Hydrogeochemical characteristics, temporal, and spatial variations for evaluation of groundwater quality of Hamedan–Bahar Plain as a major agricultural region, West of Iran (original) (raw)
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Engineering, Technology & Applied Science Research
This study aims to evaluate the hydrogeochemistry of aquifers in Fars province, Iran, from 2007 to 2017 and assess the groundwater’s suitability for drinking and agricultural uses. A total of 35,000 samples were collected from wells and qanats across the province. Piper, Gibbs, and Durov diagrams were used to assess the hydrochemical facies and processes. Cross plots of different ions were investigated to assess ion exchange and determine the effects of anthropogenic activities, as well as the weathering and dissolution of different rocks and minerals in the aquifers. Groundwater quality and suitability for agricultural and drinking purposes were also assessed using physicochemical parameters including pH, Electrical Conductivity (EC), Total Dissolved Solids (TDS), Total Hardness (TH), and calcium, magnesium, sodium, potassium, bicarbonate, sulfate, and chloride concentrations. Suitability for domestic purposes was assessed by comparing these values with the WHO standards. Sodium an...
Journal of Advances in Environmental Health Research (JAEHR), 2021
Background: The physicochemical composition of groundwater is affected by the quantity and quality of surrounding aquifers which are in turn recharging from adjacent river waters. Methods: In the present study, 20 surface and 16 groundwater samples were collected in pre- and post-monsoon season from the Jajrood River basin, Tehran, Iran. The samples were analyzed for 18 physicochemical water quality characteristics to assess the river and groundwater qualities. Hydrogeochemical analyses of groundwater samples were also performed to determine the Water Quality Index (WQI) for drinking and evaluate factors governing the water quality characteristic in the study area. Accordingly, the Piper diagram and Gibbs and Chadha plots were drawn to assess seasonal variations in hydrochemical facies and processes in the basin. Subsurface soil samples were also examined with respect to the structure, elemental composition, and multi-elemental trace analysis. Results: Results showed the abundance of major ions in the order of Ca+2 >Na+>Mg+2>K+ for cations and HCO3- >SO42- >Cl- >NO3- >F- for anions. In general, all drinking groundwater samples met WHO permissible limits except for Chemical Oxygen Demand (COD) and HCO3-. Moreover, the water is categorized as Ca-Mg-HCO3 type. Subsurface soil analyses demonstrated quartz and calcium carbonate as the main phases of soil structure, suggesting the enrichment of groundwater with temporary hardness. Conclusion: Overall, the groundwater quality was suitable for drinking and agricultural activities.
Chemie der Erde - Geochemistry, 2014
The Janah alluvial aquifer is located in southern Iran with an arid climate. The type of groundwater in this aquifer is dominantly of sodium chloride and total dissolved solid of groundwater samples range from 1.63 to 335 g/L which confirms that groundwater quality has been severely degraded by salinization. Hydrogeochemical and isotopic investigations were conducted to identify the source of salinity. Total dissolved solids and major ion concentrations were measured at 51 selected sampling sites including springs, wells and surface waters. In addition stable isotopic composition (oxygen-18 and deuterium) was measured in 6 sampling points. The study indicates that the sources of salinity of the Janah aquifer include dissolution of salt diapir and evaporite rocks, a geothermal spring and intrusion of the river water which function individually or together in different parts of the aquifer. Based on the hydrogeochemical and geological studies conceptual flow models were prepared for different parts of the aquifer which illustrate how each source of salinity deteriorates the quality of the alluvial aquifer. We proposed few remediation methods including construction of cemented channel and sealed basins to improve groundwater quality. These methods would prevent infiltration of low quality water into the alluvial aquifer.
