Birchite (original) (raw)

A valid IMA mineral species

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About BirchiteHide

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Formula:

Cd2Cu2(PO4)2(SO4) · 5H2O

Crystal System:

Orthorhombic

Name:

For William David "Bill" Birch, AM (1949-). Bill obtained his PhD in the Department of Geology at the University of Melbourne in 1976 and commenced work at the National Museum of Victoria (now Museum Victoria), as Curator with responsibilities for developing the mineral, rock and meteorite collections, a position he still holds (in 2009). He has co-described thirty new mineral species and has over 150 publications to his credit. These range from popular articles and booklets accessible to members of the general public with an interest in the geosciences, to major papers involving international mineralogical collaboration.

He has had active involvment in a number of societies such as: the Mineralogical Society of Victoria (founding President), the Gemmological Association of Australia (as present patron), the Geological Society of Australia, the Royal Society of Victoria (he is a member of Council), and the International Mineralogical Association, Commission on New Minerals, Nomenclature and Classification (Australian representative 1984-1996 and Secretary 1996-2008).

In June 2006 he was awarded the Member of the Order of Australia (AM) for "service to geological science, particularly through the study and documentation of the geology of Victoria, and to a range of professional organisations."

One of several rare Cd minerals occurring at Broken Hill, NSW, Australia.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:35925:8

83b45a03-e819-4f43-8773-96ce3926532f

IMA Classification of BirchiteHide

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Type description reference:

Elliott, P., Brugger, J., Pring, A., Cole, M. L., Willis, A. C., Kolitsch, U. (2008) Birchite, a new mineral from Broken Hill, New South Wales, Australia: Description and structure refinement. American Mineralogist, 93 (5) 910-917 doi:10.2138/am.2008.2732

Classification of BirchiteHide

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8.DB.70

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1

43.3.3.

43 : COMPOUND PHOSPHATES, ETC.
3 : Hydrated Normal Compound Phosphates, etc·

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Bc IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BirchiteHide

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Transparency:

Transparent, Translucent

Density:

3.61(4) g/cm3 (Measured) 3.647 g/cm3 (Calculated)

Optical Data of BirchiteHide

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RI values:

_n_α = 1.624(4) _n_β = 1.636(5) _n_γ = 1.669(4)

δ = 0.045

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

No or only very small dispersion.

Optical Extinction:

X = b; Y = a; Z = c.

Comments:

Very faint pleochroism. X = pale bluish, Z = pale greenish.

Comments:

Absorption: Z ≥ X.

Chemistry of BirchiteHide

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Mindat Formula:

Cd2Cu2(PO4)2(SO4) · 5H2O

Crystallography of BirchiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 10.489(6) Å, b = 20.901(7) Å, c = 6.155(5) Å

Ratio:

a:b:c = 0.502 : 1 : 0.294

Morphology:

Crystals are bladed (somewhat lath-shaped) and prismatic to acicular in habit. Elongated along [001] and sometimes also flattened on (100). Main forms are {100} and {010}. Most crystals are not well terminated, but some show minor {101} and {001} faces.

Twinning:

No twinning observed.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0004585 Birchite Elliot P, Brugger J, Pring A, Cole M L, Willis A C, Kolitsch U (2008) Birchite, a new mineral from Broken Hill, New South Wales, Australia: Description and structure refinement American Mineralogist 93 910-917 2008 Block 14 Opencut, Broken Hill, New South Wales, Australia 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
10.451 Å (100)
5.146 Å (30)
4.223 Å (40)
3.484 Å (40)
2.902 Å (70)
2.719 Å (30)
2.652 Å (30)
1.919 Å (80)

Comments:

Broken Hill, New South Wales, Australia. Data from the type description.

Geological EnvironmentHide

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Type Occurrence of BirchiteHide

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General Appearance of Type Material:

Sprays and aggregates to crystals to 0.75 mm. Individual crystals are bladed to prismatic and acicular, with a max. length of 0.3 mm and width of 0.05 mm.

Place of Conservation of Type Material:

Department of Mineralogy of the South Australian Museum, Adelaide, South Australia, australia (registration number G30968).

Geological Setting of Type Material:

Secondary mineral formed under late stage supergene low-temperature conditions.

