Adsorption of Methyl Red and Methyl Orange Using Different Tree Bark Powder (original) (raw)
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Adsorption of Methylene Blue Dye onto Bush Cane Bark Powder
The adsorption of methylene blue (MB) dye on bush cane bark powder has been studied by analyzing the effect of contact time, initial dye concentration, adsorbent dose, pH, and temperature on the amount of the MB dye adsorbed per unit mass of the bush cane bark powder adsorbent. An optimum adsorption could be achieved during 80 min contact time but, thereafter, decreased with contact time beyond 80 min. The adsorption of the methylene blue dye increased with increasing the initial dye concentration, temperature and pH. However, the amount of methylene blue adsorbed decreased with increasing the dosage of the adsorbent; a phenomenon attributed to a plausible agglomeration of the adsorbent and blocking of the preferred adsorption sites with increasing adsorbent dosage. The adsorption mechanism of the dye obeyed the Freundlich isotherm. Kinetic studies showed that the methylene blue adsorption onto bush cane bark powder adsorbent followed a second order reaction kinetics. The adsorbent was characterized by Fourier transform infra-red spectrophotometer and scanning electron microscope analysis.
Adsorption characteristics of the dye, Brilliant Green, on Neem leaf powder
Dyes and Pigments, 2003
A novel adsorbent was developed from mature leaves of natural Neem trees for removing dyes from water. The adsorbent, in the form of fine powder, was found to be very effective in removing the dye, Brilliant Green, from aqueous solution. The adsorption process was carried out in a batch process with different concentrations of the aqueous dye solution as well as with different adsorbent doses, at a range of pH values and temperature. The suitability of the adsorbent was tested by fitting the adsorption data with Langmuir and Freundlich isotherms and by computing equilibrium thermodynamic and kinetic parameters, the values of which showed the Neem leaf powder as a promising adsorbent for dyes in aqueous solution. #
A Comparitive Study of Adsorption Behaviour of a Dye Using Agro Wastes as Adsorbents
The use of cheap and eco-friendly adsorbents are studied as an alternative substitution of activated carbon for the removal of dyes from wastewater. Laboratory investigations were done to find the potential of Rice husk ash(RHA), Activated Rice Husk (ARH) and Azadirecta indica leaves (Neem) powder (NLP )to remove methylene blue dye from aqueous solution . ARH was prepared from rice husk treated with nitric acid and RHA Prepared by heating in muff furnace at 300 0 C. Neem leaves are sundried for few days and then dried at low temperature (<105°C) for 24 hrs in hot air oven to remove moisture content. The effects of various experimental parameters, such as pH , adsorbent dosage and contact time were investigated. Langmuir adsorption isotherm was applied and R 2 value was calculated which shows, Langmuir adsorption is a good fit for the experimental data. The result shows that the 85 % colour removal efficiency can be achieved at the dose of 50 g/l of ARH . 90 % colour removal efficiency is achieved at the adsorbent dose of 40 g/l of RHA. With increase in RHA dose the efficiency increased upto 96 %. 81% of colour removal efficiency is achieved with NLP .
Adsorption of an anionic dye (Congo red) from aqueous solutions by pine bark
Scientific Reports, 2019
Pinus pinaster bark, an abundant by-product from the timber industry, has been studied as a potential low-cost adsorbent for the removal of Congo red (CR) dye from wastewaters. Surface morphological and physico-chemical characteristics of pine bark were analysed using fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), determination of the point of zero charge (pH pZc) and elemental analysis. Assays were performed to determine the wavelength for the maximum absorbance and the stability with time of CR solutions depending on concentration and/or pH, which resulted to be a very significant parameter. Adsorption studies were conducted on batch mode to study the effect of contact time (till 7 days), pH (2-9), adsorbent dosage (1-10 g L −1) and temperature (25-60 °C). The bark adsorption capacity at equilibrium varied between 0.3 and 1.6 mg g −1 and the equilibrium adsorption percentage between 23.4 and 100% depending on adsorbent dosage, temperature and pH at an initial CR concentration of 5 mg L −1. Kinetic data for the removal of CR by pine bark were best fitted by the pseudo-second-order kinetic model. The equilibrium data fitted well with the Freundlich model. Thermodynamic analysis indicated that the adsorption process is exothermic and spontaneous.
ADSORPTION STUDIES OF SOME DYES ON ACACIA CONCINNA POWDER
The low cost activated carbon from Acacia Concinna was processed by treating with 2% HCl and 2% NaOH. The treated Acacia Concinna (Shikakai powder) was then roasted to get activated carbon. The influence of parameters like pH, concentration, dose and contact time were studied on adsorption of activated carbon for Congo red, Rhodamine-B, Crysoidine, Bismark brown and Titan yellow. The adsorption capacity of activated carbon was found to be 97, 98, 95, 98 and 96% respectively at pH 2 and contact time 24-48 hrs for all the dyes. The effect of concentration indicated that, as concentration increases adsorption decreases, hence increase in dose amount increases the adsorption. The data obtained through batch adsorption study was applied for Langmuir, Freundlich and Dubinin-Radushkevich(D-R) isotherms. The curve was linear for all the three isotherms and correlation coefficient (R 2) was 0.92, 0.970 and 0.977 respectively indicating that the developed model was favourable.
