Fluorcalcioroméite (original) (raw)

A valid IMA mineral species

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About FluorcalcioroméiteHide

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Formula:

(Ca,Na,◻)2Sb5+2(O,OH)6F

Lustre:

Vitreous, Resinous

Specific Gravity:

5.113 (Calculated)

Name:

The name was created during a 2010 reorganization of the pyrochlore supergroup, but it required a complete description in order to be approved as valid species. That description was published in 2013. The name indicates the chemical relationship to other roméite group species.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:40367:4

963b6af4-f08c-49b9-81d4-f4e4bdd267a7

IMA Classification of FluorcalcioroméiteHide

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IMA Formula:

(Ca,Na)2Sb5+2O6F

Classification of FluorcalcioroméiteHide

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4.DH.20

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
H : With large (+- medium-sized) cations; sheets of edge-sharing octahedra

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Fcrm IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FluorcalcioroméiteHide

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Density:

5.113 g/cm3 (Calculated)

Comment:

Could not be measured due to lack of pure material.

Optical Data of FluorcalcioroméiteHide

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Birefringence:

Isotropic minerals have no birefringence

Chemistry of FluorcalcioroméiteHide

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Mindat Formula:

(Ca,Na,◻)2Sb5+2(O,OH)6F

Crystallography of FluorcalcioroméiteHide

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Class (H-M):

m_3_m _(_4/_m_32/m ) - Hexoctahedral

Cell Parameters:

a = 10.2987(8) Å

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
5.934 Å (81)
3.102 Å (20)
2.969 Å (100)
2.572 Å (6)
1.979 Å (7)
1.818 Å (8)
1.551 Å (15)
1.484 Å (5)

Comments:

Starlera mine, Ferrera, Switzerland. The data are from the type description.

Geological EnvironmentHide

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Type Occurrence of FluorcalcioroméiteHide

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General Appearance of Type Material:

Euhedral octahedra from 0.1 to 1 mm in size.

Place of Conservation of Type Material:

Museo Regionale di Scienze Naturali, Sezione di Mineralogia, Petrografia e Geologia, Torino, Italy, number M/15925 (type).
The RRUFF project, number R120140 (cotype).
Museu de Geociências, Instituto de Geociências, Universidade de São Paulo, São Paulo, Brazil, number DR745 (cotype).

Geological Setting of Type Material:

Associated Minerals at Type Locality:

Synonyms of FluorcalcioroméiteHide

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Other Language Names for FluorcalcioroméiteHide

