Pyrolytic oil from fluidised bed pyrolysis of oil palm shell and its characterisation (original) (raw)

Characterization of Bio-Oil From Palm Kernel Shell Pyrolysis

JOURNAL OF MECHANICAL ENGINEERING AND SCIENCES, 2014

Pyrolysis of palm kernel shell in a fixed-bed reactor was studied in this paper. The objectives were to investigate the effect of pyrolysis temperature and particle size on the products yield and to characterize the bio-oil product. In order to get the optimum pyrolysis parameters on bio-oil yield, temperatures of 350, 400, 450, 500 and 550 °C and particle sizes of 212-300 µm, 300-600 µm, 600µm-1.18 mm and 1.18-2.36 mm under a heating rate of 50 °C min-1 were investigated. The maximum bio-oil yield was 38.40% at 450 °C with a heating rate of 50 °C min-1 and a nitrogen sweep gas flow rate of 50 ml min-1. The bio-oil products were analysed by Fourier transform infra-red spectroscopy (FTIR) and gas chromatography-mass spectroscopy (GCMS). The FTIR analysis showed that the bio-oil was dominated by oxygenated species. The phenol, phenol, 2-methoxy-and furfural that were identified by GCMS analysis are highly suitable for extraction from the bio-oil as value-added chemicals. The highly oxygenated oils need to be upgraded in order to be used in other applications such as transportation fuels.

Production and detailed characterization of bio-oil from fast pyrolysis of palm kernel shell

Biomass and Bioenergy, 2013

Bio-oil has been produced from palm kernel shell in a fluidized bed reactor. The process conditions were optimized and the detailed characteristics of bio-oil were carried out. The higher feeding rate and higher gas flow rate attributed to higher bio-oil yield. The maximum mass fraction of biomass (57%) converted to bio-oil at 550 C when 2 L min À1 of gas and 10 g min À1 of biomass were fed. The bio-oil produced up to 500 C existed in two distinct phases, while it formed one homogeneous phase when it was produced above 500 C. The higher heating value of bio-oil produced at 550 C was found to be 23.48 MJ kg À1. As GCeMS data shows, the area ratio of phenol is the maximum among the area ratio of identified compounds in 550 C bio-oil. The UVeFluorescence absorption, which is the indication of aromatic content, is also the highest in 550 C bio-oil.

Characterization of Palm Shell-Derived Bio-Oil Through Pyrolysis

Journal of applied agricultural science and technology, 2022

Lignocellulosic biomass is a renewable resource used to produce energy, fuels, and chemicals. This study aimed to determine the effect of pyrolysis temperature on product yield and product characterization of bio-oil. In this study, palm shells were selected and prepared as raw materials for bio-oil production. Palm shells were first soaked in 10% HCl and then pyrolyzed at temperatures of 300 o C, 350 o C, 400 o C, and 450 o C in a fixed bed reactor. Afterward, the reactor will emit smoke which later will condense into bio-oil. The experimental results show that a temperature of 450 o C will be a better choice for higher bio-oil yields (44.59%). The characteristics of the bio-oil obtained are density (905-1015.17 kg/m 3), Kinematic Viscosity (1.21-1.5 mm 2 /s), and flash point (60-68.7 o C).

BIO-CHAR AND BIO-OIL PRODUCTION FROM PYROLYSIS OF PALM KERNEL SHELL AND POLYETHYLENE

International Journal of Conservation Science, 2023

In recent years, palm kernel shell (PKS) has become a viable feedstock for making biofuels and value-added commodities using a variety of thermal conversion routes. Therefore, significant conservation is required for PKS as a resource for fuel production in biofuel facilities. Thus, this research was intended to elucidate the effects on PKS as a solid fuel through torrefaction and the production of bio-char and bio-oil by single and co-pyrolysis of PKS and polyethylene (PE). The PKS was treated through torrefaction at different temperatures and holding times. The optimum parameters for torrefaction were a temperature of 250 o C and a holding time of 60 min. Then the PKS and PE were pyrolyzed in a fixed-bed reactor at different temperatures and ratios. The product yield was analysed for single and co-pyrolysis of PKS and PE for pyrolysis. The properties of the product composition for single and co-pyrolysis of the PKS and PE were determined by proximate analysis, Fourier transform infrared (FTIR) analysis, and gas chromatography-mass spectrometry (GC-MS). The optimum parameter obtained for biochar and bio-oil production from co-pyrolysis of PKS and PE was at temperature of 500 o C at a ratio of 1:2 (PKS: PE). The ester and phenol compounds were increased around 19.02 to 23.18% and 32.51 to 34.80 %, respectively, while amide and amine decreased around 4.94 to 18.87% and 0.63 to 32.39 %, respectively, compared to the single pyrolysis of PKS. Therefore, the PKS and PE co-pyrolysis significantly increased the amount of phenol and ester compounds while slightly reducing the amount of amide and amine compounds in the bio-oil product. As a conclusion, biomass conservation enables the manufacturing of value-added chemicals.

