EFFECT OF COOLING RATE ON STRESS-STRAIN BEHAVIOUR AND MICROSTRUCTURE OF A CU- ZN- SN ALLOY (original) (raw)

Effects of Deformation on Microstructure of Cu-Zn-Ni Alloy

The thermal and mechanical effects on microstructure of Cu-12.44%Zn-4.75%Ni (wt%) alloy were investigated. The effects mechanical on both rapidly cooled sample and slowly cooled sample obtained from Cu-Zn-Ni alloy were investigated by using scanning electron microscopy (SEM), X-ray diffraction techniques (XRD). The thermal energy changes of in the alloy were examined by means of differential scanning calorimetry (DSC). As a result of SEM observations, annealing twins structures are observed in rapidly and slowly cooled samples. According to pictures of the SEM and XRD, the stress applied to samples caused to lose existing annealing twins, and led to formation of slip planes lying parallel to each other in between plates. The stress-strain behaviour is associated with applied heat treatment effect to samples. It's shown that the intensities of XRD peaks to be decrease, as a result of the increase in cooling rate. This result indicates that density defects of crystal increases with rapidly cooled in the Cu-Zn-Ni alloy. In both samples of the thermal energy changes, at the process of diffusion transformation eutectoid separation reactions have been proved to exist.

Effect of Ni Content on Microstructure and Characterization of Cu-Ni-Sn Alloys

Materials (Basel, Switzerland), 2018

Cu-xNi-5Sn (wt %) alloys with a different Ni content were prepared by a powder metallurgy method. The effect of Ni content on the hardness and yield strength of Cu-xNi-5Sn (wt %) alloys was investigated. The microstructure, composition, and morphology of Cu-xNi-5Sn (wt %) alloys were observed by X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), and cold field emission scanning electron microscope (FESEM), respectively. Results indicate that the hardness and yield strength firstly increase and then decrease with the increase of Ni content and reach up to a maximum when Ni content is 12.5 wt %. Furthermore, the formation of the sandwich structure and needle-like phase is found in the grain, the grain boundary and intragranular precipitates are rich in both the Ni and Sn phase. The formation of the inerratic and suitable lamellar precipitates of sandwich structure and needle-like phase can be responsible for the good mechanical prope...

SEM and X-Ray Diffraction Studies On Microstructures in Cu-26.04%Zn-4.01%Al Alloy

Due to fact that Cu-based alloys are very sensitive to the thermal treatments, in scanning electron microscopy and X-ray diraction observations, according to the dierent quenching techniques Cu26.04%Zn4.01%Al alloys can display dierent product phases such as martensite and precipitation. Rapidly cooling sample was formed as M18R structure from the ordered DO3 phase and in the monoclinic case, β = 89.1 • determined for sample. It was seen that a α-precipitation (fcc) phase in the matrix is slowly cooling.

Microstructure and crystallographic properties of Cu77Zn21alloy under the effect of heat treatment

Materials at High Temperatures, 2018

The influence of heat treatment process on microstructure and physiochemical properties of Cu 77 Zn 21 alloy was studied. Samples were heated from 300 to 700°C for 15 minutes and gradually cooled to room temperature. Samples were characterized using mechanical testing and surface analysis techniques. It was observed that the grain size increases with the increasing temperature. The decrease in hardness is due to composition change of the Cu-Zn alloy attributed to zinc diffusion.XRD shows the presence of only α brass with a preferential orientation along the (111) plane. The analyses show that temperature affects the crystalline parameters. The rms microstrain was reduced mainly by thermal activation. The heat treatment promotes atomic diffusion and leads to a better crystallinity of the particles. The results of Raman investigations confirmed the changes in the Cu-Zn alloy surface composition with a clear enrichment in CuO. This behavior correlates with the results obtained by mechanical testing.