Oriental Journal of Chemistry
The plant powder of Nirgudi (L. Vitex negudo) were activated with sulphuric acid and used as low cost easily available and renewable biological adsorbent for the removal of acid dyes (Acid blue, Acid red and Malachite green) from aqueous solution. Batch experiments were carried out for adsorption kinetics and isotherms. Operating variable studied were pH, temperature, adsorbent dose, initial concentration of adsorbate. Adsorption capacity seems to be enhanced by increasing temperature, adsorbent dose and for pH. Maximum dye adsorption was found to be in acidic range. Nirgudi Leaf powder (NLP) treated with Sulphuric acid (H 2 SO 4 ) solution increased the adsorption efficiency upto 80 percent. Experimental adsorption kinetic data were fitted to be Lagergren first order. Equilibrium data were well represented by the Freundlich Langmuir isotherm model for all tested adsorption systems. Beside these the thermodynamic study has showed that the acid dye adsorption onto the surface of Acid Activated Nirgudi Leaf powder (AANLP) was physical adsorption and the process was spontaneous and exothermic.
Adsorption of Basic and Acidic Dyes onto Agricultural Wastes
International Letters of Chemistry, Physics and Astronomy, 2016
The potential of almond leaves powder, (ALP) for the removal of Crystal violet (CV) and Congo red (CR) dyes from aqueous solution was investigated. The adsorbent (ALP) was characterized by FTIR and SEM analysis. Batch adsorption studies were conducted and various parameters such as contact time, adsorbent dosage, initial dye concentration, pH and temperature were studied to observe their effects in the dyes adsorption process. The optimum conditions for the adsorption of CV and CR dyes onto the adsorbent (ALP) was found to be: contact time (100mins), pH (10.0), temperature (343K) for an initial CV dye concentration of 50mg/L using adsorbent dose of 1.0g and contact time (100mins), pH (2.0), temperature (333K) for an initial CR dye concentration of 50mg/L using adsorbent dose 1.0g respectively. The experimental equilibrium adsorption data fitted best and well to the Freundlich isotherm model for both CV and CR dyes adsorption. The maximum adsorption capacity of ALP was found to be 22...
Study of Effect of Concentration on Adsorption of Methyl Red Dye using different Adsorbents
International Journal for Research in Applied Science and Engineering Technology, 2017
Textile processing industries are now widespread sectors in many developing countries. Among the various processes in the textile industry, dyeing process uses large volume of water for dyeing, fixing and washing processes. Thus, the wastewater generated from the textile processing industries contains suspended solids, high amount of dissolved solids, un-reacted dyestuffs (colour) and other auxiliary chemicals that are used in the various stages of dyeing and processing. The conventional method of textile wastewater treatment consists of chemical coagulation, biological treatment followed by activated carbon adsorption. However, wastewater containing dyes is very difficult and complex to treat, since the dyes are recalcitrant organic molecules, resistant to aerobic digestion, and are stable to light, heat and oxidizing agents due to their molecular structure and size. Adsorption techniques have gained popularity in recent years because of their proven efficiency in the removal of pollutants from Textile industry effluents which are too stable for conventional treatment methods. Apart from the high quality product obtained, the processes have proved economically feasible. In most of the textile processing industries, activated carbon is generally used as aadsorbent to remove dyes in wastewater due to its excellent adsorption ability. For the study presented here Activated carbon (Commercial), Charcoal (Cashew-nut shell) and Charcoal (Wood) were used as an adsorbent. The experimental investigations have been made to find the effect of concentration of dye on adsorption rate of different adsorbents and to find the inexpensive alternative adsorbents in order to minimize the cost of effluent treatment from Textile industry.
Adsorption of Acid Dyes from aqueous solution onto the surface of acid activated Jaswand leaf powder
The plant powder of Nirgudi (L. Vitex negudo) were activated with sulphuric acid and used as low cost easily available and renewable biological adsorbent for the removal of acid dyes (Acid blue, Acid red and Malachite green) from aqueous solution. Batch experiments were carried out for adsorption kinetics and isotherms. Operating variable studied were pH, temperature, adsorbent dose, initial concentration of adsorbate. Adsorption capacity seems to be enhanced by increasing temperature, adsorbent dose and for pH. Maximum dye adsorption was found to be in acidic range. Nirgudi Leaf powder (NLP) treated with Sulphuric acid (H 2 SO 4 ) solution increased the adsorption efficiency upto 80 percent. Experimental adsorption kinetic data were fitted to be Lagergren first order. Equilibrium data were well represented by the Freundlich Langmuir isotherm model for all tested adsorption systems. Beside these the thermodynamic study has showed that the acid dye adsorption onto the surface of Acid Activated Nirgudi Leaf powder (AANLP) was physical adsorption and the process was spontaneous and exothermic.