Evaluation of Oil Palm Biomass Potential for Bio-oil Production via Pyrolysis Processes

2020

The yield and quality of bio-oil obtained from pyrolysis processes depends on many factors, including pyrolysis types, reactor types, operating conditions and biomass property. The objective of this work was therefore to evaluate the potential of oil palm biomass, including oil palm trunk (OPT), oil palm fronds (OPF), oil palm decanter (DC) and oil palm root (OPR) for producing bio-oil via pyrolysis processes. The potential of oil palm biomass was considered in terms of proximate analysis, ultimate analysis, heating value, equivalent heating value, Thermogravimetric analyser (TGA) and lignocellulose content. The results showed that the moisture content of fried samples was in the range of 7.5-10.7% (w.b), which was relatively low and appropriate for pyrolysis. The volatile content of OPT and OPF was higher than 72% (wt.). The carbon, oxygen and hydrogen content of oil palm samples were in the range of 41.5-45.6, 30.7-40.2 and 5.7-5.9% (wt.), respectively. The higher heating value (H...

Fuel Properties and Chemical Compositions of Bio-oils from Biomass Pyrolysis

Pyrolysis of biomass is a promising alternative route for producing energy and chemical feedstock. This research proposes to investigate effect of pyrolysis temperature on product yields and the determination of their physicochemical properties. Slow pyrolysis of biomass (cassava pulp residue, palm shell and palm kernel) was performed in a fixed bed reactor. Palm kernel pyrolysis provided the highest liquid yield (54.34 wt%) at 700°C. Fuel properties of bio-oils are viscosity at 40°C, 1.46-58.72 cSt (mm 2 /s); pH, 2.8-5.6 and heating value, 14.92-40.00 MJ/kg. The boiling range distribution of dewatered palm kernel oil was closest to that of diesel oil while its heating value approached that of fuel oil.

Bio-oil from Oil Palm Shell Pyrolysis as Renewable Energy: A Review

Chemica : Jurnal Teknik Kimia (e-journal), 2022

Oil palm shell (OPS) is biomass with high carbon and hydrogen content, so it has the potential to produce renewable energy through the thermochemical method. Pyrolysis is a relatively inexpensive thermochemical method that continuously converts biomass into valuable gas, bio-oil, and char products. Bio-oil is used directly to fuel boilers and furnaces or to produce fuel oil. This article reviews the pyrolysis process of biomass from oil palm shells, discussing the operating parameters that influence the pyrolysis process and the method of upgrading bio-oil. This review shows a relationship between biomass composition (cellulose, hemicellulose, and lignin) and bio-oil yield. The water content in the raw material needs to be controlled at around 10%. The optimum particle size is closely related to the biomass's natural structure and reactor type. The higher the ash and fixed carbon content, the lower the bio-oil yield. The optimum temperature for pyrolysis is between 450-550 ºC. A high heating rate will increase the decomposition of biomass into bio-oil. Particle size and reactor type strongly influence feed rate, residence time, and reaction time. A fluidized bed reactor gives the highest bio-oil yield. Using plastic in co-pyrolysis and catalyst increases the heating value and decreases the oxygenated content. This is an open access article under the CC-BY-SA license.

Bio-oils from pyrolysis of oil palm empty fruit bunches

2009

The palm oil industry generates an abundance of oil palm biomass such as the mesocarp fibre, shell, empty fruit bunch (EFB), frond, trunk and palm oil mill effluent (POME). For 80 million tonnes of fresh fruit bunch (FFB) processed last year, the amount of oil palm biomass was more than 25 million tones. The objectives of this study were to: (i) Determine the effect of various pyrolysis parameters on product yields and (ii) Characterise liquid product obtained under different condition. Approach: In this study, pyrolysis of oil palm Empty Fruit Bunches (EFB) was investigated using quartz fluidized fixed bed reactor. The effects of pyrolysis temperatures, particle sizes and heating rates on the yield of the products were investigated. The temperature of pyrolysis and heating rate were varied in the range 300-700 °C and 10-100 °C min1 respectively. The particle size was varied in the range of <90, 91-106, 107-125 and 126-250 μm. The elemental analysis and calorific value of the bio-oil were determined. The chemical composition of the oil was investigated using chromatographic and spectroscopic techniques. Results: Under the experimental conditions, the maximum bio-oil yield was 42.28% obtained at 500 °C, with a heating rate of 100 °C min-1 and particle size of 91-106 μm. The calorific values of bio-oil ranged from 20-21 MJ kg-1. A great range of functional groups of phenol, alcohols, ketones, aldehydes and carboxylic acids were indicated in FTIR spectrum. Conclusion: The chemical characterisation results showed that the bio-oil obtained from oil palm EFB maybe a potentially valuable source as fuel or chemical feedstocks.

Analysis Of Bio-Oil Produced By Pyrolysis Of Coconut Shell

2017

The utilization of biomass as a source of new and renewable energy is being carried out. One of the technologies to convert biomass as an energy source is pyrolysis which is converting biomass into more valuable products, such as bio-oil. Bio-oil is a liquid which is produced by steam condensation process from the pyrolysis of coconut shells. The composition of a coconut shell e.g. hemicellulose, cellulose and lignin will be oxidized to phenolic compounds as the main component of the bio-oil. The phenolic compounds in bio-oil are corrosive; they cause various difficulties in the combustion system because of a high viscosity, low calorific value, corrosiveness, and instability. Phenolic compounds are very valuable components which phenol has used as the main component for the manufacture of antiseptic, disinfectant (known as Lysol) and deodorizer. The experiments typically occurred at the atmospheric pressure in a pyrolysis reactor at temperatures ranging from 300 <sup>o</su...