In-Situ XRD Research Papers - Academia.edu (original) (raw)

O 12 is a promising electrolyte for rechargeable all solid state batteries. The stability of low temperature cubic phase of garnet in argon and air was determined. The garnet stoichiometry was maintained in argon while in air lithium loss... more

O 12 is a promising electrolyte for rechargeable all solid state batteries. The stability of low temperature cubic phase of garnet in argon and air was determined. The garnet stoichiometry was maintained in argon while in air lithium loss occurred. The influence of CO 2 adsorption on the structural modifications of garnet was proved. a b s t r a c t Rechargeable all solid-state lithium batteries are a promising technology for the next generation of safer batteries. In this context, strict requirements are placed on the electrolytes, among which is emerging the Li 7 La 3 Zr 2 O 12 garnet, chiefly for the relationships among synthesis conditions and phase stability. Here, the structural modifications of the low temperature (LT) Li 7 La 3 Zr 2 O 12 cubic form were investigated by using in situ X-Rays diffraction analysis. In particular, we studied the role of both temperature and atmosphere (air or argon) on phase stabilization. In argon flow, the LT phase is stable under 750 C, and it transforms into the tetragonal one at lower temperature. In air, it partially decomposes to La 2 Zr 2 O 7 due to Li loss above 250 C. ICP-OES analysis confirmed that garnet stoichiometry was maintained in argon, whereas in air lithium loss occurred. The structural transformations are driven by the CO 2 absorbed in the LT structure that can form Li 2 CO 3 and/or La 2 (CO 3) 3 so causing stoichiometry changes responsible of the structural evolution.