Metavivianite Mineral Data (original) (raw)
General Metavivianite Information
(Fe++3-x,Fe+++x)(PO4)2(OH)x•8-x(H2O), x=0.5
Molecular Weight = 501.10 gm
Iron 33.43 % Fe 35.84 % FeO / 7.97 % Fe2O3
Phosphorus 12.36 % P 28.33 % P2O5
Hydrogen 3.12 % H 27.86 % H2O
Oxygen 51.09 % O
______ ______
100.00 % 100.00 % = TOTAL OXIDE
Fe2+2.5Fe3+0.5(PO4)2(OH)0.5•7.5(H2O)
Oxidized and dehydrated compared to vivianite.
Approved IMA 1974
Big Chief pegmatite, Glendale, Pennington County, South Dakota, USA. Link to MinDat.org Location Data.
Named to reflect the relationship with vivianite.
Egueiite - a hydrous Ca-Fe phosphate, possibly altered metavivianite
ICSD 201137
Kertschenite
Oxykertschenite
PDF 26-1137
Metavivianite Image
Metavivianite Comments: Rust-brown, metavivianite var. kertschenite crystals to 1.5 cm in length. Location: Kertsch Crimea, Ukraine.Scale: 5.5 x 3.5 cm. © John Veevaert |
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Metavivianite Crystallography
a:b:c =0.8601:1:0.5121
a = 7.81, b = 9.08, c = 4.65, Z = 1; alpha = 94.77°, beta = 97.15°, gamma = 107.37° V = 311.19 Den(Calc)= 2.67
TriclinicSpace Group: P1 or P1
By Intensity(I/Io): 6.71(1), 4.86(0.4), 8.59(0.4),
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| | Dormann J , Gasperin M , Poullen J F , Bulletin de Mineralogie , 105 (1982) p.147-160, Etude structurale de la sequence d oxydation de la vivianite Fe3(PO4)2*8(H2O) | | ------------------------------------------------------------------------------------------------------------------------------------------------------------------------ |
Physical Properties of Metavivianite
{110} Perfect
Leek green, Gray green, Reddish brown.
2.69
Opaque to translucent
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline).
Striated - Parallel lines on crystal surface or cleavage face.
1.5-2 - Talc-Gypsum
Sub Metallic
yellowish brown
Optical Properties of Metavivianite
CI meas= 0.061 (Fair) - where the CI = (1-KPDmeas/KC)
CI calc= 0.061 (Fair) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2244,KPDmeas= 0.2244,KC= 0.2391
Ncalc = 1.64
Biaxial (+), a=1.579, b=1.603, g=1.629, bire=0.0500, 2V(Calc)=90, 2V(Meas)=85.
blue or bluish green.
yellowish green or yellowish green.
yellowish green or yellowish green.
Calculated Properties of Metavivianite
Bulk Density (Electron Density)=2.70 gm/cc
note: Specific Gravity of Metavivianite =2.69 gm/cc.
Fermion Index = 0.0073380032
Boson Index = 0.9926619968
PEMetavivianite = 10.36 barns/electron
U=PEMetavivianite x rElectron Density= 27.98 barns/cc.
GRapi = 0 (Gamma Ray American Petroleum Institute Units)
Metavivianite is Not Radioactive
Metavivianite Classification
40.03.09.01 (40)Hydrated Phosphates, etc
(40.03)where (A++)3 (XO4)2 � x(H2O)
(40.03.09)Dana Group
40.03.09.01 Metavivianite (Fe3-x,Fex)(PO4)2(OH)x•8-x(H2O),x=0.5 P1 or P1 Tri
08.CE.85 08 - PHOSPHATES, ARSENATES, VANADATES
08.C - Phosphates without Additional Anions, with H2O
08.CE -With only medium-sized cations, RO4:H2O � 1:2.5
08.CE.85 Metavivianite (Fe3-x,Fex)(PO4)2(OH)x•8-x(H2O),x=0.5 P1 or P1 Tri
08.CE.85 Metakottigite (Zn,Fe,Fe)3(AsO4)2•8((H2O),OH) P1 1
Other Metavivianite Information
NAME( Dana8) PHYS. PROP.(Dana8) OPTIC PROP.(Dana8)
Links to other databases for Metavivianite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - EUROmin Project
4 - Ecole des Mines de Paris
5 - GeoScienceWorld
6 - Google Images
7 - Google Scholar
8 - Handbook of Mineralogy (MinSocAm)
9 - Handbook of Mineralogy (UofA)
10 - MinDAT
11 - Mineralienatlas (Deutsch)
12 - Online Mineral Museum
13 - QUT Mineral Atlas
14 - Ruff.Info
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Metavivianite
(Fe++3-x,Fe+++x)(PO4)2(OH)x•8-x(H2O), x=0.5
Dana No: 40.03.09.01 Strunz No: 08.CE.85
Locality:
Notes: