Chiral enolate design (original) (raw)

New chiral acetate imide enolate for stereoselective aldol reactions

Claudio Palomo

Tetrahedron Letters, 1996

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Enantioselective Generation and Diastereoselective Reactions of Chiral Enolates Derived from ?-Heterosubstituted Carboxylic Acids. Preliminary Communication

Reto Naef

Helvetica Chimica Acta, 1981

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Bifunctional chiral auxiliaries 7: Aldol reactions of enolates derived from 1,3-diacyl-imidazolidine-2-thiones and 1,3-diacylimidazolidin-2-ones

Gary Evans, Andrew A Mortlock

Tetrahedron, 1994

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Metal-assisted aldol condensation of chiral .alpha.-halogenated imide enolates: a stereocontrolled chiral epoxide synthesis

Ahmed Abdel-Magid

Journal of the American Chemical Society, 1986

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Direct asymmetric catalytic syntheses of alpha,beta-difunctional amino and hydroxy carbonyls via the bifunctional catalytic in-situ generation of chiral enolates

Gary Cutting

2006

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Asymmetric alkylation reactions of chiral imide enolates. A practical approach to the enantioselective synthesis of .alpha.-substituted carboxylic acid derivatives

David Mathre

Journal of the American Chemical Society, 1982

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Diastereoselective aldol reactions using .beta.-keto imide derived enolates. A versatile approach to the assemblage of polypropionate systems

George Sheppard

Journal of the American Chemical Society, 1990

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ChemInform Abstract: Chiral Ligands Containing Heteroatoms. Part 15. Cyclic β-Amino Alcohols as Chiral Inductors for Enantioselective Reductions of Ketones

Cristina Collu

ChemInform, 2010

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An improved method for the asymmetric protonation of enolates with chiral α-sulfinyl alcohols/trifluoroethanol

Gregorio Asensio

Tetrahedron: Asymmetry, 2001

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Enolate formation from cyclopropyl ketones via iodide-induced ring opening and its use for stereoselective aldol reaction

Hiroshi Shinokubo

Tetrahedron, 2001

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Chiral ligands containing heteroatoms. 15.1 cyclic β-amino alcohols as chiral inductors for enantioselective reductions of ketones

Cristina Collu

Tetrahedron: Asymmetry, 1996

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Highly Diastereoselective α-Hydroxylation of Fox Chiral Auxiliary-Based Amide Enolates with Molecular Oxygen

Arnaud Tessier

Organic Letters, 2010

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Alkylation of .alpha.-formamido ketone enolate anions. A versatile synthesis of .alpha.-alkyl .alpha.-amino ketones

Angel M Haycock

The Journal of Organic Chemistry, 1986

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Highly Stereoselective Kinetic Enolate Formation: Steric vs Electronic Effects

Linfeng Xie

The Journal of Organic Chemistry, 1997

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Addition to activated imines of enolates from chiral N-acyloxazolidinones

Isaac Abrahams

Tetrahedron, 1994

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Organic synthesis via enolates

Vimal Rarh

2008

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First synthesis of the chiral mixed O/S ligands, 1,2-sulfinyl thiols: application as chiral proton sources in enantioselective protonations of enolates

Gregorio Asensio

Tetrahedron: Asymmetry, 2000

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Traceless chirality transfer from a norbornene β-amino acid to pyrimido[2,1- a ]isoindole enantiomers

Kristóf Bozó

Tetrahedron: Asymmetry

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Asymmetric reactions of chiral imide enolates with α-keto esters

E.Prabhakar Reddy

Tetrahedron Letters, 1996

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Enantioselective synthesis of 3-amino-2-azetidinones via the ester enolate - imine condensation

George Britovsek

The Journal of Organic Chemistry, 1992

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Concerning the diastereofacial selectivity of aldol reactions of chiral methyl ketone enolates: Evidence for remote chelation in the bafilomycin aldol reaction

Thomas Bannister

Tetrahedron Letters, 1993

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Asymmetric aldol reactions using chiral CF3-Oxazolidines (Fox) as chiral auxiliary

Arnaud Tessier

Journal of Fluorine Chemistry, 2009

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Highly Regio and Stereospecific Palladium-Catalysed Allyation of Enolates from Ketones

Rob John

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A Desilylative Approach to Alkyl Substituted C(1)‐Ammonium Enolates: Application in Enantioselective [2+2] Cycloadditions

David Cordes

Angewandte Chemie

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Stereoselective syntheses of (+)-isoretronecanol and (+)-5-epi-tashiromine via addition of chiral titanium (iv) enolates to cyclic n-acyliminium ions

Ronaldo Aloise Pilli

2008

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Diastereoselective C-arylation of prochiral enolates by the SRN1 reaction

Sara Palacios

Chirality, 2004

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Aldol reactions of methyl (2-tributylstannyl)tetrahydrofuran-3-ylcarboxylate lithium enolate

Peter Quayle

Tetrahedron Letters, 1994

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Efficient asymmetric protonation of enolates with readily accessible chiral α-sulfinyl alcohols

Gregorio Asensio

Tetrahedron: Asymmetry, 1998

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Memory of Chirality (MOC) Concept in Imino-Aldol Reaction: Enantioselective Synthesis of α,β-Diamino Esters and Aziridines

SANDIPAN HALDER

The Journal of Organic Chemistry, 2013

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New approach to exclusive formation of both enantiomers of �-amino acid derivatives

Jesus De Los Santos

Tetrahedron, 2008

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Substrate Control in Enantioselective and Diastereoselective Aldol Reaction by Memory of Chirality: A Rapid Access to Enantiopure β-Hydroxy Quaternary α-Amino Acids

Régis Guillot

Organic Letters, 2014

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ChemInform Abstract: Highly Diastereoselective Synthesis of Enantiopure β-Trifluoromethyl β-Amino Alcohols from Chiral Trifluoromethyl Oxazolidines (Fox)

Julien Simon, Evelyne Chelain

2012

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A New Family of Modular Chiral Ligands for the Catalytic Enantioselective Reduction of Prochiral Ketones

Albert Moyano

The Journal of Organic Chemistry, 1999

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Bifunctional chiral auxiliaries 3: Synthesis of homochiral 1,3-diols via asymmetric aldol reactions of dialkylboron enolates of 1,3-dipropionyl-trans-4,5-diphenyl-imidazolidin-2-one and aldehydes

Andrew A Mortlock

Tetrahedron: Asymmetry, 1991

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New approach to exclusive formation of both enantiomers of β-amino acid derivatives

Ana Cardoso

Tetrahedron, 2008

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