Microstructure and mechanical properties of ultra fine grained Cu–Zn and Cu–Al alloys produced by cryorolling and annealing

Materials Science and Engineering A-structural Materials Properties Microstructure and Processing, 2008

Using the high pressure torsion (HPT) deformation method the medium carbon steel (AISI 1045) was the experimental material used to conduct the deformation process. The torsion deformation experiment was performed at increased temperature of 400°C. The influence of deformation processing parameters, resolved shear strain c (number of turns N = 1-6) and applied pressure p (constant pressure of 7 GPa), was evaluated by microstructure analysis and mechanical properties. The strength behaviour was assessed by microhardness measurements across the disc to detect the positional hardening, by tensile tests and in situ measured torque. In situ measurement of torque during deformation allows characterizing the changes in mechanical properties due to the large shear deformation developed across the disc. To obtain absolute values of strength the ultimate tensile strength was measured in radial direction with respect to the deformed sample. From each deformed disc two sub-sized tensile test specimens with gauge length of 2.5 mm were machined. The tensile strength in samples increased markedly with the number of turns. The hardness measured at disc edge gradually increases as straining increases until it saturates after 2-3 turns. However, the hardness values at edge were different from those measured in disc centre and for applied straining no saturation was reached across the disc. The SEM and TEM investigations were carried out to analyze the fine microstructure evolution regarding the strain introduced. To follow the difference in strain distribution across the deformed disc the microstructure analysis was performed at edge and central site of the disc in order to evaluate the effect of the strain distribution. TEM investigation confirmed the increasing misorientation even in very small grains, the fragmentation and dissolution of the cementite lamellae, (diffuse cementite/ferrite boundaries), the alignment of the fragments to the shear plane with increasing deformation. Indistinct deformation of ferrite and preserved cementite lamellae morphology were found at the centre of the disc.

Cooling Rate and Fibrous Type Striated Deformations Effects on the Mechanical Properties of Sn– 8.6 wt. % Zn Alloy

— Sn-Zn alloy has been taken as one of the most important lead free solder alloys due to the toxicity and the alpha radiation of lead impurities. The influence of cooling rate on the mechanical and structural properties of Sn – 8.6 wt. % Zn lead free solder alloy was studied. The microstructure of the quenched and slowly cooled samples of Sn – Zn alloy was examined by X – rays analysis and Scanning electron microscopy (SEM). There is an appearance of fibrous type striated deformations on the surfaces of the quenched samples more than those on the surfaces of the slowly cooled samples. The hardening parameters were obtained through stress-strain relations in the temperature range 333-393K for slowly cooled and quenched samples. The quenching samples indicated an improvement in the mechanical properties. The energy activated the rate controlling mechanisms has been calculated and found to be 17.85 and 24.57 kJ/mol for slowly cooled and quenched samples respectively. These values were found to be close to those reported for the grain boundary sliding mechanism in Sn-based alloys.

X-ray diffraction studies of the decomposition and microstructural characterization of cold-worked powders of Cu–15Ni–Sn alloys by Rietveld analysis

Journal of Alloys and Compounds, 2004

The present work concerns study of the precipitation sequence due to aging below the critical aging temperature of cold-worked powder samples of industrially important Cu-Ni-Sn alloys with compositions, wt.% Sn. The analysis adopts a recently developed JAVA based software Materials Analysis Using Diffraction (MAUD), based on Rietveld's whole X-ray pattern fitting methodology. The evoluted phases have been characterized microstructurally in terms of different defect parameters, namely, stacking, twin and compound fault probabilities, crystallite (domain) sizes, microstrains (root mean square, rms strains), dislocation densities, preferred orientation parameters, etc. The analysis also includes quantitative estimation of phase abundances of the precipitating phases. The decomposition due to aging with varying Sn composition and aging period has been critically studied and the percentage of volume fraction of the evoluted phases has been evaluated and compared. The results depict, for the three different alloy compositions, three distinct different types of precipitation sequence comprising ␣, ␥ and ␦ phases with continuously varying volume fractions with aging time. The size-strain-shape analysis adopting the Popa model reveals almost isotropic values of both the crystallite sizes and rms strains in all [h k l] directions for the evoluted phases. The values of all the above defect parameters have been evaluated and compared for elucidating a better structure-property relationship. .in (M. De).

