliite (Cu,Zn)2Zn(AsO4,SbO4)(OH)3 Trig. 3 : _P_3
8.BE.75 Theisite Cu5Zn5(AsO4,SbO4)2(OH)14 Orth.
8.BE.80 Coparsite Cu4(AsO4,VO4)O2Cl Orth. m m m _(_2/_m_2/_m_2/m ) : P b c m
8.BE.85 Waterhouseite Mn2+7(PO4)2(OH)8 Mon. 2/m : _P_21/b
8.BE.90 Vasilseverginite Cu9O4(AsO4)2(SO4)2 Mon. 2/m

Fluorescence of JarosewichiteHide

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for JarosewichiteHide

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Localities for JarosewichiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

USA
New Jersey Sussex County Franklin Franklin Mine Buckwheat dump mineral collecting site King (n.d.)
Buckwheat pit (TL) Dunn et al. (1982) +1 other reference