Kyanoxalite (original) (raw)
A valid IMA mineral species
About KyanoxaliteHide
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Formula:
Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)
Colour:
Pale bluish, bright blue, greenish-blue, grayish-blue or colorless
Name:
Name reflects the mineral's blue colour and the presence of oxalate.
Two kyanoxalite varieties are distinguished:
(1) with predominantly acid oxalate groups and
(2) predominantly neutral oxalate groups.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:38989:7
027b27a0-c973-4d79-b49b-594a48b19641
IMA Classification of KyanoxaliteHide
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IMA Formula:
Na7(Al5-6Si6-7O24)(C2O4)0.5-1.0 · 5H2O
Type description reference:
Classification of KyanoxaliteHide
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9.FB.05
9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.9.21
76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Kox | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of KyanoxaliteHide
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Colour:
Pale bluish, bright blue, greenish-blue, grayish-blue or colorless
Density:
2.30(1) g/cm3 (Measured) 2.327 g/cm3 (Calculated)
Optical Data of KyanoxaliteHide
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RI values:
_n_ω = 1.494(1) _n_ε = 1.491(1)
δ = 0.003
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Comments:
E = colourless, O = light blue
Chemistry of KyanoxaliteHide
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Mindat Formula:
Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)
Crystallography of KyanoxaliteHide
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Class (H-M):
6 - Pyramidal
Cell Parameters:
a = 12.6792(6) Å, c = 5.1772(2) Å
Unit Cell V:
720.79 ų (Calculated from Unit Cell)
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
6.39 Å | (44) |
4.73 Å | (92) |
3.679 Å | (72) |
3.264 Å | (100) |
2.618 Å | (36) |
2.437 Å | (24) |
2.126 Å | (29) |
Geological EnvironmentHide
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Type Occurrence of KyanoxaliteHide
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General Appearance of Type Material:
Colorless to pale bluish anhedral, isometric to prismatic grains to 2mm.
Place of Conservation of Type Material:
Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia, registration 3735/1.
Geological Setting of Type Material:
Typically in tiny veinlets between nepheline grains or as replacement rims surrounding sodalite-nosean masses in matrix.
Associated Minerals at Type Locality:
Reference:
Chukanov, N.V., Pekov, I.V., Olysych, L.V., Massa, W., Yakubovich, O.V., Zadov, A.E., Rastsvetaeva, R.K., Vigasina, M.F. (2009) Kyanoxalite - a new cancrinite-group mineral with extra-framework oxalate anion, from Lovozero alkaline massif, Kola Peninsula. Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva: 138(6): 18-35.
Synonyms of KyanoxaliteHide
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Relationship of Kyanoxalite to other SpeciesHide
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Other Members of this group:
Afghanite | (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 | Trig. 3_m_ : P_31_c |
---|---|---|
Alloriite | (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 | Trig. 3_m_ : P_31_c |
Balliranoite | (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) | Hex. 6 : _P_63 |
Betzite | Na6Ca2(Al6Si6O24)Cl4 | Hex. 6 : _P_63 |
Biachellaite | (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O | Trig. 3 : _P_3 |
Bystrite | (Na,K)7Ca(Al6Si6O24)(S5)Cl | Trig. 3_m_ : P_31_c |