Associated Minerals at Type Locality:

Reference:

Elliott, P., Brugger, J., Pring, A., Cole, M.L., Willis, A.C. and Kolitsch, U. (2008) Birchite, a new mineral from Broken Hill, New South Wales, Australia: description and structure refinement. American Mineralogist: 93: 910-917.

Synonyms of BirchiteHide

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Other Language Names for BirchiteHide

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8.DB. Arangasite Al2F(PO4)(SO4) · 9H2O Mon. 2/m : _P_2/b
8.DB. Camaronesite [Fe3+(H2O)2(PO3OH)]2(SO4) · 1-2H2O Trig. 32 : _R_32
8.DB. Höslite Fe3+3(VO4)2(SO4)(OH)(H2O)4 · 3H2O Mon. 2/m : _P_21/b
8.DB.05 Diadochite Fe3+2(PO4)(SO4)(OH) · 6H2O Amor.
8.DB.05 Pitticite (Fe, AsO4, H2O) (?) Amor.
8.DB.05 Destinezite Fe3+2(PO4)(SO4)(OH) · 6H2O Tric. 1 : _P_1
8.DB.07 Wilhelmgümbelite ZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DB.07 Schmidite [Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2O Orth.
8.DB.07 Wildenauerite Zn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
8.DB.10 Vashegyite Al11(PO4)9(OH)6 · 38H2O Orth. m m m _(_2/_m_2/_m_2/m )
8.DB.15 Schoonerite ZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b a m
8.DB.20 Sinkankasite Mn2+Al(PO3OH)2(OH) · 6H2O Tric. 1 : _P_1
8.DB.25 Mitryaevaite Al6(PO4)((P,S)O3(OH,O))2F2(OH)2 · 14.5H2O Tric. 1 : _P_1
8.DB.30 Sanjuanite Al2(PO4)(SO4)(OH) · 9H2O Tric.
8.DB.35 Sarmientite Fe3+2(AsO4)(SO4)(OH) · 5H2O Mon. 2/m : _P_21/b
8.DB.40 Bukovskýite Fe3+2(AsO4)(SO4)(OH) · 9H2O Tric. 1 : _P_1
8.DB.40 Flurlite Zn3Mn2+Fe3+(PO4)3(OH)2 · 9H2O Mon. 2/m : _P_21/m
8.DB.40 Manganflurlite ZnMn2+3Fe3+(PO4)3(OH)2(H2O)7 · 2H2O Mon. 2/m : _P_21/m
8.DB.42 Bohuslavite Fe3+4(PO4)3(SO4)(OH) · nH2O Tric. 1 : _P_1
8.DB.45 Zýkaite Fe3+4(AsO4)3(SO4)(OH) · 15H2O Orth. 222 : _P_222
8.DB.47 Lapeyreite Cu3O[AsO3(OH)]2 · 0.75H2O Mon. 2/m : _B_2/m
8.DB.50 Giniite Fe2+Fe3+4(PO4)3(OH)5 · 2H2O Mon. 2/m : _P_2/b
8.DB.50 Rossiantonite Al3(PO4)(SO4)2(OH)2(H2O)14 Tric. 1 : _P_1
8.DB.52 Arctowskite Al9(PO4)8(OH)3 · 27H2O Orth.
8.DB.55 Sasaite (Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2O Orth.
8.DB.60 Mcauslanite Fe3Al2(PO4)3(PO3OH)F · 18H2O Tric.
8.DB.65 Goldquarryite CuCd2Al3(PO4)4F2(H2O,F)2 · 10H2O Tric. 1 : _P_1
8.DB.75 Braithwaiteite NaCu5(Ti4+Sb5+)(AsO4)4(HAsO4)2O2 · 8H2O Tric. 1 : _P_1

Fluorescence of BirchiteHide

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Other InformationHide

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Notes:

Slowly soluble, without effervescence, in cold 10% HCl.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for BirchiteHide

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Reference List:

Elliott, P., Brugger, J., Pring, A., Cole, M. L., Willis, A. C., Kolitsch, U. (2008) Birchite, a new mineral from Broken Hill, New South Wales, Australia: Description and structure refinement. American Mineralogist, 93 (5) 910-917 doi:10.2138/am.2008.2732

Localities for BirchiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia (TL)
New South Wales Yancowinna Co. Broken Hill district Broken Hill (TL) Elliott et al. (2008)
Block 14 opencut John Haupt