Quantum-chemical studies of hydrogen bonding involving thioxoketones, thienols, thioformaldehyde and hydrogen sulfide with specific reference to the strength of intramolecular hydrogen bonds (original) (raw)

Dioxygen Cleavage and Methane Activation on Diiron Enzyme Models: A Theoretical Study

Takehiro Ohta

Journal of the American Chemical Society, 1997

View PDFchevron_right

Dioxygen activation in enzymatic systems and in inorganic models

Constantinos Varotsis

Inorganica Chimica Acta, 1996

View PDFchevron_right

Synthesis, X-ray Structures, Electronic Properties, and O2/NO Reactivities of Thiol Dioxygenase Active-Site Models

Thomas Brunold

Inorganic Chemistry, 2016

View PDFchevron_right

The mechanism of methane and dioxygen activation in the catalytic cycle of methane monooxygenase

Albert Shteinman

FEBS Letters, 1995

View PDFchevron_right

Nuclear hyperfine coupling of nitrogen in the coordination sphere of the diiron center of methane monooxygenase hydroxylase

Jack Peisach

The Journal of Biological Chemistry, 1994

View PDFchevron_right

Carboxylate as the Protonation Site in (Peroxo)diiron(III) Model Complexes of Soluble Methane Monooxygenase and Related Diiron Proteins

Pierre Moënne-Loccoz

Journal of the American Chemical Society, 2010

View PDFchevron_right

Reactivity of methane mono-oxygenase, insights from quantum mechanic studies on synthetic iron model complexes

William Goddard

Journal of Molecular Catalysis A: Chemical, 2001

View PDFchevron_right

Dioxygen Activation at Non-Heme Diiron Centers: Oxidation of a Proximal Residue in the I100W Variant of Toluene/ o -Xylene Monooxygenase Hydroxylase †

Roman Davydov

Biochemistry, 2007

View PDFchevron_right

An abiotic analogue of the diiron(IV)oxo ‘‘diamond core’’ of soluble methane monooxygenase generated by direct activation of O2 in aqueous Fe(II)/EDTA solutions: thermodynamics and electronic structure

Leonardo Bernasconi, E. Baerends

View PDFchevron_right

Theoretical Study of the Mechanism of Alkane Hydroxylation and Ethylene Epoxidation Reactions Catalyzed by Diiron Bis-oxo Complexes. The Effect of Substrate Molecules

Djamaladdin Musaev

Journal of the American Chemical Society, 2002

View PDFchevron_right

Quantum-chemical study of the four-electron catalytic oxidation of water to dioxygen in the presence of dinuclear and tetranuclear hydroxide complexes of cobalt(III) and iron(III): Intermediates of the catalytic cycle and their relative energies

Valentin Parmon

Journal of Molecular Catalysis, 1994

View PDFchevron_right

Interplay of Electronic Cooperativity and Exchange Coupling in Regulating the Reactivity of Diiron(IV)-oxo Complexes towards C-H and O-H Bond Activation

Asmita Singha, Dr. Mursaleem Ansari

Chemistry: A European Journal, 2017

View PDFchevron_right

Dioxygen activation and bond cleavage by mixed-valence cytochrome c oxidase

Michelle Pressler

Proceedings of the …, 1998

View PDFchevron_right

Reaction Mechanisms of Metalloenzymes and Synthetic Model Complexes Activating Dioxygen : A Computational study

Valentin Georgiev

2009

View PDFchevron_right

Insights into the P-to-Q conversion in the catalytic cycle of methane monooxygenase from a synthetic model system

Lawrence Que

Proceedings of the National Academy of Sciences, 2008

View PDFchevron_right

The structure–activity relationships of methane mono-oxygenase mimics in alkane activation

William Goddard

Catalysis Today, 2003

View PDFchevron_right

Further Evidence for Multiple Pathways in Soluble Methane-Monooxygenase-Catalysed Oxidations from the Measurement of Deuterium Kinetic Isotope Effects