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Hydrogeochemical investigations of groundwater in Torbat-Zaveh plain have been carried out to assess the water quality for drinking and irrigation purposes. In this study, 190 groundwater samples were collected and analyzed for physicochemical parameters and major ion concentrations. The abundance of major cations and anions was in the following order: Na+ > Mg2+ > Ca2+ > K+, and Cl− > SO2−4 > HCO−3 > CO2−3. As a result, alkaline element (Na+) exceeds alkaline earth elements (Mg2+ and Ca2+), and strong acids (Cl− and SO2−4) dominate weak acids (HCO−3 and CO2−3) in majority of the groundwater samples. Statistical analyses including Spearman correlation coefficients and factor analysis display good correlation between physicochemical parameters (EC, TDS and TH) and Na+, Mg2+, Ca2+, Cl− and SO2−4. The results display that rock-weathering interactions and ion-exchange processes play important role in controlling groundwater chemistry. Saturation index values also indicate that water chemistry is significantly affected by carbonate minerals such as calcite, aragonite and dolomite. US Salinity Laboratory(USSL) and Wilcox diagrams together with permeability index values reveal that most of the groundwater samples are suitable for irrigation purpose. However, in some regions, the water samples do not indicate required irrigational quality.
Hydrogeochemistry study and groundwater quality assessment in the north of Isfahan, Iran
Environmental geochemistry and health, 2017
This study presents the groundwater quality assessment in the north of Isfahan, Iran. In the study area, assessment and measurement of groundwater hydrochemical parameters such as pH, total dissolved solids (TDS), electrical conductivity (EC), sodium absorption ratio (SAR), total hardness, major cations (K(+), Na(+), Ca(2+) and Mg(2+)) and major anions (Cl(-), [Formula: see text] and [Formula: see text]) concentrations were performed. Accordingly, the 66 water samples from different locations were collected during April and May 2015. Water samples collected in the field were analyzed in the laboratory for cations and anions using the standard methods. In this research, the analytical results of physiochemical parameters of groundwater were compared with the standard guideline values as recommended by the world health organization (WHO) for drinking and public health purposes. The pH values of groundwater samples varied from 7.05 to 8.95 with a mean of 7.78, indicating a neutral to s...
Groundwater for Sustainable Development, 2021
The hydrogeochemical and quality status of groundwater resources in Yazd province, the central plateau of Iran, has been investigated. The most common water type, followed by chemical facies in this study area, is Cl type (with 50.46%) and Na-Cl facies (47.71%), respectively. Besides, the most samples with industrial and agricultural uses show the Cl type and Na-Cl hydrochemical facies. The position of samples on the Gibbs and van Wirdum diagrams indicate that the water-rock interaction and dissolution of evaporites are the main controlling process of water chemistry. Distribution of samples based on Na/Cl vs. EC, Ca + Mg vs. SO 4 + HCO 3 , and Na-Cl vs. Ca + Mg-SO 4-HCO 3 highlight the significant role of direct ion exchange in water chemistry change. The water quality for agricultural use is assessed based on some indices including EC, Na%, sodium absorption ratio (SAR), residual sodium carbonate (RSC), magnesium absorption ratio (MAR), permeability index (PI), Kelly's ratio (KR), and Wilcox diagram. In general, the water quality for irrigation purposes is mainly excellent to permissible. The water quality assessment for industrial purposes is performed using some indices including Langelier Saturation Index (LSI), Ryznar Stability Index (RSI), Larson-Skold Index (L-SI), Puckorious scaling index (PSI), and total hardness (TH). Based on these indices, most groundwater samples have mild to high potential to corrode the equipment and pipelines.
Journal of Water and Land Development, 2019
Based on chemical analyses, the quality of ground waters for drinking, agricultural and industrial purposes was determined in Rafsanjan Plain-Iran. Samples for analyses were taken from 22 wells in 2012. Because of high water hardness and total dissolved solids content, water was found to be unsuitable for drinking purposes. Water quality for agriculture was determined with the use of the Wilcox method. Among the analysed water, 10.33% were attributed to C3-S1 class (high electrolytic conductivity and low sodium adsorption ratio), 59.5% to class C4-S1 (very high EC and low SAR) and 30.17% to class C4-S2 (very high EC and medium SAR). 89.67% of studied wells were unsuitable for agriculture. Because of corrosive water properties all but two wells on Rafsanjan Plain were undesirable for use in the industry. The results of qualitative analyses were presented in GIS and in databases to support making decision and management of groundwater on Rafsanjan Plain.
