Nickeltyrrellite (original) (raw)

A valid IMA mineral species

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About NickeltyrrelliteHide

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Specific Gravity:

7.36 (Calculated)

Name:

In allusion to being the Ni-dominant analogue of tyrrellite.

The Ni analogue of tyrrellite. Unique combination of elements.

Nickeltyrrellite formed in response to alteration of quijarroite + hansblockite + watkinsonite + clausthalite + penroseite aggregates by oxidizing, low-T, Cu-Ni-Co-Pb-bearing fluids at a fSe2/fS2 ratio greater than unity (Förster et al. 2019).

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:53346:1

abd64eba-499d-4fac-b968-167203855fbe

IMA Classification of NickeltyrrelliteHide

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Type description reference:

Förster, Hans-Jürgen, Ma, Chi, Grundmann, Günter, Bindi, Luca, Stanley, Christopher J. (2019) Nickeltyrrellite, CuNi2Se4, a new member of the spinel supergroup from El Dragón, Bolivia. The Canadian Mineralogist, 57 (5) 637-646 doi:10.3749/canmin.1900025

Classification of NickeltyrrelliteHide

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2.DA.05

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
D : Metal Sulfides, M: S = 3 :4 and 2:3
A : M:S = 3:4

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Nty IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of NickeltyrrelliteHide

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Hardness Data:

Could not be measured

Parting:

No obvious parting

Fracture:

Irregular/Uneven

Density:

7.36 g/cm3 (Calculated)

Optical Data of NickeltyrrelliteHide

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Anisotropism:

Between crossed polarizers, it is isotropic

Reflectivity:

Wavelength R
400nm 42.1%
420nm 43.3%
440nm 44.4%
460nm 45.4%
470nm 45.9%
480nm 46.2%
500nm 46.7%
520nm 47.1%
540nm 47.5%
546nm 47.6%
560nm 47.8%
580nm 48.3%
589nm 48.1%
600nm 48.8%
620nm 49.9%
640nm 49.7%
650nm 49.8%
660nm 50.1%
680nm 50.5%
700nm 51.0%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 51.0%.

Chemistry of NickeltyrrelliteHide

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Crystallography of NickeltyrrelliteHide

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Class (H-M):

m_3_m _(_4/_m_32/m ) - Hexoctahedral

Cell Parameters:

a = 9.99 Å

Morphology:

Anhedral to subhedral grains (up to 20 μm in size).

Comment:

Measured using electron back- scatter diffraction (EBSD)

X-Ray Powder DiffractionHide

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Comments:

X-ray powder diffraction pattern not available (CNMNC Newsletter No. 47). Structure was determined using Electron Backscatter Diffraction (EBSD).

Geological EnvironmentHide

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Type Occurrence of NickeltyrrelliteHide

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General Appearance of Type Material:

Anhedral to subhedral grains (up to 20 μm in size).

Place of Conservation of Type Material:

Type material is deposited in the mineralogical collections of the Natural History Museum, London, catalogue number BM2018,19 (holotype), and the Mineralogical State Collection Munich − Museum Reich der Kristalle, inventory number MSM 73587 (cotype).

Empirical Formula of Type Material:

Cu1.00(Ni1.42Co0.56Fe0.02)Σ2.00(Se3.84S0.16)Σ4.00

Chemical Analysis of Type Material:

Cu 13.01 %
Fe 0.27 %
Co 6.66 %
Ni 16.98 %
S 1.04 %
Se 61.91 %
Total: 99.87 %

Geological Setting of Type Material:

In a series of thinly stratified, pyrite-rich black shales and reddish-grey, hematite-bearing silt-stones of probably Devonian age. These rocks host a single vein from 0.5 to 2 cm in thickness, rich in selenium.

Associated Minerals at Type Locality:

Reference:

Förster, H.-J., Ma, C. Grundmann, G., Bindi, L., Stanley, C.J. (2019) Nickeltyrrellite, CuNi2Se4, a New Member of the Spinel Supergroup from El Dragón, Bolivia. The Canadian Mineralogist: 57 (5): 637–646.

Synonyms of NickeltyrrelliteHide

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Relationship of Nickeltyrrellite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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2.DA. Zaykovite Rh3Se4 Mon. 2/m : _B_2/m
2.DA. Grimmite NiCo2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA. Zolenskyite FeCr2S4 Mon. 2/m : _B_2/m
2.DA. Ezochiite Cu+(Rh3+Pt4+)S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA. Ferrodimolybdenite FeMo2S4 Mon. 2/m : _B_2/b
2.DA.05 Bornhardtite Co2+Co3+2Se4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Carrollite CuCo2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Cuproiridsite (Cu,Fe)Ir2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Cuprorhodsite (Cu1+0.5Fe3+0.5)Rh3+2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Daubréelite Fe2+Cr3+2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Fletcherite CuNi2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Florensovite (Cu,Zn)Cr1.5Sb0.5S4 Iso. m_3_m _(_4/_m_32/m )
2.DA.05 Greigite Fe2+Fe3+2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Indite FeIn2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Kalininite ZnCr2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Linnaeite Co2+Co3+2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Malanite Cu1+(Ir3+Pt4+)S4 Iso. m_3_m _(_4/_m_32/m )
2.DA.05 Polydymite Ni2+Ni3+2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Siegenite CoNi2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Trüstedtite Ni3Se4 Iso.
2.DA.05 Tyrrellite Cu(Co3+,Ni3+)2Se4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Violarite Fe2+Ni3+2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Xingzhongite Pb2+Ir3+2S4 Iso.
2.DA.05 Cadmoindite CdIn2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Cuprokalininite CuCr2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Joegoldsteinite MnCr2S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.05 Shiranuiite Cu+(Rh3+Rh4+)S4 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
2.DA.10 Rhodostannite Cu1+(Fe2+0.5Sn4+1.5)S4 Tet. 4/m : _I_41/a
2.DA.10 Toyohaite Ag1+(Fe2+0.5Sn4+1.5)S4 Tet. 4/m : _I_41/a
2.DA.15 Brezinaite Cr3S4 Mon. 2/m
2.DA.15 Heideite (Fe,Cr)1.15(Ti,Fe)2S4 Mon. 2/m
2.DA.20 Inaglyite Cu3Pb(Ir,Pt)8S16 Hex.
2.DA.20 Konderite Cu3Pb(Rh,Pt,Ir)8S16 Hex. 6/m : _P_6/m
2.DA.25 Kingstonite (Rh,Ir,Pt)3S4 Mon. 2/m : _B_2/m

Fluorescence of NickeltyrrelliteHide

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for NickeltyrrelliteHide

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Reference List:

Miyawaki, Ritsuro, Hålenius, Ulf, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2019) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) NEWSLETTER 47. European Journal of Mineralogy, 31 (1) 197-202 doi:10.1127/ejm/2019/0031-2839

Förster, Hans-Jürgen, Ma, Chi, Grundmann, Günter, Bindi, Luca, Stanley, Christopher J. (2019) Nickeltyrrellite, CuNi2Se4, a new member of the spinel supergroup from El Dragón, Bolivia. The Canadian Mineralogist, 57 (5) 637-646 doi:10.3749/canmin.1900025

Localities for NickeltyrrelliteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Bolivia (TL)
Potosí Antonio Quijarro Province Porco Municipality El Dragón mine (TL) Förster et al. (2019) +1 other reference