Cancrinite | (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O | Hex. 6 : _P_63 |
Cancrisilite | Na7(Al5Si7O24)(CO3) · 3H2O | Hex. 6_m_ m : P_63_m c |
Carbobystrite | Na8(Al6Si6O24)(CO3) · 3.5H2O | Trig. 3_m_ : P_31_c |
Davyne | (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 | Hex. 6/m : _P_63/m |
Depmeierite | Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) | Hex. 6 : _P_63 |
Fantappièite | [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O | Trig. 3 : _R_3 |
Farneseite | (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O | Hex. 6/m : _P_63/m |
Franzinite | (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O | Hex. |
Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 | Trig. 3_m_ : P_31_c |
Hydroxycancrinite | Na8(Al6Si6O24)(OH)2 · 2H2O | Hex. 6 : _P_63 |
Kircherite | Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O | Trig. 32 : _R_32 |
Liottite | (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 | Hex. 6 : _P_6 |
Marinellite | (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O | Trig. 3_m_ : P_31_c |
Microsommite | Na4K2Ca2(Al6Si6O24)(SO4)Cl2 | Hex. 622 : _P_6322 |
Pitiglianoite | Na6K2(Al6Si6O24)(SO4) · 2H2O | Hex. 6 : _P_63 |
Quadridavyne | (Na,K)6Ca2(Al6Si6O24)Cl4 | Hex. 6/m : _P_63/m |
Sacrofanite | (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O | Hex. |
Steudelite | Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O | Hex. 6_m_2 : P_62_c |
Sulfhydrylbystrite | Na5K2Ca[Al6Si6O24](S5)2(SH) | Trig. 3_m_ : P_31_c |
Tounkite | (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O | Hex. 622 : _P_6222 |
UM2004-48-SiO:AlClCaNaS | (Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3 | |
UM2009-23-SiO:AlCCaClHKNaS | (Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2O | Trig. 3 : _P_3 |
Vishnevite | (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O | Hex. 6 : _P_63 |
Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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9.FB. | Steudelite | Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O | Hex. 6_m_2 : P_62_c |
---|---|---|---|
9.FB. | Sapozhnikovite | Na8(Al6Si6O24)(HS)2 | Iso. 43_m_ : P_43_n |
9.FB. | Betzite | Na6Ca2(Al6Si6O24)Cl4 | Hex. 6 : _P_63 |
9.FB. | Slyudyankaite | Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O | Tric. 1 : _P_1 |
9.FB. | Bolotinaite | (Na7◻)(Al6Si6O24)F · 4H2O | Iso. 43_m_ : I_43_m |
9.FB. | Wenlanzhangite-(Y) | Y2V3+2V4+2(SiO4)2O4(OH)4 | Tric. 1 : _P_1 |
9.FB.05 | Afghanite | (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 | Trig. 3_m_ : P_31_c |
9.FB.05 | Bystrite | (Na,K)7Ca(Al6Si6O24)(S5)Cl | Trig. 3_m_ : P_31_c |
9.FB.05 | Cancrinite | (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Cancrisilite | Na7(Al5Si7O24)(CO3) · 3H2O | Hex. 6_m_ m : P_63_m c |
9.FB.05 | Davyne | (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 | Hex. 6/m : _P_63/m |
9.FB.05 | Franzinite | (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O | Hex. |
9.FB.05 | Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 | Trig. 3_m_ : P_31_c |
9.FB.05 | Hydroxycancrinite | Na8(Al6Si6O24)(OH)2 · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Liottite | (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 | Hex. 6 : _P_6 |
9.FB.05 | Microsommite | Na4K2Ca2(Al6Si6O24)(SO4)Cl2 | Hex. 622 : _P_6322 |
9.FB.05 | Pitiglianoite | Na6K2(Al6Si6O24)(SO4) · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Quadridavyne | (Na,K)6Ca2(Al6Si6O24)Cl4 | Hex. 6/m : _P_63/m |
9.FB.05 | Sacrofanite | (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O | Hex. |
9.FB.05 | Tounkite | (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O | Hex. 622 : _P_6222 |
