Method validation and evaluation of household processing on reduction of pesticide residues in tomato (original) (raw)
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Effectiveness of Common Household Washing of Tomatoes on the Removal of Pesticide Residues
2021
The effectiveness of common household washing processes of tomatoes on the removal of pesticide residues was investigated in Iringa, Tanzania. Analyses of cleaned-up extracts were carried out using gas chromatography-mass spectrometry (GC-MS). Nine pesticide residues were detected in unwashed and washed samples. The compounds detected were chlorothalonil, pirimiphos-methyl, chlorpyrifos, profenofos, endosulfan sulphate, endosulfan ether, lambda cyhalothrin, cypermethrin and metalaxyl. The concentrations of chlorothalonil, pirimiphos-methyl, chlorpyrifos, profenofos, cypermethrin and lambda cyhalothrin in some unwashed and washed samples exceeded the maximum residue limits (MRLs). Washing reduced the concentrations of chlorothalonil and endosulfan sulphate in tomatoes by 22.2–98.0% (mean = 70%) and 33.3–55.6% (mean = 44.4%), respectively. The effectiveness of washing processes on the removal of pirimiphos methyl, chlorpyrifos and profenofos residues in tomatoes had mean values of 78....
Removal of Pesticide Residues from Tomato and its Products
Journal of Basic & Applied Sciences, 2014
Plant protection agents (more commonly known as pesticides) are widely used in agriculture to increase the yield, improve the quality and extend the storage life of food crops. The study was carried out in order to determine the effectiveness of various traditional processing treatments on reducing the residual load of pesticides from tomato and its products. Results showed that lipid soluble pesticides residues were reduced most effectively in sun-drying (90-97%) followed by frying (91-99%) and thermal dehydration (89-90%). The data further indicated that profenofos residues dislodged more effectively than bifenthrin and endosulfan. The least reduction was noticed in endosulfan residues. Similarly in case of water soluble pesticides, the effect of sun-drying, frying and thermal dehydration on reduction of pesticide residues were within the range of 94-97%, 92-96% and 91-96%, respectively. Maximum reduction was found in emamectin benzoate residues followed by imidacloprid and diafen...
2013
Metalaxyl is a widely used fungicide around the world. Very limited data have been reported concerning the dissipation and residue of metalaxyl in agricultural products. Residues and dissipation rate of metalaxyl were estimated in tomato fruit by HPLC following single application of the fungicide at 262.5 g a.i. ha À1 . The average initial deposit of metalaxyl on tomato fruits was found to be 2.39 mg kg À1 . Residues of metalaxyl dissipated below the maximum residue limit (MRL) of 0.5 mg kg À1 in 7 days. Half-life (t 1/2 ) for degradation of metalaxyl on tomato fruit was observed to be 1.81 days. A waiting period of 7 days is suggested for safe consumption of tomato. The results would be useful for the safe use of metalaxyl and to prevent any health problem to customers. ª 2012 King Saud University. Production and hosting by Elsevier B.V. All rights reserved. *
Effects of Types of Washing and Peeling in Relation to Pesticide Residues in Tomatoes
Journal of the Brazilian Chemical Society, 2015
Tomatoes are widely consumed and most often without cooking, therefore it is important to estimate the reduction of residues using simple washing procedures. An experiment was carried out to evaluate the effects of household processing such as: washing with water, washing with 10% of vinegar solution and washing with 10% of sodium bicarbonate solution on pesticide residue levels of acetamiprid, azoxystrobin, diflubenzuron, dimethoate, fipronil, imidacloprid, procymidone and thiamethoxam, in spiked tomato samples. The amount of residue remaining in the peel and pulp was also investigated. The pesticide residues were monitored using the quick, easy, cheap, effective, rugged and safe (QuEChERS) extraction and analysed by liquid chromatography tandem mass spectrometry method (LC-MS/MS) in dynamic multiple-reaction monitoring mode (DMRM). The effect of the number of washing treatments (n = 3) and control, with six replicates, differed significantly for all pesticides evaluated (n = 8), but despite washing, fipronil residues were not removed from the tomato samples. Overall, washing with water or other solutions, and peeling before consumption are shown to reduce pesticide residues in tomatoes.