Assessment of groundwater quality and hydrochemical characteristics in Farashband plain, Iran
Arabian Journal of Geosciences, 2016
Groundwater in Farashband plain, Southern Iran, is the main source of water for domestic and agricultural uses. This study was carried out to assess the overall water quality and identify major variables affecting the groundwater quality in Farashband plain. The hydrochemical study was undertaken by randomly collecting 84 groundwater samples from observation wells located in 13 different stations covering the entire plain in order to assess the quality of the groundwater through analysis of major ions. The water samples were analyzed for various physicochemical attributes. Groundwater is slightly alkaline and largely varies in chemical composition; e.g., electrical conductivity (EC) ranges from 2314 to 12,678 μS/cm. All the samples have total dissolved solid values above the desirable limit and belong to a very hard type. The abundance of the major ions is as follows: Na + > Ca 2+ > Ma 2+ > K + and Cl − > SO 4 2-> HCO 3 −. Interpretation of analytical data shows three major hydrochemical facies (Ca-Cl, Na-Cl, and mixed Ca-Mg-Cl) in the study area. Salinity, total dissolved solids, total hardness, and sodium percentage (Na%) indicate that most of the groundwater samples are not suitable for irrigation as well as for domestic purposes and far from drinking water standard. A comparison of groundwater quality in relation to drinking water standards showed that most of the water samples are not suitable for drinking purposes. Based on the US salinity diagram, most of samples belong to high salinity and low to very high sodium type.
Preliminary assessment of groundwater hydrogeochemistry within Gilan, a northern province of Iran
In four basins of Gilan province, groundwater samples were collected from 127 piezometric wells to investigate the hydrogeochemistry of groundwater, and additionally its suitability for drinking and irrigation purposes. The average concentrations of major cations and anions follow the order of Ca 2+ > Na + > Mg 2+ > K + and HCO − 3 > Cl − > SO 2− 4 > CO 2− 3 , respectively. Using Piper diagram delineation, CaMgHCO 3 was determined as the main hydrogeochemical facies of groundwater. According to Piper diagrams, Gibbs plots, and ionic ratios, silicate weathering and ion exchange are the major processes regulating the groundwater hydrochemistry. Furthermore, saturation indices (SIs) revealed that carbonate precipitation also plays an important role in aquifers. Among the processes, weathering of silicate minerals seems to be the dominant process. Comparing the analyzed major ions and phys-icochemical parameters with the WHO guideline values indicates that the potability of most groundwater samples is generally acceptable. Electrical conductivity (EC) and total dissolved solid (TDS) measurements along with sodium percentage (SP), sodium adsorption ratio (SAR), Kelley's index (KI), and residual sodium carbonate (RSC) calculations suggest that groundwater in many areas is suitable for irrigation use. Nonetheless, total hardness (TH) values ranging as high as 650.0 mg/l reveal many groundwater samples to be classified as hard and very hard, indicating a requirement for long-term monitoring and further evaluation. The present study shows that the groundwater quality in Lahijan, Astaneh, and to a lesser extent Fouman drainage basins is lower than in Talesh. Therefore, intense monitoring programs towards enhanced water management practices are recommended before poorer quality groundwater is further utilized.
Groundwater for Sustainable Development, 2018
The suitability of rural groundwater quality for drinking purposes were investigated in the north west of Iran. Major anions, cations and heavy metals were measured in 39 water wells during the summer and spring seasons. The spatial distribution of major parameters and hydro-chemical faces were described by developing GIS-based maps and Piper and Gibbs diagrams. According to the results, the EC values were in the range of 461 and 2600 μs/cm with the hardness contents between 220 and 720 mg/L as CaCO 3. It was found that, the total hardness is highly correlated with the magnesium concentration than calcium in all samples. The dominant cations and anions were in the order of Mg 2+ > Na + > Ca 2+ > K + and HCO 3-> SO 4 2-> Cl-> NO 3-> F-, respectively. The major water types in the area were fresh (Ca-HCO 3) and saline (Ca-Mg-Cl). Based on Gibbs plot, the main mechanisms controlling groundwater chemistry were rainfall dominance, rock weathering dominance, and evaporationparticipation dominance. The lower quality of water resources sited in the southern and northern parts of the area was observed according to the GIS maps. It was found that