A DSC analysis of thermodynamic properties and solidification characteristics for binary Cu–Sn alloys

The liquidus temperatures and enthalpies of fusion for Cu–Sn alloys are systematically measured across the whole composition range by differential scanning calorimetry (DSC). The liquidus slope vs. Sn content is derived on the basis of the measured results. The measured enthalpy of fusion is related to the Sn content by polynomial functions, which exhibit one maximum value at 55 wt.% Sn and two minimum values around 28.9 wt.% Sn and 90 wt.% Sn, respectively. The undercoolability of those liquid alloys solidifying with primary a (Cu) solid solution phase is stronger and can be further enhanced by increasing the cooling rate. However, other alloys with the preferential nucleation of intermetallic compounds display smaller undercoolings and are not influenced by cooling rate. Microstructural observations reveal that peritectic reactions can rarely be completed. With the increase in undercooling, the primary a (Cu) dendrites are refined in the peritectic Cu–22 wt.% Sn alloy. For the hyperperitectic Cu–70 wt.% Sn alloy, typical peritectic cells are formed in which the peritectic g(Cu 6 Sn 5) phase has wrapped the primary e(Cu 3 Sn) phase. The DSC curves of metatectic-type Cu–Sn alloys indicate that the metatectic transformation c ! e + L upon cooling is an exothermic event, and a large undercooling of 70 K is required to initiate this transformation in metatectic Cu–42.5 wt.% Sn alloy. The metatectic microstructures are characterized by (e + g) composite structures. The g phase is mainly distributed at the grain boundaries of the coarse e phase, but are also dispersed as small particles inside e grains. The volume fraction of the g phase increases with the Sn content.

Effect of Cold Rolling and Annealing Temperature on the Characteristics of Cu-28Zn-3.2Mn Alloy

IOP Conference Series: Materials Science and Engineering

Common material for bullet shell is cartridge brass which contains 26-32 wt. % Zn. In the deep drawing process, problems are typically found, such as cracking and tearing, due to low ductility. Therefore, manganese is added to cartridge brass to increase its ductility. In this study, Cu-28Zn alloy with addition of 3.2 wt. % Mn was fabricated by gravity casting. As cast samples were homogenized at 800 °C for 2 hours. Afterwards, the specimens were cold-rolled with deformation of 20, 40, and 70 %. The 70 % cold-rolled samples were subsequently annealed at 350, 400, and 450 ℃ for 15 minutes. Samples underwent characterizations by microstructure analysis using optical microscope and Scanning Electron Microscope (SEM)-Energy Dispersive Spectroscopy (EDS), and Vickers microhardness testing. The results showed that higher degree of deformation led to more elongated grains with increasing values of L/D ratio, and higher hardness. Annealing at 350 ℃ for 15 min did not change the deformed microstructures which indicated the stage of recovery and stress relieve. Meanwhile, higher annealing temperatures of 400 and 450 ℃ led to recrystallization and grain growth, respectively. Hardness declined with the increase in annealing temperature. Mn increases the hardness and recrystallization temperature.

Microstructure and Mechanical Behavior of Hot Pressed Cu-Sn Powder Alloys

Advances in Materials Science and Engineering, 2016

Cu-Sn based alloy powders with additives of elemental Pb or C were densified by hot pressing technique. The influence of densifying on the properties of the hot pressed materials was investigated. The properties, such as the hardness, compressive strength, and wear resistance of these materials, were determined. The hot pressed Cu-Sn specimens included intermetallic/phases, which were homogeneously distributed. The presence of graphite improved the wear resistance of Cu-Sn alloys three times. Similarly, the presence of lead improved the densification parameter of Cu-Sn alloys three times. There was no significant difference in the mechanical behavior associated with the addition of Pb to the Cu-Sn alloys, although Cu-Pb alloys showed considerably higher ultimate strength and higher elongation. The Cu-Sn-C alloys had lower strength compared with those of Cu-Sn alloys. Evidence of severe melting spots was noticed in the higher magnifications of the compression fracture surface of 85% Cu-10% Sn-5% C and 80% Cu-10% Sn-10% Pb alloys. This was explained by the release of load at the final event of the fracture limited area.