Journal of the Brazilian Chemical Society, 2011
A cultura do tomate é frequentemente afetada por pragas, doenças e estresses abióticos, resultando em menor produtividade e perda de qualidade dos frutos. O uso intensivo de pesticidas em tomates sem utilização das boas práticas agrícolas tem causado grande preocupação quanto à provável contaminação do produto final. O método QuEChERS foi utilizado para a determinação de seis pesticidas (buprofezina, carbofurano, α-endosulfan, β-endosulfan, sulfato de endosulfan e monocrotofós) em amostras de tomate coletadas em supermercados. O método envolveu a extração líquido-líquido com acetonitrila, adição de MgSO4 e NaCl seguida de extração em fase sólida dispersiva com PSA (amina primária secundária) e as análises foram realizadas com cromatografia gasosa/espectrometria de massa ion trap. O estudo de recuperação para os pesticidas variou de 71 a 111% e o desvio padrão relativo foi inferior a 15%. Não foram detectados resíduos de pesticidas (> LOD) nas trinta e três amostras de tomate analisadas. Tomato crop is frequently damaged by diseases, pests and abiotic stresses, resulting in lower yielding and loss of fruit quality. The intensive use of pesticides in tomatoes without observation of good agriculture practices and regulations has caused great concern with a probable final product contamination. The QuEChERS method of sample preparation was used for the determination of six pesticides (buprofezin, carbofuran, endosulfan-α, endosulfan-β, endosulfan sulfate and monocrotophos) in thirty three tomato samples collected from local market retailers. The method involved extraction with acetonitrile, liquid-liquid partition with addition of MgSO 4 and NaCl followed by dispersive solid phase extraction using primary secondary amine sorbent and the analyses were carried out with a gas chromatography/mass spectrometry equipment by ion trap. Recovery studies for different pesticides ranged from 71 to 111% and the relative standard deviation (RSD) was below 15%. No pesticide residue was detected (> LOD) among the thirty three tomato samples analysed.
International Journal of Food Properties, 2017
The removal of pesticide residues is essential in order to control and reduce the harmful effects of pesticides commonly used in agriculture. The aim of this study was to investigate the effectiveness of 18 different household washing solutions for the reduction of methomyl and acetamiprid residues from tomatoes. These basic household solutions were used to prepare washing solution to remove pesticides. During this study, tomatoes were divided into two groups: in the first group, tomatoes were treated with the pesticides and the second group was washed with household solutions (distilled water, acetic acid, sodium chloride, ethanol, sodium bicarbonate, hydrogen peroxide, sodium hypochlorite, and liquid soap, lemon juice, mineral water, zam-zam water, whey, milk, and their combinations) after treating with pesticides. The pesticides residues in all samples were extracted by the QuEChERS technique, analyzed by LC-MS/MS. The results showed significant reduction in residues of all washed groups compared with the control (p < 0.01). Acetic acid, sodium chloride+sodium bicarbonate, zam-zam water, acetic acid+sodium chloride, sodium hypochlorite, milk, acetic acid+sodium chloride+sodium bicarbonate, liquid whey, liquid soap, lemon juice, ethanol, and sodium bicarbonate were found to remove more than 50% of both pesticide residues. The effectiveness of washing solutions was different for every type of pesticide. In the same way, blend of washing solutions has shown a synergetic effect on the removal of pesticides and was more effective compared to one solution. This research has raised the potential use of household solutions easily found at home that could be used to remove pesticide residues.
Development of MSPD method for the determination of pesticide residues in tomato by GC-MS
Journal of The Brazilian Chemical Society, 2006
Um método simples e eficiente baseado na técnica de dispersão da matriz em fase sólida foi desenvolvido para determinar resíduos de dimetoato, parationa-metílica, malationa, tebuconazol, e cipermetrina em tomate, por cromatografia gasosa acoplada a espectrometria de massas no modo de monitoramento de íons selecionados. Diferentes parâmetros foram avaliados, tais como: tipo (C 18 , alumina, sílica-gel e Florisil) e quantidade de sorbente e solvente de eluição (diclorometano, acetato de etila, n-hexano e n-hexano:acetato de etila (1:1 e 1:3, v/v)), sendo que o mais adequado foi alumina na proporção matriz:sorbente de 4:1 (m/m), Florisil como sorbente de purificação e diclorometano como solvente de eluição. Recuperações médias (n=7) de tomates fortificados (0,05-4,0 mg kg-1) variaram de 77 a 100%, com coeficiente de variação entre 3,7% e 12,9%. Os limites de detecção variaram entre 0,01 e 0,02 mg kg-1 , enquanto que os limites de quantificação variaram entre 