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Relationship of Fluorcalcioroméite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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4.DH. Fluornatropyrochlore (Na,Pb,Ca,REE,U)2Nb2O6F Iso. m_3_m _(_4/_m_32/m )
4.DH. Roméite Group A2(Sb5+)2O6Z
4.DH. Hydroxykenomicrolite (◻,Na,Sb3+)2Ta2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH. Fluornatroroméite (Na,Ca)2Sb2(O,OH)6F
4.DH. Oxyplumboroméite Pb2Sb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH. Cesiokenopyrochlore ◻Nb2(O,OH)6(Cs,◻) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH. Oxyyttrobetafite-(Y) Y2Ti2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.05 Brannerite UTi2O6 Mon. 2/m : _B_2/m
4.DH.05 Orthobrannerite U4+U6+Ti4O12(OH)2 Orth.
4.DH.05 Thorutite (Th,U,Ca)Ti2(O,OH)6 Mon.
4.DH.10 Kassite CaTi2O4(OH)2 Mon. 2/m : _P_21/b
4.DH.10 Lucasite-(Ce) CeTi2(O,OH)6 Mon.
4.DH.15 va Alumotungstite ◻2W2O6(H2O) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Bismutomicrolite (of Hogarth 1977) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydroplumboelsmoreite (Pb,◻)(W,Fe3+)2O6 · H2O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydropyrochlore (H2O,◻)2Nb2(O,OH)6(H2O) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Plumbomicrolite (of Hogarth 1977)
4.DH.15 Stibiomicrolite (of Groat et al.)
4.DH.15 Strontiopyrochlore (of Hogarth 1977) A2Nb2(O,OH)6Z
4.DH.15 Fluornatromicrolite (Na1.5Bi0.5)Ta2O6F Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Bismutopyrochlore (of Chukanov et al.) (Bi,Ca,U,Pb)2-xNb2(O,OH)6(OH) Amor.
4.DH.15 Hydrokenoelsmoreite ◻2W2O6(H2O) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Fluorcalciomicrolite (Ca,Na)2(Ta,Nb)2O6F Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Oxycalciobetafite Ca2(Ti,Nb)2O6O
4.DH.15 va Yttromicrolite (of Hogarth) (Ca,Y3+,U,Na)2-x(Ta,Nb,Ti,Fe3+)2O7 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Oxynatropyrochlore (Na,Ca,U)2Nb2O6(O,OH)
4.DH.15 Hydroxycalciopyrochlore (Ca,Na,U,◻)2(Nb,Ti)2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Fluorcalciopyrochlore (Ca,Na)2(Nb, Ti)2O6F Iso.
4.DH.15 Oxycalciopyrochlore Ca2Nb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Fluorstrontiopyrochlore (Sr,◻)2Nb2(O,OH)6F
4.DH.15 Oxyplumbopyrochlore Pb2Nb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Kenoplumbopyrochlore (Pb,◻)Nb2O6(◻,O)
4.DH.15 Oxyyttropyrochlore-(Y) (Y,◻)2Nb2O6O
4.DH.15 Fluorkenopyrochlore (◻,Sr,Ce,Ca,Na)2(Nb,Ti)2O6F
4.DH.15 Oxyuranobetafite (U,Ca,◻)2(Ti,Nb)2O6O
4.DH.15 Oxycalciomicrolite Ca2Ta2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Oxystannomicrolite Sn2Ta2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Kenoplumbomicrolite (Pb,◻)2Ta2O6(◻,OH,O) Iso.
4.DH.15 Oxystibiomicrolite (Sb3+,Ca)2Ta2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydromicrolite (H2O,◻)2Ta2(O,OH)6(H2O)
4.DH.15 Hydrokenomicrolite (◻,H2O)2Ta2(O,OH)6(H2O) Iso. m_3_m _(_4/_m_32/m )
4.DH.15 Hydroxymanganopyrochlore (Mn2+,Th,Na,Ca,REE)2(Nb,Ti)2O6(OH) Iso. m_3(2/m_3)
4.DH.15 Hydroxycalciomicrolite Ca1.5Ta2O6(OH) Iso. 432 : _P_4232
4.DH.15 Fluorplumbopyrochlore (Pb,Y,Th,U,Na,Ca)2-x(Nb,Ti)2O6F Iso.
4.DH.15 Hydroxyplumbopyrochlore (Pb1.5◻0.5)Nb2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Oxynatromicrolite (Na,Ca,U)2(Ta,Nb)2O6(O,F) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Fluorhydropyrochlore
4.DH.15 Hydroxykenoelsmoreite (◻,Pb)2(W,Fe3+,Al)2(O,OH)6(OH) Trig. 3 : _R_3
4.DH.15 Hydrokenopyrochlore (◻,x)2Nb2O6(H2O,Cs) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydroxykenopyrochlore (◻,Ce,Ba)2(Nb,Ti)2O6(OH,F) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydroxynatropyrochlore (Na,Ca,Ce)2Nb2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydroxynatromicrolite (Na,Bi3+,◻)2Ta2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Unnamed (Sb-analogue of Hydroxymanganopyrochlor) (Mn,Ca,Y)2(Sb,Ti)2O6(OH)
4.DH.15 Oxybismutomicrolite (Bi1.33◻0.67)Σ2Ta2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Oxyplumbopyrochlore Pb2Nb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.20 Bindheimite Pb2Sb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.20 Hydroxycalcioroméite (Ca,Sb3+)2(Sb5+,Ti)2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.20 Monimolite Pb2Sb5+2O7 Iso. m_3_m _(_4/_m_32/m )
4.DH.20 Cuproroméite Cu2Sb2(O,OH)7 Iso.
4.DH.20 Stetefeldtite Ag2Sb2(O,OH)7 Iso.
4.DH.20 Stibiconite Sb3+Sb5+2O6(OH) Iso. m_3_m _(_4/_m_32/m )
4.DH.20 Oxycalcioroméite Ca2Sb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.20 Hydroxyferroroméite (Fe2+1.5◻0.5)Sb5+2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.25 Rosiaite PbSb5+2O6 Trig. 3_m_ _(_32/m ) : P_31_m
4.DH.30 Zirconolite CaZrTi2O7 Orth.
4.DH.30 Laachite (Ca,Mn)2Zr2Nb2TiFeO14 Mon. 2/m : _B_2/b
4.DH.30 Nöggerathite-(Ce) (Ce,Ca)2Zr2(Nb,Ti)(Ti,Nb)2Fe2+O14 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a
4.DH.30 Stefanweissite (Ca,REE)2Zr2(Nb,Ti)(Ti,Nb)2Fe2+O14 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a
4.DH.35 Liandratite U(Nb,Ta)2O8 Trig. 3_m_ _(_32/m ) : P_31_m
4.DH.35 Petscheckite UFe(Nb,Ta)2O8 Hex.
4.DH.40 Ingersonite Ca3Mn2+Sb5+4O14 Trig. 32 : _P_3121
4.DH.45 Pittongite Na0.22(W,Fe3+)(O,OH)3 · 0.44H2O Hex. 6_m_2 : _P_6_m_2
4.DH.50 Tazzoliite Ba4-xNaxTi2Nb3SiO17[PO2(OH)2]x(OH)(1-2x) Orth. m m m _(_2/_m_2/_m_2/m ) : F m m m

