Spheniscidite Mineral Data (original) (raw)
General Spheniscidite Information
(NH4,K)(Fe+++,Al)2(PO4)2(OH)•2(H2O)
Molecular Weight = 413.28 gm
Potassium 3.78 % K 4.56 % K2O
Aluminum 5.22 % Al 9.87 % Al2O3
Iron 22.97 % Fe 32.84 % Fe2O3
Phosphorus 14.99 % P 34.35 % P2O5
Hydrogen 0.59 % H - % Calc as (NH4)2O
Hydrogen 1.63 % H 14.60 % H2O
Nitrogen 2.03 % N 3.78 % (NH4)2O
Oxygen 48.78 % O
______ ______
100.00 % 100.00 % = TOTAL OXIDE
(NH4)0.6K0.4Fe3+1.7Al0.8(PO4)2(OH)2.5�2.1(H2O)
Formed by interaction of phosphate solutions derived from quano with micacous and chloritic minerals in soil under a penguin rookery.
Approved IMA 1986
On Elephant Island, South Shetland Islands, about 800 km southeast of Cape Horn, British Antarctic Territory, Antartica. Link to MinDat.org Location Data.
Named for "Sphenisciformes," the Latin order name or penguins.
ICSD 75229
PDF 41-593
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Spheniscidite Crystallography
a:b:c =1.0124:1:1.0072
a = 9.75, b = 9.63, c = 9.7, Z = 4; beta = 102.567° V = 888.94 Den(Calc)= 3.09
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: P 21/n
By Intensity(I/Io): 6.79(1), 5.99(0.9), 3.05(0.45),
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| | Cavellec M , Riou D , Ferey G , Acta Crystallographica, Section C , 50 (1994) p.1379-1381, Synthetic spheniscidite, Locality: synthetic | | ------------------------------------------------------------------------------------------------------------------------------------------ |
Physical Properties of Spheniscidite
Brown.
2.71
Transparent to Translucent
Selvage - As a reaction rim, surrounding the host mineral.
1-1.5 - Talc or a little harder
Earthy (Dull)
white
Optical Properties of Spheniscidite
CI meas= -0.053 (Good) - where the CI = (1-KPDmeas/KC)
CI calc= 0.077 (Fair) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2265,KPDmeas= 0.2583,KC= 0.2453
Ncalc = 1.66 - 1.76
Biaxial (?), b=1.7
Calculated Properties of Spheniscidite
Bulk Density (Electron Density)=2.71 gm/cc
note: Specific Gravity of Spheniscidite =2.71 gm/cc.
Fermion Index = 0.02
Boson Index = 0.98
PESpheniscidite = 7.99 barns/electron
U=PESpheniscidite x relectron= 21.63 barns/cc.
GRapi = 54.53 (Gamma Ray American Petroleum Institute Units)
Concentration of Spheniscidite per GRapi unit = 1.83 (%)
Estimated Radioactivity from Spheniscidite - barely detectable
Spheniscidite Classification
42.11.06.03 (42)Hydrated Phosphates, etc., Containing Hydroxyl or Halogen
(42.11)where (AB)4 (XO4)3 Zq � x(H2O)
(42.11.06)Leucophosphite Group
42.11.06.01 Leucophosphite KFe2(PO4)2(OH)•2(H2O) P 21/n 2/m
42.11.06.02 Tinsleyite KAl2(PO4)2(OH)•2(H2O) P 21/n 2/m
42.11.06.03 Spheniscidite (NH4,K)(Fe,Al)2(PO4)2(OH)•2(H2O) P 21/n 2/m
08.DH.10 08 - PHOSPHATES, ARSENATES, VANADATES
08.D - Phosphates, etc
08.DH -With large and medium-sized cations, (OH, etc.):RO4 < 1:1
08.DH.10 Leucophosphite KFe2(PO4)2(OH)•2(H2O) P 21/n 2/m
08.DH.10 Spheniscidite (NH4,K)(Fe,Al)2(PO4)2(OH)•2(H2O) P 21/n 2/m
08.DH.10 Tinsleyite KAl2(PO4)2(OH)•2(H2O) P 21/n 2/m
Other Spheniscidite Information
NAME( AntBidBlaNic4) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990)
Links to other databases for Spheniscidite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - EUROmin Project
4 - Ecole des Mines de Paris
5 - GeoScienceWorld
6 - Google Images
7 - Google Scholar
8 - Handbook of Mineralogy (MinSocAm)
9 - Handbook of Mineralogy (UofA)
10 - MinDAT
11 - Mineralienatlas (Deutsch)
12 - Online Mineral Museum
13 - QUT Mineral Atlas
14 - Ruff.Info
15 - WWW-MINCRYST
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Spheniscidite
(NH4,K)(Fe+++,Al)2(PO4)2(OH)•2(H2O)
Dana No: 42.11.06.03 Strunz No: 08.DH.10
Locality:
Notes: