Kassite (original) (raw)

A valid IMA mineral species

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About KassiteHide

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Colour:

Brownish pink to pale yellow

Crystal System:

Monoclinic

Name:

In honour of Academician Nikolai Grigor’evich Kassin (Николай Григорьевич Кассин) (14 December 1885, Gnusino, Vyatka province, Russian empire - 28 October 1949, Alma-Ata, Kazakh SSR (now Kazakhstan), USSR), geologist with the Academy of Sciences of the Kazakh SSR. He discovered the Afrikanda massif, Russia.

This page provides mineralogical data about Kassite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2166:7

776ffbf7-07fd-4965-9b55-48bc3f6d148c

IMA Classification of KassiteHide

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Type description reference:

Kukharenko, A.A., Orlova, M.P., Bulakh, A.G., Bagdasarov, E.A., Rimskaya-Korsakova, O.M., Nefedov, Y.I., Ilyinskiy, G.A., Sergeyev, A.C., Abakumova, N.B. (1965) The Caledonian complex of the ultrabasic alkaline rocks and carbonatites of the Kola Peninsula and northern Karelia. Izdatelstvo "Nedra" Moskva: 1965: 368-375.

Classification of KassiteHide

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4.DH.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
H : With large (+- medium-sized) cations; sheets of edge-sharing octahedra

8.3.9.1

8 : MULTIPLE OXIDES CONTAINING NIOBIUM,TANTALUM OR TITANIUM
3 : AB2O6

7.9.7

7 : Oxides and Hydroxides
9 : Oxides of Ti

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Kas IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KassiteHide

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Colour:

Brownish pink to pale yellow

Cleavage:

Perfect
Perfect on {010} and distinct on {101}.

Density:

3.42 g/cm3 (Measured) 3.418 g/cm3 (Calculated)

Optical Data of KassiteHide

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RI values:

_n_α = 1.950(1) _n_β = 2.130 _n_γ = 2.210

2V:

Measured: 58° , Calculated: 62°

δ = 0.260

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

very strong: r> v

Comments:

Colorless to pale yellow

Chemistry of KassiteHide

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Mindat Formula:

CaTi2O4(OH)2

Crystallography of KassiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 5.275(1) Å, b = 9.009(2) Å, c = 9.557(2) Å
β = 90.43°

Ratio:

a:b:c = 0.586 : 1 : 1.061

Unit Cell V:

454.16 ų (Calculated from Unit Cell)

Morphology:

Flattened on {010}, the predominant face. Smaller {181} and {270} and minor {251}, {031} and {101}.

Twinning:

Twinning common on (101} and (181).

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0003155 Kassite Grey I E, Mumme W G, Pekov I V, Pushcharovsky D Y (2003) The crystal structure of chromian kassite from the Saranovskoye deposit, Northern Urals, Russia American Mineralogist 88 1331-1335 2003 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
4.763 Å (26)
3.300 Å (100)
3.273 Å (97)
2.603 Å (23)
2.316 Å (19)
2.282 Å (37)
1.776 Å (18)
1.762 Å (41)
1.516 Å (24)

Geological EnvironmentHide

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Type Occurrence of KassiteHide

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General Appearance of Type Material:

Crystals on the walls of miarolitic cavities. Forms pseudomorphs after perovskite and replaces ilmentite.

Place of Conservation of Type Material:

Mineralogcal Museum, St. Petersburg University, St. Petersburg, Russia, 17402.

Geological Setting of Type Material:

Miarolitic cavities of alkalic pegmatites.

Associated Minerals at Type Locality:

Reference:

Kukharenko, A.A., Orlova, M.P., Bulakh, A.G., Bagdasarov, E.A., Rimskaya-Korsakova, O.M., Nefedov, Y.I., Ilyinskiy, G.A., Sergeyev, A.C., Abakumova, N.B. (1965) The Caledonian complex of the ultrabasic alkaline rocks and carbonatites of the Kola Peninsula and northern Karelia. Izdatelstvo "Nedra" Moskva: 1965: 368-375.

Other Language Names for KassiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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4.DH. Fluornatropyrochlore (Na,Pb,Ca,REE,U)2Nb2O6F Iso. m_3_m _(_4/_m_32/m )
4.DH. Roméite Group A2(Sb5+)2O6Z
4.DH. Hydroxykenomicrolite (◻,Na,Sb3+)2Ta2O6(OH,Cs) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH. Fluornatroroméite (Na,Ca)2Sb2(O,OH)6F
4.DH. Oxyplumboroméite Pb2Sb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH. Cesiokenopyrochlore ◻Nb2(O,OH)6(Cs,◻) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH. Oxyyttrobetafite-(Y) Y2Ti2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.05 Brannerite UTi2O6 Mon. 2/m : _B_2/m
4.DH.05 Orthobrannerite U4+U6+Ti4O12(OH)2 Orth.
4.DH.05 Thorutite (Th,U,Ca)Ti2(O,OH)6 Mon.
4.DH.10 Lucasite-(Ce) CeTi2(O,OH)6 Mon.
4.DH.15 va Alumotungstite ◻2W2O6(H2O) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Bismutomicrolite (of Hogarth 1977) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydroplumboelsmoreite (Pb,◻)(W,Fe3+)2O6 · H2O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydropyrochlore (H2O,◻)2Nb2(O,OH)6(H2O) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Plumbomicrolite (of Hogarth 1977)
4.DH.15 Stibiomicrolite (of Groat et al.)
4.DH.15 Strontiopyrochlore (of Hogarth 1977) A2Nb2(O,OH)6Z
4.DH.15 Fluornatromicrolite (Na1.5Bi0.5)Ta2O6F Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Bismutopyrochlore (of Chukanov et al.) (Bi,Ca,U,Pb)2-xNb2(O,OH)6(OH) Amor.
4.DH.15 Hydrokenoelsmoreite ◻2W2O6(H2O) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Fluorcalciomicrolite (Ca,Na)2(Ta,Nb)2O6F Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Oxycalciobetafite Ca2(Ti,Nb)2O6O
4.DH.15 va Yttromicrolite (of Hogarth) (Ca,Y3+,U,Na)2-x(Ta,Nb,Ti,Fe3+)2O7 Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Oxynatropyrochlore (Na,Ca,U)2Nb2O6(O,OH)
4.DH.15 Hydroxycalciopyrochlore (Ca,Na,U,◻)2(Nb,Ti)2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Fluorcalciopyrochlore (Ca,Na)2(Nb, Ti)2O6F Iso.
4.DH.15 Oxycalciopyrochlore Ca2Nb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Fluorstrontiopyrochlore (Sr,◻)2Nb2(O,OH)6F
4.DH.15 Oxyplumbopyrochlore Pb2Nb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Kenoplumbopyrochlore (Pb,◻)Nb2O6(◻,O)
4.DH.15 Oxyyttropyrochlore-(Y) (Y,◻)2Nb2O6O
4.DH.15 Fluorkenopyrochlore (◻,Sr,Ce,Ca,Na)2(Nb,Ti)2O6F
4.DH.15 Oxyuranobetafite (U,Ca,◻)2(Ti,Nb)2O6O
4.DH.15 Oxycalciomicrolite Ca2Ta2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Oxystannomicrolite Sn2Ta2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Kenoplumbomicrolite (Pb,◻)2Ta2O6(◻,OH,O) Iso.
4.DH.15 Oxystibiomicrolite (Sb3+,Ca)2Ta2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydromicrolite (H2O,◻)2Ta2(O,OH)6(H2O)
4.DH.15 Hydrokenomicrolite (◻,H2O)2Ta2(O,OH)6(H2O) Iso. m_3_m _(_4/_m_32/m )
4.DH.15 Hydroxymanganopyrochlore (Mn2+,Th,Na,Ca,REE)2(Nb,Ti)2O6(OH) Iso. m_3(2/m_3)
4.DH.15 Hydroxycalciomicrolite Ca1.5Ta2O6(OH) Iso. 432 : _P_4232
4.DH.15 Fluorplumbopyrochlore (Pb,Y,Th,U,Na,Ca)2-x(Nb,Ti)2O6F Iso.
4.DH.15 Hydroxyplumbopyrochlore (Pb1.5◻0.5)Nb2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Oxynatromicrolite (Na,Ca,U)2(Ta,Nb)2O6(O,F) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Fluorhydropyrochlore
4.DH.15 Hydroxykenoelsmoreite (◻,Pb)2(W,Fe3+,Al)2(O,OH)6(OH) Trig. 3 : _R_3
4.DH.15 Hydrokenopyrochlore (◻,x)2Nb2O6(H2O,Cs) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydroxykenopyrochlore (◻,Ce,Ba)2(Nb,Ti)2O6(OH,F) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydroxynatropyrochlore (Na,Ca,Ce)2Nb2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Hydroxynatromicrolite (Na,Bi3+,◻)2Ta2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Unnamed (Sb-analogue of Hydroxymanganopyrochlor) (Mn,Ca,Y)2(Sb,Ti)2O6(OH)
4.DH.15 Oxybismutomicrolite (Bi1.33◻0.67)Σ2Ta2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.15 Oxyplumbopyrochlore Pb2Nb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.20 Bindheimite Pb2Sb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.20 Hydroxycalcioroméite (Ca,Sb3+)2(Sb5+,Ti)2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.20 Monimolite Pb2Sb5+2O7 Iso. m_3_m _(_4/_m_32/m )
4.DH.20 Cuproroméite Cu2Sb2(O,OH)7 Iso.
4.DH.20 Stetefeldtite Ag2Sb2(O,OH)7 Iso.
4.DH.20 Stibiconite Sb3+Sb5+2O6(OH) Iso. m_3_m _(_4/_m_32/m )
4.DH.20 Fluorcalcioroméite (Ca,Na,◻)2Sb5+2(O,OH)6F Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.20 Oxycalcioroméite Ca2Sb2O6O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.20 Hydroxyferroroméite (Fe2+1.5◻0.5)Sb5+2O6(OH) Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
4.DH.25 Rosiaite PbSb5+2O6 Trig. 3_m_ _(_32/m ) : P_31_m
4.DH.30 Zirconolite CaZrTi2O7 Orth.
4.DH.30 Laachite (Ca,Mn)2Zr2Nb2TiFeO14 Mon. 2/m : _B_2/b
4.DH.30 Nöggerathite-(Ce) (Ce,Ca)2Zr2(Nb,Ti)(Ti,Nb)2Fe2+O14 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a
4.DH.30 Stefanweissite (Ca,REE)2Zr2(Nb,Ti)(Ti,Nb)2Fe2+O14 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a
4.DH.35 Liandratite U(Nb,Ta)2O8 Trig. 3_m_ _(_32/m ) : P_31_m
4.DH.35 Petscheckite UFe(Nb,Ta)2O8 Hex.
4.DH.40 Ingersonite Ca3Mn2+Sb5+4O14 Trig. 32 : _P_3121
4.DH.45 Pittongite Na0.22(W,Fe3+)(O,OH)3 · 0.44H2O Hex. 6_m_2 : _P_6_m_2
4.DH.50 Tazzoliite Ba4-xNaxTi2Nb3SiO17[PO2(OH)2]x(OH)(1-2x) Orth. m m m _(_2/_m_2/_m_2/m ) : F m m m

