Ferrarisite (original) (raw)

A valid IMA mineral species

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About FerrarisiteHide

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Formula:

Ca5(AsO4)2(HAsO4)2 · 9H2O

Colour:

Colorless to white

Lustre:

Sub-Vitreous, Silky

Name:

Named in honour of professor Giovanni Ferraris (1937- ), Institute of Mineralogy, Crystallography and Geochemistry, University of Turin, Italy, who worked on crystal structure of several arsenate minerals from Sainte-Marie-aux-Mines, France.

Ferrarisite dehydrates very slowly in dry air at room temperature and turns from colourless to white; dehydrated crystals were also found in nature in Sainte Marie aux Mines and in Wittichen (Catti & Ivaldi, 1981). Fresh ferrarisite is visually very similar to pharmacolite.

A triclinic compound with the formula Ca5(AsO4)2(HAsO4).2.5H2O (Unnamed (Ca arsenate hydrate)) was obtained by dehydration at 60°C of ferrarisite (Catti & Ivaldi, 1981).

A closely related mineral is vladimirite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:1485:0

836c8301-c56b-4402-aa4f-f37ba90998ae

IMA Classification of FerrarisiteHide

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IMA Formula:

Ca5(AsO3OH)2(AsO4)2 · 9H2O

Classification of FerrarisiteHide

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8.CJ.30

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
J : With only large cations

39.2.3.1

39 : HYDRATED ACID PHOSPHATES,ARSENATES AND VANADATES
2 : (AB)5[HXO4]2[XO4]2.xH2O

20.2.12

20 : Arsenates (also arsenates with phosphate, but without other anions)
2 : Arsenates of Be, Mg, Ca or Ba

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Fer IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FerrarisiteHide

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Transparency:

Transparent, Translucent

Colour:

Colorless to white

Comment:

White mineral may be dehydrated to unspecified minerals

Cleavage:

Perfect
{001} perfect

Density:

2.63 g/cm3 (Measured) 2.60 g/cm3 (Calculated)

Optical Data of FerrarisiteHide

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RI values:

_n_α = 1.562 _n_β = 1.572 _n_γ = 1.585

2V:

Measured: 83° , Calculated: 84°

δ = 0.023

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

X ^ c = 8°-17°; Z perpendicular to {110}

Pleochroism:

Non-pleochroic

Chemistry of FerrarisiteHide

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Mindat Formula:

Ca5(AsO4)2(HAsO4)2 · 9H2O

Crystallography of FerrarisiteHide

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Class (H-M):

1 - Pinacoidal

Cell Parameters:

a = 8.294 Å, b = 6.722 Å, c = 11.198 Å
α = 106.16°, β = 92.94°, γ = 99.20°

Ratio:

a:b:c = 1.234 : 1 : 1.666

Unit Cell V:

588.90 ų (Calculated from Unit Cell)

Comment:

Bull Min. (1980): 103:541 structure

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0012071 Ferrarisite Catti M, Chiari G, Ferraris G (1980) The structure of ferrarisite, Ca5(HAsO4)2(AsO4)2*9H2O: disorder, hydrogen bonding, and polymorphism with guerinite Bulletin de Mineralogie 103 541-546 1980 Sainte Marie-aux-Mines, Alsace, France 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
10.8 Å (100)
6.34 Å (30)
5.36 Å (30)
4.73 Å (30)
4.07 Å (40)
3.57 Å (40)
3.17 Å (80)
2.83 Å (90)

Geological EnvironmentHide

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Type Occurrence of FerrarisiteHide

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General Appearance of Type Material:

White radiating very elongated crystals.

Geological Setting of Type Material:

Oxidized vein assemblages in arsenic-rich mines

Associated Minerals at Type Locality:

