New osmium hydrides containing the bulky phosphine 1,2-bis(diisopropylphosphino)ethane (dippe (original) (raw)
Preparation and reactivity of osmium(II) hydride complexes with phosphites and polypyridyls
Gabriele Albertin, Stefano ANTONIUTTI
Journal of Organometallic Chemistry, 2004
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Classical, nonclassical, and mixed-metal osmium(II) polyhydrides stabilized by the tetraphosphine P(CH2CH2PPh2)3. Hydrogen/deuterium isotope exchange reactions promoted by a strongly bound dihydrogen ligand
Alfonso Polo
Inorganic Chemistry, 1993
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Preparation and Characterization of Osmium−Stannyl Polyhydrides: d 4 −d 2 Oxidative Addition of Neutral Molecules in a Late Transition Metal
Montserrat Oliván
Organometallics, 2003
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Preparation and reactivity with azo-species of hydride and dihydrogen complexes of osmium stabilised by tris(pyrazolyl)borate and phosphite ligands
Gianluigi Zanardo, Gabriele Albertin, Stefano ANTONIUTTI
Journal of Organometallic Chemistry, 2007
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Preparation of Hydride-Ethylene Complexes of Osmium
Stefano ANTONIUTTI
Zeitschrift für anorganische und allgemeine Chemie, 2016
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Formation and Stereochemistry of Octahedral Cationic Hydride-Azavinylidene Osmium(IV) Complexes
Agusti Lledos
European Journal of Inorganic Chemistry, 2001
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Dihydride versus Elongated Dihydrogen in [H 2 Os( κ 2 -O 2 CCH 3 )L(P i Pr 3 ) 2 ] + Complexes: Influence of the L Ligand
Montserrat Oliván
Organometallics, 2002
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Reactivity of OsH4(CO)(PiPr3)2 toward terminal alkynes: synthesis and reactions of the alkynyl-dihydrogen complexes OsH(C2R)(.eta.2-H2)(CO)(PiPr3)2 (R = Ph, SiMe3)
Cristina Robles Valero
Organometallics, 1993
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Synthesis, reactivity, molecular structure, and catalytic activity of the novel dichlorodihydridoosmium(IV) complexes OsH2Cl2(PR3)2 (PR3 = P-i-Pr3, PMe-t-Bu2)
M. Esteruelas
Inorganic Chemistry, 1991
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Oxo Complexes of Osmium(IV) Formed via Dioxygen Activation. X-ray Structures of [OsX(dcpe) 2 ]PF 6 (X = Cl, Br), [OsCl(η 2 -O 2 )(dcpe) 2 ]BPh 4 , and [OsCl(O)(dcpe) 2 ]BPh 4 (dcpe = 1,2-Bis(dicyclohexylphosphino)ethane)
Antonio Mezzetti
Inorganic Chemistry, 2000
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Oxidative Addition of Group 14 Element Hydrido Compounds to OsH 2 (η 2 -CH 2 CHEt)(CO)(P i Pr 3 ) 2 : Synthesis and Characterization of the First Trihydrido−Silyl, Trihydrido−Germyl, and Trihydrido−Stannyl Derivatives of Osmium(IV)
Feliu Maseras, Pablo Espinet, Agusti Lledos
Inorganic Chemistry, 1996
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The tris(triphenylphosphine)osmium zerovalent complexes Os(CO)2(PPh3)3, .Os(CO)(CNR)(PPh3)3, Os(CO)(CS)(PPh3)3, Os(CS)(cNR)(PPh3)3 and derived compounds
Terrence Collins
Journal of Organometallic Chemistry, 1982
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Synthesis, molecular structure, and reactivity of octahedral alkylhydridoosmium(II) complexes [OsH(R)(CO)2(PR'3)2]
Cristina Robles Valero
Organometallics, 1992
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Complex Formation and Rearrangement Reactions of the Phosphine Hydride Anions [OsH 3 (PPh 3 ) 3 ] - and [IrH 2 (PPh 3 ) 3 ]
Sean McGrady
Organometallics, 2006
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Osmium(IV) Halide Complexes with Dimethyl Sulfoxide[H(dmso) 2 ][OsX 5 (dmso‐κ O )], X=Cl, Br: Synthesis, Structure, and Properties
Olga V . Rudnitskaya
ChemistrySelect, 2020
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Chemistry of 2-(phenylazo)pyridine complexes of osmium: synthesis, characterization and reactivities
S. Bhatacharya
Polyhedron, 2000
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A new diphosphinite derived from cyclohexane-1,4-diol: oxidation reactions, metal complexes, P–O bond cleavage and X-ray crystal structures of Ph2P(E)O(C6H10)OP(E)Ph2 (E=S, Se)
Maravanji Balakrishna
Polyhedron, 2005
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Reactivity of [(μ-H)Os3(CO)8{Ph2PCH2P(Ph)C6H4}] with organic heterothiols; X-ray structures of [H(μ-H)Os3(CO)8(η2-pyS){Ph2PCH2P(Ph)C6H4}] and [Os3(CO)8(μ-η2-pyS){Ph2PCH2P(Ph)C6H4}]
Abdul Mottalib
Journal of Organometallic Chemistry, 2000
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Synthesis and Characterization of the Dinuclear Polyhydrides [Os 2 H 7 (PPh i Pr 2 ) 4 ] + and [Os 2 H 6 (PPh i Pr 2 ) 4 ]
Sarah Hoyte, John Spencer
Inorganic Chemistry, 2009
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OsXCl(phosphine)2(diamine) and OsXCl(diphosphine)(diamine) (X = Cl, H) Complexes for Ketone Hydrogenation
Maurizio Ballico
Organometallics, 2017
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Osmium mediated decarbonylation of aldehydes and ketones. Synthesis, structure and reactivities of some osmium carbonyl complexes
Parna Gupta
2003
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Reactions of a Dihydride−Osmium(IV) Complex with Aldehydes: Influence of the Substituent at the Carbonyl Group
Montserrat Oliván
Organometallics, 2008
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Tris(N-pyrrolyl)phosphine complexes of osmium(II) and osmium(0)
Warren Roper
Journal of Organometallic Chemistry, 2002
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Osmium dimethyl sulfoxide complexes: Synthesis and properties of [H(dmso)2][OsIII(dmso)2Br4]
Ekaterina Dobrokhotova
Russian Journal of Inorganic Chemistry, 2014
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Heterolytic H 2 Activation by Dihydrogen Complexes. Effects of the Ligand X in [M(X)H 2 {Ph 2 P(CH 2 ) 3 PPh 2 } 2 ] n + (M = Ru, Os; X = CO, Cl, H)
Alessandro Del Zotto, Antonio Mezzetti
Inorganic Chemistry, 1997
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Influence of the Cis Ligand on the H−H Separation and the Rotation Barrier of the Dihydrogen in Osmium-Elongated Dihydrogen Complexes Containing an Ortho-Metalated Ketone †
Agusti Lledos
Organometallics, 2004
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Complexes of Osmium with the 2-[(Diphenylphosphanyl)-methyl]-pyridine Ligand †
Werner Kaminsky
The Journal of Physical Chemistry C, 2008
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