Other InformationHide

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Thermal Behaviour:

DTA curve shows a small endothermic effect at 250-300 C, a large one at 600-700 C (loss of hydroxyl), and a sharp exothermic break at 800-850 C (formation of perovskite + rutile).

Notes:

Insoluble in acids.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for KassiteHide

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Reference List:

Kukharenko, A.A., Orlova, M.P., Bulakh, A.G., Bagdasarov, E.A., Rimskaya-Korsakova, O.M., Nefedov, Y.I., Ilyinskiy, G.A., Sergeyev, A.C., Abakumova, N.B. (1965) The Caledonian complex of the ultrabasic alkaline rocks and carbonatites of the Kola Peninsula and northern Karelia. Izdatelstvo "Nedra" Moskva: 1965: 368-375.

Bortolozzi, G., Boscardin, M., Rocchetti, I., Bersani, D. (2013): Cafetite e kassite della cava di Pilcante in Val d'Adige (Ala, Trento). Micro, 11, 1, 39-48.

Localities for KassiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Angola
Huíla Province Quilengues Mount Bonga Amores-Casals et al. (2019)
Canada
Ontario Thunder Bay District Killala Lake Area Prairie Lake carbonatite Martins et al. (2014)
China
Henan Pingdingshan Wugang County Wugang Fe ore field Batai Mine Zhao'anzhuang deposit ? Yu S. et al. (1982) +1 other reference
Hungary
Borsod-Abaúj-Zemplén County Edelény District Perkupa Zajzon et al. (2013)
India
Telangana Jogulamba Gadwal District Raichur kimberlite field SK-2 Kimberlite Xu et al. (2018)
Italy
Trentino-Alto Adige (Trentino-South Tyrol) Trento Province (Trentino) Ala Pilcante Val di Serra Quarry Bortolozzi et al. (2013)
Kazakhstan
Aktobe Region Kargaly District Kempirsai Cr deposit Main ore field Dzharlybutak Ore Group Almaz-Zhemchuzhina deposit Saveliev et al. (2023)
Geofizicheskoe-VII deposit Saveliev et al. (2023)
Russia
Magadan Oblast Severo-Evensky District Nevenrekan Deposit Priymenko et al. (2022)
Murmansk Oblast Afrikanda complex (TL) World of Stones 95: 5-6 +1 other reference
Khibiny Massif Rasvumchorr Mt Lapis 1996 (4)
Yukspor Mt Pavel.M. Kartashov (n.d.)
Perm Krai Gornozavodskii District Sarany Saranovskii Mine Am Min et al. (2003)
South Africa
Free State Thabo Mofutsanyane District Municipality Setsoto Local Municipality Clocolan Monastery Mine Kamenetsky et al. (2014)
USA
Arkansas Hot Spring County Magnet Cove Diamond Jo Quarry Evans et al. (1986)
Montana Meagher County Gordon Butte ? Chakhmouradian et al. (2002)
Oregon Josephine County Josephine Creek Mining District Josephine Creek placers Self et al. (1991)
Wyoming Laramie County Iron Mountain Kimberlite District Martins et al. (2014)