Ferrarisite (original) (raw)
A valid IMA mineral species
About FerrarisiteHide
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Formula:
Ca5(AsO4)2(HAsO4)2 · 9H2O
Colour:
Colorless to white
Lustre:
Sub-Vitreous, Silky
Name:
Named in honour of professor Giovanni Ferraris (1937- ), Institute of Mineralogy, Crystallography and Geochemistry, University of Turin, Italy, who worked on crystal structure of several arsenate minerals from Sainte-Marie-aux-Mines, France.
Ferrarisite dehydrates very slowly in dry air at room temperature and turns from colourless to white; dehydrated crystals were also found in nature in Sainte Marie aux Mines and in Wittichen (Catti & Ivaldi, 1981). Fresh ferrarisite is visually very similar to pharmacolite.
A triclinic compound with the formula Ca5(AsO4)2(HAsO4).2.5H2O (Unnamed (Ca arsenate hydrate)) was obtained by dehydration at 60°C of ferrarisite (Catti & Ivaldi, 1981).
A closely related mineral is vladimirite.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:1485:0
836c8301-c56b-4402-aa4f-f37ba90998ae
IMA Classification of FerrarisiteHide
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IMA Formula:
Ca5(AsO3OH)2(AsO4)2 · 9H2O
Classification of FerrarisiteHide
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8.CJ.30
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
J : With only large cations
39.2.3.1
39 : HYDRATED ACID PHOSPHATES,ARSENATES AND VANADATES
2 : (AB)5[HXO4]2[XO4]2.xH2O
20.2.12
20 : Arsenates (also arsenates with phosphate, but without other anions)
2 : Arsenates of Be, Mg, Ca or Ba
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Fer | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of FerrarisiteHide
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Transparency:
Transparent, Translucent
Colour:
Colorless to white
Comment:
White mineral may be dehydrated to unspecified minerals
Cleavage:
Perfect
{001} perfect
Density:
2.63 g/cm3 (Measured) 2.60 g/cm3 (Calculated)
Optical Data of FerrarisiteHide
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RI values:
_n_α = 1.562 _n_β = 1.572 _n_γ = 1.585
2V:
Measured: 83° , Calculated: 84°
δ = 0.023
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Optical Extinction:
X ^ c = 8°-17°; Z perpendicular to {110}
Pleochroism:
Non-pleochroic
Chemistry of FerrarisiteHide
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Mindat Formula:
Ca5(AsO4)2(HAsO4)2 · 9H2O
Crystallography of FerrarisiteHide
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Class (H-M):
1 - Pinacoidal
Cell Parameters:
a = 8.294 Å, b = 6.722 Å, c = 11.198 Å
α = 106.16°, β = 92.94°, γ = 99.20°
Ratio:
a:b:c = 1.234 : 1 : 1.666
Unit Cell V:
588.90 ų (Calculated from Unit Cell)
Comment:
Bull Min. (1980): 103:541 structure
Crystal StructureHide
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ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0012071 | Ferrarisite | Catti M, Chiari G, Ferraris G (1980) The structure of ferrarisite, Ca5(HAsO4)2(AsO4)2*9H2O: disorder, hydrogen bonding, and polymorphism with guerinite Bulletin de Mineralogie 103 541-546 | 1980 | Sainte Marie-aux-Mines, Alsace, France | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
10.8 Å | (100) |
6.34 Å | (30) |
5.36 Å | (30) |
4.73 Å | (30) |
4.07 Å | (40) |
3.57 Å | (40) |
3.17 Å | (80) |
2.83 Å | (90) |
Geological EnvironmentHide
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Type Occurrence of FerrarisiteHide
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General Appearance of Type Material:
White radiating very elongated crystals.
Geological Setting of Type Material:
Oxidized vein assemblages in arsenic-rich mines
Associated Minerals at Type Locality:
Synonyms of FerrarisiteHide
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Other Language Names for FerrarisiteHide
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Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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8.CJ. | Sainfeldite | Ca5(AsO4)2(AsO3OH)2 · 4H2O | Mon. 2/m : _B_2/b |
---|---|---|---|
8.CJ. | Caesiumpharmacosiderite | CsFe4[(AsO4)3(OH)4] · 4H2O | Iso. 43_m_ : P_43_m |
8.CJ. | Jeankempite | Ca5(AsO4)2(HAsO4)2 · 7H2O | Tric. 1 : _P_1 |
8.CJ. | Airdite | Sr(V4+O)2(PO4)2 · 4H2O | Mon. m : B b |
