Access to an unusual Fe9 core topology from the initial use of tricine in iron(III) cluster chemistry (original) (raw)

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* Corresponding authors

a WestCHEM, School of Chemistry, University of Glasgow, University Avenue, Glasgow, UK
E-mail: mark.murrie@glasgow.ac.uk
Fax: +44 141 330 4888
Tel: +44 141 330 4486

b Department of Chemistry, University of Bath, Claverton Down, Bath

Abstract

We describe an enneanuclear Fe(III) complex with an unusual boat-shaped core topology and an S = 11/2 ground state, assembled using the ligands tricine {_N_-(2-hydroxy-1,1-bis(hydroxymethyl)ethyl)glycine, H4L} and 2-phenoxybenzoate.

Graphical abstract: Access to an unusual Fe9 core topology from the initial use of tricine in iron(iii) cluster chemistry

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Article information

DOI

https://doi.org/10.1039/C0DT01712D

Article type

Communication

Submitted

06 Dec 2010

Accepted

03 Feb 2011

First published

24 Feb 2011

Download Citation

Dalton Trans., 2011,40, 3125-3127

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Access to an unusual Fe9 core topology from the initial use of tricine in iron(III) cluster chemistry

K. Graham, A. Ferguson, F. J. Douglas, L. H. Thomas and M. Murrie,Dalton Trans., 2011, 40, 3125DOI: 10.1039/C0DT01712D

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