Advances in primary lithium liquid cathode batteries (original) (raw)

Liquid electrolytes for lithium and lithium-ion batteries

Journal of Power Sources, 2003

A number of advances in electrolytes have occurred in the past 4 years, which have contributed to increased safety, wider temperature range of operation, better cycling and other enhancements to lithium-ion batteries. The changes to basic electrolyte solutions that have occurred to accomplish these advances are discussed in detail. The solvent components that have led to better low-temperature operation are also considered. Also, additives that have resulted in better structure of the solid electrolyte interphase (SEI) are presented as well as proposed methods of operation of these additives. Other additives that have lessened the flammability of the electrolyte when exposed to air and also caused lowering of the heat of reaction with the oxidized positive electrode are discussed. Finally, additives that act to open current-interrupter devices by releasing a gas under overcharge conditions and those that act to cycle between electrodes to alleviate overcharging are presented. As a class, these new electrolytes are often called ''functional electrolytes''. Possibilities for further progress in this most important area are presented. Another area of active work in the recent past has been the reemergence of ambient-temperature molten salt electrolytes applied to alkali metal and lithium-ion batteries. This revival of an older field is due to the discovery of new salt types that have a higher voltage window (particularly to positive potentials) and also have greatly increased hydrolytic stability compared to previous ionic liquids. While practical batteries have not yet emerged from these studies, the increase in the number of active researchers and publications in the area demonstrates the interest and potentialities of the field. Progress in the field is briefly reviewed. Finally, recent results on the mechanisms for capacity loss on shelf and cycling in lithium-ion cells are reviewed. Progress towards further market penetration by lithium-ion cells hinges on improved understanding of the failure mechanisms of the cells, so that crucial problems can be addressed.

Lithium batteries: a 50-year perspective, 1959-2009

Solid State Ionics, 2000

The principles for realising commercially successful lithium secondary batteries are now well established. What is necessary during the next decade is the application of sophisticated solid state chemistry and materials science in order to find optimised solutions to the many conflicting requirements placed on the battery materials.

Solid Electrolyte: the Key for High-Voltage Lithium Batteries

Advanced Energy Materials, 2014

tremendous research efforts have been devoted to developing new electrolytes with expanded safety window 12 ] as well as modifying the surface of anodes and cathodes 14 ] for improved stability, it is not easy to address the above four problems simultaneously. High-voltage lithium batteries can be successfully utilized only if all these problems associated with the cathode, the electrolyte, and the anode are solved fully.

Investigation of new types of lithium-ion battery materials

Journal of Power Sources, 2002

This paper reports part of the activities in progress in our laboratory in the investigation of electrode and electrolyte materials which may be of interest for the development of lithium-ion batteries with improved characteristics and performances. This investigation has been directed to both anode and cathode materials, with particular attention to convertible oxides and defect spinel-framework Li-insertion compounds in the anode area and layered mixed lithium±nickel±cobalt oxide and high voltage, metal type oxides in the cathode area. As for the electrolyte materials, we have concentrated the efforts on composite polymer electrolytes and gel-type membranes. In this work we report the physical, chemical and electrochemical properties of the defect spinel-framework Li-insertion anodes and of the high voltage, mixed metal type oxide cathodes, by describing their electrochemical properties in cells using either``standard'' liquid electrolytes and`a dvanced'' gel-type, polymer electrolytes.

Analysis of a lithium/thionyl chloride battery under moderate-rate discharge

Journal of The Electrochemical Society, 1999

A one-dimensional mathematical model of a spirally wound lithium/thionyl chloride primary battery is developed and used for parameter estimation and design studies. The model formulation is based on the fundamental conservation laws using porous electrode theory and concentrated solution theory. The model is used to estimate the transference number, the diffusion coefficient, and the kinetic parameters for the reactions at the anode and the cathode as a function of temperature. These parameters are obtained by fitting the simulated capacity and average cell voltage to experimental data over a wide range of temperatures (Ϫ55 to 49ЊC) and discharge loads (10-250 ⍀). The experiments were performed on D-sized, cathode-limited, spirally wound lithium/thionyl chloride cells. The model is also used to study the effect of cathode thickness on the cell capacity as a function of temperature, and it was found that the optimum thickness for the cathode-limited design is temperature and load dependent.

A review of cathode and anode materials for lithium-ion batteries

SoutheastCon 2016, 2016

Lithium ion batteries are one of the most commercially sought after energy storages today. Their application widely spans from Electric Vehicle (EV) to portable devices. Their lightness and high energy density makes them commercially viable. More research is being conducted to better select the materials for the anode and cathode parts of Lithium (Li) ion cell. This paper presents a comprehensive review of the existing and potential developments in the materials used for the making of the best cathodes, anodes and electrolytes for the Liion batteries such that maximum efficiency can be tapped. Observed challenges in selecting the right set of materials is also described in detail. This paper also provides a brief history of battery technology and their wide applicability in the energy market today, the chemistry and principle of operation behind the batteries, and their potential applications even beyond the energy sector. Safety concerns related to Li-ion batteries have also been taken into account considering recent events.