Fluorescence of FluorcalcioroméiteHide

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Non-fluorescent under ultraviolet light.

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for FluorcalcioroméiteHide

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Reference List:

Atencio, D., Andrade, M. B., Christy, A. G., Giere, R., Kartashov, P. M. (2010) The pyrochlore supergroup of minerals: nomenclature. The Canadian Mineralogist, 48 (3) 673-698 doi:10.3749/canmin.48.3.673

Atencio, D., Ciriotti, M. E., Andrade, M. B. (2013) Fluorcalcioroméite, (Ca,Na)2Sb25+(O,OH)6F, a new roméite-group mineral from Starlera mine, Ferrera, Grischun, Switzerland: description and crystal structure. Mineralogical Magazine, 77 (4) 467-473 doi:10.1180/minmag.2013.077.4.06

Localities for FluorcalcioroméiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Austria
Salzburg Tamsweg District Tweng Fuchs Alp - Fuchs lake area Kolitsch et al. (2021)
Tyrol Innsbruck-Land District Navis Navis stream (Navis creek) Kolitsch et al. (2019)
Obernberg am Brenner Obernberger Tribulaun Kolitsch et al. (2018)
Trins Kirchdachspitze Kolitsch et al. (2021)
Brazil
Minas Gerais Ouro Preto Miguel Burnier identified by EDAX and SEM Image. See ...
Italy
Aosta Valley Saint-Marcel Praborna Mine Lopes et al. (2021)
Poland
Lesser Poland Voivodeship Gorlice County Pasternik borehole Gołębiowska et al. (2021)
Oświęcim County Włosienica borehole Gołębiowska et al. (2021)
Lower Silesian Voivodeship Dzierżoniów County Piława Górna DSS Piława Górna Quarry Julianna pegmatite Pieczka et al. (2018)
Slovakia
Banská Bystrica Region Banská Bystrica District Brusno Sopotnická Valley Uher et al. (1998) +1 other reference
Spain
Andalusia Almería Cuevas del Almanzora Las Herrerías Berja Mines Santa Matilde open pit Analysis made by César Menor Salván +1 other reference
Sweden
Värmland County Filipstad Långban Ore District Långban Mine Welin (1968) +1 other reference
Switzerland
Grisons Viamala Region Ferrera Ausserferrera Fianel Roth et al. (2013)
Schmorrasgrat-South Roth et al. (2013)
Starlera Valley Starlera Mine (TL) Brugger et al. (1999) +3 other references
Rheinwald Splügen Tanatz Alp Roth et al. (2013)
Turkey
Niğde Province Çamardı District Kestel Mine Powell et al. (2021)