Synonyms of FerrarisiteHide

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Other Language Names for FerrarisiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.CJ. Sainfeldite Ca5(AsO4)2(AsO3OH)2 · 4H2O Mon. 2/m : _B_2/b
8.CJ. Caesiumpharmacosiderite CsFe4[(AsO4)3(OH)4] · 4H2O Iso. 43_m_ : P_43_m
8.CJ. Jeankempite Ca5(AsO4)2(HAsO4)2 · 7H2O Tric. 1 : _P_1
8.CJ. Airdite Sr(V4+O)2(PO4)2 · 4H2O Mon. m : B b
8.CJ. Dobšináite Ca2Ca(AsO4)2 · 2H2O Mon. 2/m : _P_21/b
8.CJ.05 Stercorite (NH4)Na(PO3OH) · 4H2O Tric. 1 : _P_1
8.CJ.10 Mundrabillaite (NH4)2Ca(PO3OH)2 · H2O Mon. m : P m
8.CJ.10 Swaknoite (NH4)2Ca(PO3OH)2 · H2O Orth.
8.CJ.15 Nabaphite NaBaPO4 · 9H2O Iso. 23 : _P_213
8.CJ.15 Nastrophite Na(Sr,Ba)PO4 · 9H2O Iso. 23 : _P_213
8.CJ.20 Haidingerite CaHAsO4 · H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.CJ.25 Vladimirite Ca4(AsO4)2(AsO3OH) · 4H2O Mon. 2/m : _P_21/b
8.CJ.25 Rhabdophane-(Y) YPO4 · H2O Hex. 622 : _P_6222
8.CJ.27 Churchite-(Dy) (Dy,Sm,Gd,Nd)PO4 · 2H2O Mon.
8.CJ.35 Machatschkiite (Ca,Na)6(AsO4)(HAsO4)3(PO4,SO4) · 15H2O Trig. 3_m_ : R_3_c
8.CJ.35 Fulbrightite Ca(VO)2(AsO4)2 · 4H2O Tric. 1 : _P_1
8.CJ.40 Phaunouxite Ca3(AsO4)2 · 11H2O Tric.
8.CJ.40 Rauenthalite Ca3(AsO4)2 · 10H2O Tric. 1 : _P_1
8.CJ.45 Brockite (Ca,Th,Ce)PO4 · H2O Hex. 622 : _P_6222
8.CJ.45 Grayite (Th,Pb,Ca)(PO4) · H2O Hex. 622 : _P_6222
8.CJ.45 Rhabdophane-(Ce) Ce(PO4) · 0.6H2O Trig. 32 : _P_3121
8.CJ.45 Rhabdophane-(La) La(PO4) · H2O Hex. 622 : _P_6222
8.CJ.45 Rhabdophane-(Nd) Nd(PO4) · H2O Hex. 622 : _P_6222
8.CJ.45 Tristramite (Ca,U,Fe)(PO4,SO4) · 2H2O Hex. 622 : _P_6222
8.CJ.45 Smirnovskite (Th,Ca)PO4 · nH2O Hex. 622 : _P_6222
8.CJ.45 Štěpite U(AsO3OH)2 · 4H2O Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d
8.CJ.47 Vysokýite U4+[AsO2(OH)2]4 · 4H2O Tric. 1 : _P_1
8.CJ.50 Ardealite Ca2(PO3OH)(SO4) · 4H2O Mon. m : B b
8.CJ.50 Brushite Ca(PO3OH) · 2H2O Mon. m : B b
8.CJ.50 Churchite-(Y) Y(PO4) · 2H2O Mon. 2/m : _B_2/b
8.CJ.50 Pharmacolite Ca(HAsO4) · 2H2O Mon. m
8.CJ.50 Churchite-(Nd) Nd(PO4) · 2H2O Mon.
8.CJ.55 Mcnearite NaCa5(AsO4)(HAsO4)4 · 4H2O Tric.
8.CJ.60 Dorfmanite Na2(PO3OH) · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
8.CJ.65 Sincosite Ca(VO)2(PO4)2 · 5H2O Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_42/n n m
8.CJ.65 Bariosincosite Ba(VO)2(PO4)2 · 4H2O Tet.
8.CJ.70 Catalanoite Na2(PO3OH) · 8H2O Orth. m m m _(_2/_m_2/_m_2/m ) : I b c a
8.CJ.75 Guérinite Ca6(HAsO4)3(AsO4)2 · 10.5H2O Mon. 2/m : _P_21/b
8.CJ.85 Ningyoite (U,Ca,Ce)2(PO4)2 · 1-2H2O Orth.

Fluorescence of FerrarisiteHide

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for FerrarisiteHide

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Localities for FerrarisiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

France
Grand Est Haut-Rhin Colmar-Ribeauvillé Sainte-Marie-aux-Mines Neuenberg P&T N°23-24 et al. (Haut-Rhin)
Sankt Jakob vein Gabe Gottes Mine (TL) Bari: Lapis 6/1983 +1 other reference
Giftgrube mine Bari (1982)
Sankt Jakob Mine This mine worked the same vein as Gabe ... +2 other references
Provence-Alpes-Côte d'Azur Alpes-Maritimes Nice Arrondissement Duranus L'Eguisse Mine Perroud (1989)
Germany
Baden-Württemberg Freiburg Region Rottweil Schenkenzell Wittichen Burgfelsen Johann Mine
Heubach Valley Anton Mine Walenta (1992)
Bavaria Lower Franconia Aschaffenburg District Sailauf Hartkoppe Fuchs Quarry see locality page
Hesse Kassel Region Hersfeld-Rotenburg Nentershausen Süß Richelsdorf Smelter Ore dumps Weiß (1990)
Wilhelm Mine Weiß (1990)
North Rhine-Westphalia Arnsberg Hochsauerlandkreis Olsberg Dörnberg Mine
Saxony-Anhalt Harz Wernigerode Hasserode Das Aufgeklärte Glück Mine (Aufgeklärtes Glück Mine) XRD and EDS Analysis Thomas Witzke
Greece
Attica East Attica Lavreotiki Lavrion Mining District Rieck et al. (2020)
Plaka Plaka Mines Plaka Mine No. 80 Rieck et al. (2020)
Japan
Oita Prefecture Saiki City Kiura Mine Uriya deposit OHNISHI et al. (2013) +1 other reference
Switzerland
Valais Sierre Anniviers Ayer Grand-Praz Mine Stalder et al. (1998) +1 other reference