0,03 e 0,06 mg kg-1. O método foi aplicado em amostras de tomates coletadas na cidade de Aracaju, SE, sendo que resíduos de parationa-metílica, malationa e dimetoato foram detectados, porém abaixo dos limites máximos de resíduos (LMRs) estabelecidos pela legislação brasileira e pelo Codex Alimentarius. A simple and effective extraction method based on matrix solid-phase dispersion was developed to determine dimethoate, methyl-parathion, malathion, tebuconazole and cypermethrin in tomato using gas chromatography-mass spectrometry and selected ion monitoring (GC-MS, SIM). Different parameters of the method were evaluated, such as type of solid phase (C 18 , alumina, sílica-gel and Florisil), the amount of solid phase and eluent [dichloromethane, ethyl acetate, n-hexane and n-hexane:ethyl acetate (1:1 and 1:3, v/v)]. The best results were obtained using 2.0 g of tomato, 0.5 g of alumina as dispersant sorbent, 0.5 g of Florisil as clean-up sorbent and dichloromethane as eluting solvent. The method was validated by fortified tomato samples at different concentration levels (0.05 to 4.0 mg kg-1). Average recoveries (7 replicates) ranged from 77% to 100% with relative standard deviation between 3.7% and 12.9%. Detection and quantification limits ranged from 0.01 to 0.02 mg kg-1 and 0.03 to 0.06 mg kg-1 for the whole fruit of tomato, respectively. The proposed method was applied to analyze of these compounds in commercial tomato samples and residues of methyl-parathion, dimethoate and malathion were detected on the tomato samples at concentrations below the maximum residue levels (MRLs) established by Brazilian legislation and Codex Alimentarius.
Farm to table: Residues of different pesticides in tomato and tomato juice – Food safety aspects
Acta Veterinaria Hungarica
During plant cultivation, the pesticides can get into the tissue of vegetables due to crop protection processes, and thus into the food chain. Therefore, they constitute a potential risk to the consumer's health. Depletion of pesticides [spirotetramat (Movento), azoxystrobin and difenoconazole (Amistar Top)] was monitored by testing tomatoes treated individually or simultaneously and tomato juices prepared from the treated tomatoes. The investigations aimed to reveal any kinetic interaction between the compounds tested and changes in their elimination, and thus to assess their compliance with the official Maximum Residue Limits (MRLs). The co-presence of pesticides prolonged the elimination of the individual compounds which reached significantly higher residue levels (P < 0.0001) in tomato, especially difenoconazole (45%) and azoxystrobin (50%) on day 8 after treatment that can cause food safety issues to the human consumers. However, the concentrations of pesticides applied ...
Analytical Methods in Environmental Chemistry Journal
The present study aimed to extract pesticide residues in the field and greenhouse-grown tomatoes and homemade paste based on the (QuEChERS) method before being determined by liquid chromatography-mass spectrometry (LC-MS). The mean difference in percentage reduction of deltamethrin (DLM) and acetamiprid (ACT) in raw tomatoes of greenhouse-grown was obtained at 91.42 and 90.00%, respectively, which was insignificantly more than filed condition (84.91% and 86.34%). Maximum reduction percentages of the DLM in paste under greenhouse and field tomato conditions were achieved by more than 95.86% and 93.11%, respectively. The residual concentration of both DLM (91.42%) and ACT (90.00%) in the greenhouse decreased more than the field (84.91% and 86.34%), respectively. Abamectin(ABA) reached below the MRL in a shorter time after spraying (2 days). Considering the pre-harvest interval (PHI) period of deltamethrin and abamectin can reach their residual concentration to the MRL in both conditi...
Persistence use of pesticide residue leaves behind toxic residues on the crop surface. Upon ingestion of these exposed food crops is hazardous to human health in addition to polluting the ecosystem. Different classes of pesticides have been detected in vegetables and fruits offered for the market in many parts of the globe. Their levels exceed the set maximum limits and therefore are of concern. In the current work, spinach, tomatoes and potatoes were treated with chlorpyrifos, chlorothalonil, pentachlorophenol and lambda cyhalothrin and subjected to various aqueous chemical solutions to determine the pesticide reduction efficiency. The washing solutions were: 0.9% NaCl, 0.1% NaHCO3, 0.001% KMnO4 and 0.1% acetic acid (5% Distilled vinegar) and distilled water. After washing, degration of residues in washing solutions and reduction levels were determined by UV-Visible spectrophotometer. 0.001 % KMnO4 washing solution was found to be most effective in reducing the pesticide residues which was due to the high degree in the pesticide degradation. Key words: pesticide residues, degradation, effectiveness, toxic, maximum residue levels