Hydridometallacycloalkane complexes of iridium. Unassisted intramolecular distal carbon-hydrogen bond activation (original) (raw)

Hydrido formyl, methoxycarbonyl, hydroxymethyl, and methyl complexes of iridium: syntheses and reactivities

David Thorn

Organometallics, 1982

View PDFchevron_right

Labile Hydrido Complexes of Iridium(III): Synthesis, Dynamic Behavior in Solution, and Reactivity toward Alkenes

Jose Lopez

Organometallics, 1999

View PDFchevron_right

C−H Activation and C−C Coupling Reactions in 2-Vinylpyridine Cationic Complexes of Iridium

Eduardo Sola

Organometallics, 2004

View PDFchevron_right

Polynuclear iridium hydrido complexes

Pierre Braunstein

Coordination Chemistry Reviews, 1989

View PDFchevron_right

C–H Bond Activation by Cationic Iridium(III) NHC Complexes: A Combined Experimental and Computational Study

Werner Kaminsky

Organometallics, 2012

View PDFchevron_right

Synthesis and X-ray structures of cyclometalated iridium complexes including the hydrides

Jianliang Xiao

Dalton Trans., 2013

View PDFchevron_right

Activation of carbon-hydrogen bonds in alkanes and other organic molecules by Ir(I), Rh(I) and Ir(III) complexes

Bruce Weiller

Pure and Applied Chemistry, 1995

View PDFchevron_right

Reactivity of the parent amido complexes of iridium with olefins: C–NH2 bond formation versus C–H activation

Fernando Lahoz

Dalton Transactions, 2017

View PDFchevron_right

Stoichiometric and Catalytic H/D Incorporation by Cationic Iridium Complexes: A Common Monohydrido-Iridium Intermediate

Marc Skaddan

Journal of the American Chemical Society, 2004

View PDFchevron_right

“Pincer” Pyridine-Dicarbene-Iridium Complexes: Facile CH Activation and Unexpected η 2 -Imidazol-2-ylidene Coordination

Andreas Danopoulos

Angewandte Chemie International Edition, 2008

View PDFchevron_right

Formation of Hydrido–η3Allyl Complexes of IrIII by Sequential Olefinic CH Bond Activation and CC Coupling of Alkenyl and Olefin Ligands

Enrique Gutiérrez

Chemistry-a European Journal, 1997

View PDFchevron_right

Cooperative Bimetallic Effects on New Iridium(III) Pyrazolate Complexes: Hydrogen−Hydrogen, Carbon−Hydrogen, and Carbon−Chlorine Bond Activations

José López

Organometallics, 1998

View PDFchevron_right

Remarkable Base Effect in the Synthesis of Mono and Dinuclear Iridium(I) NHC Complexes

christophe raynal

Organometallics, 2009

View PDFchevron_right

Iridium(I), Iridium(III), and Iridium(V) Complexes Containing the (2-Methoxyethyl)cyclopentadienyl Ligand †

Francisco J. Fernández-Alvarez

Organometallics, 2006

View PDFchevron_right

Thermal and photochemical carbon-hydrogen bond reactions of alkenes in (tris(pyrazolyl)borato)iridium(I) complexes

Robin Tanke

Inorganic Chemistry, 1989

View PDFchevron_right

Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes

Natalia Belkova

Mendeleev Communications, 2019

View PDFchevron_right

Trifunctional pNHC, Imine, Pyridine Pincer-Type Iridium(III) Complexes: Synthetic, Structural, and Reactivity Studies

Pierre Braunstein

Organometallics, 2015

View PDFchevron_right

Syntheses and reactions of a cationic hydrido(hydroxymethyl)iridium complex. The crystal and molecular structure of hydrido(hydroxymethyl)tetrakis(trimethylphosphine)iridium(III) hexafluorophosphate, [IrH(CH2OH) (PMe3)4][PF6]

Thom Tulip

Organometallics, 1982

View PDFchevron_right

The interaction of a cyclo-octa-1,5-diene-iridium complex with molecular hydrogen

Michele Rossi

Inorganica Chimica Acta, 1973

View PDFchevron_right

Cyclometalated Iridium(III) Complexes Containing Hydroxide/Chloride Ligands: Isolation of Heterobridged Dinuclear Iridium(III) Compounds Containing μ-OH and μ-Pyrazole Ligands

kelvin chen

Inorganic Chemistry, 2012

View PDFchevron_right

C−H Bond Activations by New Labile η6-Arene Complexes of Iridium

Fernando Lahoz

Journal of the American Chemical Society, 1999

View PDFchevron_right

The migratory insertion of carbon monoxide in pentamethylcyclopentadienyliridium (III) complexes. Structural effects on reactivity and mechanism for rhodium and iridium systems

Peter Maitlis, Mauro Bassetti, Anthony Haynes

Inorganica Chimica Acta, 1995

View PDFchevron_right

Room-temperature synthesis of cyclometalated iridium(iii) complexes: kinetic isomers and reactive functionalities

Ayan kumar Maity

Chemical Science, 2013

View PDFchevron_right

C−H Bond Activations by New Labile η 6 -Arene Complexes of Iridium

Eduardo Sola

Journal of the American Chemical Society, 1999

View PDFchevron_right

Synthesis and Reactivity of New Complexes of Rhodium and Iridium with Bis(dichloroimidazolylidene) Ligands. Electronic and Catalytic Implications of the Introduction of the Chloro Substituents in the NHC Rings

Elena Mas Marzá

Organometallics, 2006

View PDFchevron_right

Iridium alkoxide and amide hydride complexes. Synthesis, reactivity, and the mechanism of oxygen-hydrogen and nitrogen-hydrogen reductive elimination

David Glueck

Organometallics, 1991

View PDFchevron_right

Isolation and characterization of iridium(iii) and iridium(v) complexes of 2-(arylazo)pyridine and studies of amine fusion reactions at the coordinated diazo-ligandElectronic supplementary information (ESI) available: Fig. S1: 1H NMR spectra of 1a and tcc-[RuCl2(HL1a)2] in CDCl3. Inset: Methyl re...

Chayan Das

Dalton Transactions, 2004

View PDFchevron_right

Iridium−Germanium and −Tin Carbonyl Complexes

Eszter Trufan

Organometallics, 2010

View PDFchevron_right

Reactivity of the parent amido complexes of iridium with olefins: C–NH2 bond formation versus C–H activation

Miguel Casado

Dalton Trans., 2017

View PDFchevron_right

Evidence for C−H···X−Ir (X = Cl or I) Hydrogen Bonding between Imidazolium Salts and Iridium-Bound Halides and Formation of Ir(I) NHC Complexes †

Pierre Braunstein

Organometallics, 2010

View PDFchevron_right

Addition of N–H bonds to iridium: Synthesis and characterization of N–Ir–H complexes and the observation that an iridium N-bonded indole ring becomes activated for Michael addition to alkynes

Folami Ladipo, Joseph Merola

Polyhedron, 2015

View PDFchevron_right