8.CJ. | Dobšináite | Ca2Ca(AsO4)2 · 2H2O | Mon. 2/m : _P_21/b |
8.CJ.05 | Stercorite | (NH4)Na(PO3OH) · 4H2O | Tric. 1 : _P_1 |
8.CJ.10 | Mundrabillaite | (NH4)2Ca(PO3OH)2 · H2O | Mon. m : P m |
8.CJ.10 | Swaknoite | (NH4)2Ca(PO3OH)2 · H2O | Orth. |
8.CJ.15 | Nabaphite | NaBaPO4 · 9H2O | Iso. 23 : _P_213 |
8.CJ.15 | Nastrophite | Na(Sr,Ba)PO4 · 9H2O | Iso. 23 : _P_213 |
8.CJ.20 | Haidingerite | CaHAsO4 · H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n |
8.CJ.25 | Vladimirite | Ca4(AsO4)2(AsO3OH) · 4H2O | Mon. 2/m : _P_21/b |
8.CJ.25 | Rhabdophane-(Y) | YPO4 · H2O | Hex. 622 : _P_6222 |
8.CJ.27 | Churchite-(Dy) | (Dy,Sm,Gd,Nd)PO4 · 2H2O | Mon. |
8.CJ.35 | Machatschkiite | (Ca,Na)6(AsO4)(HAsO4)3(PO4,SO4) · 15H2O | Trig. 3_m_ : R_3_c |
8.CJ.35 | Fulbrightite | Ca(VO)2(AsO4)2 · 4H2O | Tric. 1 : _P_1 |
8.CJ.40 | Phaunouxite | Ca3(AsO4)2 · 11H2O | Tric. |
8.CJ.40 | Rauenthalite | Ca3(AsO4)2 · 10H2O | Tric. 1 : _P_1 |
8.CJ.45 | Brockite | (Ca,Th,Ce)PO4 · H2O | Hex. 622 : _P_6222 |
8.CJ.45 | Grayite | (Th,Pb,Ca)(PO4) · H2O | Hex. 622 : _P_6222 |
8.CJ.45 | Rhabdophane-(Ce) | Ce(PO4) · 0.6H2O | Trig. 32 : _P_3121 |
8.CJ.45 | Rhabdophane-(La) | La(PO4) · H2O | Hex. 622 : _P_6222 |
8.CJ.45 | Rhabdophane-(Nd) | Nd(PO4) · H2O | Hex. 622 : _P_6222 |
8.CJ.45 | Tristramite | (Ca,U,Fe)(PO4,SO4) · 2H2O | Hex. 622 : _P_6222 |
8.CJ.45 | Smirnovskite | (Th,Ca)PO4 · nH2O | Hex. 622 : _P_6222 |
8.CJ.45 | Štěpite | U(AsO3OH)2 · 4H2O | Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d |
8.CJ.47 | Vysokýite | U4+[AsO2(OH)2]4 · 4H2O | Tric. 1 : _P_1 |
8.CJ.50 | Ardealite | Ca2(PO3OH)(SO4) · 4H2O | Mon. m : B b |
8.CJ.50 | Brushite | Ca(PO3OH) · 2H2O | Mon. m : B b |
8.CJ.50 | Churchite-(Y) | Y(PO4) · 2H2O | Mon. 2/m : _B_2/b |
8.CJ.50 | Pharmacolite | Ca(HAsO4) · 2H2O | Mon. m |
8.CJ.50 | Churchite-(Nd) | Nd(PO4) · 2H2O | Mon. |
8.CJ.55 | Mcnearite | NaCa5(AsO4)(HAsO4)4 · 4H2O | Tric. |
8.CJ.60 | Dorfmanite | Na2(PO3OH) · 2H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a |
8.CJ.65 | Sincosite | Ca(VO)2(PO4)2 · 5H2O | Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _P_42/n n m |
8.CJ.65 | Bariosincosite | Ba(VO)2(PO4)2 · 4H2O | Tet. |
8.CJ.70 | Catalanoite | Na2(PO3OH) · 8H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : I b c a |
8.CJ.75 | Guérinite | Ca6(HAsO4)3(AsO4)2 · 10.5H2O | Mon. 2/m : _P_21/b |
8.CJ.85 | Ningyoite | (U,Ca,Ce)2(PO4)2 · 1-2H2O | Orth. |
Fluorescence of FerrarisiteHide
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Other InformationHide
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Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for FerrarisiteHide
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References for FerrarisiteHide
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Localities for FerrarisiteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
France | |
---|---|
Grand Est Haut-Rhin Colmar-Ribeauvillé Sainte-Marie-aux-Mines ⓘ Neuenberg | P&T N°23-24 et al. (Haut-Rhin) |
Sankt Jakob vein ⓘ Gabe Gottes Mine (TL) | Bari: Lapis 6/1983 +1 other reference |
ⓘ Giftgrube mine | Bari (1982) |
ⓘ Sankt Jakob Mine | This mine worked the same vein as Gabe ... +2 other references |
Provence-Alpes-Côte d'Azur Alpes-Maritimes Nice Arrondissement Duranus ⓘ L'Eguisse Mine | Perroud (1989) |
Germany | |
Baden-Württemberg Freiburg Region Rottweil Schenkenzell Wittichen Burgfelsen ⓘ Johann Mine | |
Heubach Valley ⓘ Anton Mine | Walenta (1992) |
Bavaria Lower Franconia Aschaffenburg District Sailauf Hartkoppe ⓘ Fuchs Quarry | see locality page |
Hesse Kassel Region Hersfeld-Rotenburg Nentershausen Süß Richelsdorf Smelter ⓘ Ore dumps | Weiß (1990) |
ⓘ Wilhelm Mine | Weiß (1990) |
North Rhine-Westphalia Arnsberg Hochsauerlandkreis Olsberg ⓘ Dörnberg Mine | |
Saxony-Anhalt Harz Wernigerode Hasserode ⓘ Das Aufgeklärte Glück Mine (Aufgeklärtes Glück Mine) | XRD and EDS Analysis Thomas Witzke |
Greece | |
Attica East Attica Lavreotiki ⓘ Lavrion Mining District | Rieck et al. (2020) |
Plaka Plaka Mines ⓘ Plaka Mine No. 80 | Rieck et al. (2020) |
Japan | |
Oita Prefecture Saiki City Kiura Mine ⓘ Uriya deposit | OHNISHI et al. (2013) +1 other reference |
Switzerland | |
Valais Sierre Anniviers Ayer ⓘ Grand-Praz Mine | Stalder et al. (1998) +1 other reference |