Christopher Samuel

European Journal of Biochemistry, 1994

View PDFchevron_right

Reactivity of Compound II: Electronic Structure Analysis of Methane Hydroxylation by Oxoiron(IV) Porphyrin Complexes

Angela Rosa

Inorganic Chemistry, 2012

View PDFchevron_right

Intermediates in the oxygenation of a nonheme diiron(II) complex, including the first evidence for a bound superoxo species

Lawrence Que

Proceedings of the National Academy of Sciences, 2005

View PDFchevron_right

O 2 Activation by Non-Heme Diiron Proteins: Identification of a Symmetric μ-1,2-Peroxide in a Mutant of Ribonucleotide Reductase †

Pierre Moënne-Loccoz

Biochemistry, 1998

View PDFchevron_right

From activation of dioxygen to formation of high-valent oxo species: Ab initio DFT studies

Malgorzata Witko

Journal of Molecular Catalysis A: Chemical, 2007

View PDFchevron_right

Moessbauer, EPR, and ENDOR studies of the hydroxylase and reductase components of methane monooxygenase from Methylosinus trichosporium OB3b

K Kristoffer Andersson

Journal of the American Chemical Society, 1993

View PDFchevron_right

Hydroxylation Catalysis by Mononuclear and Dinuclear Iron Oxo Catalysts: a Methane Monooxygenase Model System versus the Fenton Reagent Fe IV O(H 2 O) 5 2+

Evert-jan Baerends

Inorganic Chemistry, 2012

View PDFchevron_right

Modeling the Syn Disposition of Nitrogen Donors in Non-Heme Diiron Enzymes. Synthesis, Characterization, and Hydrogen Peroxide Reactivity of Diiron(III) Complexes with the Syn N -Donor Ligand H 2 BPG 2 DEV

Pierre Moënne-Loccoz

Journal of the American Chemical Society, 2009

View PDFchevron_right

Spectroscopic properties of the hydroxylase of methane monooxygenase

ROGER PRINCE

Biochimica et Biophysica Acta (BBA) - Protein Structure and Molecular Enzymology, 1988

View PDFchevron_right

De Novo Simulation and Spectroscopic Study of Iron Speciation in Micro-And Mesoporous Biomimetic Materials Active in the Selective Oxidation of Methane

Peter-Paul Knops-Gerrits

View PDFchevron_right

DFT Mechanistic Insight into the Dioxygenase-like Reactivity of a CoIII-peroxo Complex: O–O Bond Cleavage via a [1,3]-Sigmatropic Rearrangement-like Mechanism

CHAOSHEN ZHANG

Inorganic Chemistry, 2020

View PDFchevron_right

Ligation of the diiron site of the hydroxylase component of methane monooxygenase: An endor study

K Kristoffer Andersson

Journal of Inorganic Biochemistry, 1991

View PDFchevron_right

Kinetics of oxygen-atom transfer reactions involving molybdenum dithiolene complexes

Christian Lorber

Journal of The Chemical Society-dalton Transactions, 1997

View PDFchevron_right

Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective

Sumit Kumar Sahu

Journal of the American Chemical Society, 2016

View PDFchevron_right

Dioxygen Binding to Complexes with Fe II 2 (μ-OH) 2 Cores: Steric Control of Activation Barriers and O 2 Adduct Formation

Sanjay Mandal

Inorganic Chemistry, 2005

View PDFchevron_right

Controlled Oxidation of Hydrocarbons by the Membrane-Bound Methane Monooxygenase: The Case for a Tricopper Cluster

Steve Yu

Accounts of Chemical Research, 2008

View PDFchevron_right

Quantum mechanical/molecular mechanical study on the mechanisms of compound I formation in the catalytic cycle of chloroperoxidase: an overview on heme enzymes

K. Bebenek, Lalith Perera

The journal of physical chemistry. B, 2008

View PDFchevron_right