9.FB.05 | Vishnevite | (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Marinellite | (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O | Trig. 3_m_ : P_31_c |
9.FB.05 | Farneseite | (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O | Hex. 6/m : _P_63/m |
9.FB.05 | Alloriite | (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 | Trig. 3_m_ : P_31_c |
9.FB.05 | Biachellaite | (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O | Trig. 3 : _P_3 |
9.FB.05 | Fantappièite | [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O | Trig. 3 : _R_3 |
9.FB.05 | Balliranoite | (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) | Hex. 6 : _P_63 |
9.FB.05 | Carbobystrite | Na8(Al6Si6O24)(CO3) · 3.5H2O | Trig. 3_m_ : P_31_c |
9.FB.05 | Depmeierite | Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) | Hex. 6 : _P_63 |
9.FB.05 | Kircherite | Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O | Trig. 32 : _R_32 |
9.FB.05 | Sulfhydrylbystrite | Na5K2Ca[Al6Si6O24](S5)2(SH) | Trig. 3_m_ : P_31_c |
9.FB.10 | Bicchulite | Ca2(Al2SiO6)(OH)2 | Iso. 43_m_ : I_43_m |
9.FB.10 | Danalite | Be3Fe2+4(SiO4)3S | Iso. 43_m_ : P_43_n |
9.FB.10 | Genthelvite | Be3Zn4(SiO4)3S | Iso. 43_m_ : P_43_n |
9.FB.10 | Haüyne | Na3Ca(Si3Al3)O12(SO4) | Iso. 43_m_ : P_43_n |
9.FB.10 | Helvine | Be3Mn2+4(SiO4)3S | Iso. 43_m_ : P_43_n |
9.FB.10 | Kamaishilite | Ca2(Al2SiO6)(OH)2 | Tet. |
9.FB.10 | Lazurite | Na7Ca(Al6Si6O24)(SO4)(S3) · H2O | Iso. 43_m_ : P_43_n |
9.FB.10 | Nosean | Na8(Al6Si6O24)(SO4) · H2O | Iso. 43_m_ : P_43_n |
9.FB.10 | Sodalite | Na4(Si3Al3)O12Cl | Iso. 43_m_ : P_43_n |
9.FB.10 | Tsaregorodtsevite | (N(CH3)4)(AlSi5O12) | Orth. 222 : _I_222 |
9.FB.10 | Tugtupite | Na4BeAlSi4O12Cl | Tet. 4 : _I_4 |
9.FB.10 | Vladimirivanovite | Na6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2O | Orth. m m m _(_2/_m_2/_m_2/m ) |
9.FB.15 | Marialite | Na4Al3Si9O24Cl | Tet. 4/m : _I_4/m |
9.FB.15 | Meionite | Ca4Al6Si6O24CO3 | Tet. 4/m : _I_4/m |
9.FB.15 | Silvialite | (Ca,Na)4(Al6Si6O24)(SO4,CO3) | Tet. 4/m : _I_4/m |
Other InformationHide
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Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for KyanoxaliteHide
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References for KyanoxaliteHide
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Reference List:
Pekov, I. V., Olysych, L. V., Chukanov, N. V., Zubkova, N. V., Pushcharovsky, D. Y., Van, K. V., Giester, G., Tillmanns, E. (2011) Crystal chemistry of cancrinite-group minerals with an AB-type framework: A review and new data. I. Chemical and structural variations. The Canadian Mineralogist, 49 (5) 1129-1150 doi:10.3749/canmin.49.5.1129
Chukanov, N. V., Pekov, I. V., Olysych, L. V., Zubkova, N. V., Vigasina, M. F. (2011) Crystal chemistry of cancrinite-group minerals with an AB-type framework: A review and new data. II. IR spectroscopy and its crystal-chemical implications. The Canadian Mineralogist, 49 (5) 1151-1164 doi:10.3749/canmin.49.5.1151
Chukanov, Nikita V., Vigasina, Marina F., Shendrik, Roman Yu., Varlamov, Dmitry A., Pekov, Igor V., Zubkova, Natalia V. (2022) Nature and Isomorphism of Extra-Framework Components in Cancrinite- and Sodalite-Related Minerals: New Data. Minerals, 12 (6) 729 doi:10.3390/min12060729
Localities for KyanoxaliteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
Russia | |
---|---|
Murmansk Oblast Lovozersky District ⓘ Alluaiv Mountain | Kyanoxalite et al. (from Geology of Ore Deposits) |
ⓘ Karnasurt Mountain (TL) | Chukanov et al. (2009) |
ⓘ Selsurt Mountain | Chukanov +6 other references |