Kinetic measurements and product studies used to determine the nucleophilicity of α-aryl vinyl azides (original) (raw)

Zitation: Thiruvengetam, Prabaharan und Gross, Christoph und Ofial, Armin: Kinetic measurements and product studies used to determine the nucleophilicity of α-aryl vinyl azides. 29. Dezember 2025. Open Data LMU. 10.5282/ubm/data.761

Kinetic measurements and product studies used to determine the nucleophilicity of α-aryl vinyl azides

Kinetic measurements and product studies used to determine the nucleophilicity of α-aryl vinyl azides

The zip file contains

(1) a folder named "kinetics", which contains

txt files with absorbance vs. time data;

exp files used for the k(obs) determination;

pdf files with results of the k(obs) determination.

Folder and file names CGxxx and PTxxx refer to individual experiments and are identical to those in the Supporting Information (docx/rtf/pdf).

(2) a folder named "products" which contains analytical data (NMR, IR, and HRMS) used to characterize the synthetically prepared vinyl azides as well as the amides isolated from the reactions of vinyl azides with benzhydrylium ions.

Folder and file names CGxxx and PTxxx for the characterized chemical compounds are identical to those in the Supporting Information (docx/rtf/pdf).

This Supplemental Material is part of an article published in Chemical Communications (doi.org/10.1039/D6CC00190D).

kinetics, product characterization, nucleophiles, time-resolved spectroscopy

Thiruvengetam, Prabaharan

29. Dez. 2025

2025

https://doi.org/10.5282/ubm/data.761

DOI: 10.5282/ubm/data.761

Dieser Datensatz steht unter der Creative Commons Lizenz

CC BY 4.0

Be­schrei­bung

The zip file contains (1) a folder named "kinetics", which contains txt files with absorbance vs. time data; exp files used for the k(obs) determination; pdf files with results of the k(obs) determination. Folder and file names CGxxx and PTxxx refer to individual experiments and are identical to those in the Supporting Information (docx/rtf/pdf). (2) a folder named "products" which contains analytical data (NMR, IR, and HRMS) used to characterize the synthetically prepared vinyl azides as well as the amides isolated from the reactions of vinyl azides with benzhydrylium ions. Folder and file names CGxxx and PTxxx for the characterized chemical compounds are identical to those in the Supporting Information (docx/rtf/pdf). This Supplemental Material is part of an article published in Chemical Communications (doi.org/10.1039/D6CC00190D).

Stichwörter

kinetics, product characterization, nucleophiles, time-resolved spectroscopy

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