Kyanoxalite (original) (raw)

A valid IMA mineral species

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About KyanoxaliteHide

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Formula:

Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)

Colour:

Pale bluish, bright blue, greenish-blue, grayish-blue or colorless

Name:

Name reflects the mineral's blue colour and the presence of oxalate.

Cancrinite group

Two kyanoxalite varieties are distinguished:
(1) with predominantly acid oxalate groups and
(2) predominantly neutral oxalate groups.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:38989:7

027b27a0-c973-4d79-b49b-594a48b19641

IMA Classification of KyanoxaliteHide

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IMA Formula:

Na7(Al5-6Si6-7O24)(C2O4)0.5-1.0 · 5H2O

Type description reference:

Chukanov, N.V., Pekov, I.V., Olysych, L.V., Massa, W., Yakubovich, O.V., Zadov, A.E., Rastsvetaeva, R.K., Vigasina, M.F. (2009) Kyanoxalite - a new cancrinite-group mineral with extra-framework oxalate anion, from Lovozero alkaline massif, Kola Peninsula. Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva: 138(6): 18-35.

Classification of KyanoxaliteHide

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9.FB.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions

76.2.9.21

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Kox IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KyanoxaliteHide

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Colour:

Pale bluish, bright blue, greenish-blue, grayish-blue or colorless

Density:

2.30(1) g/cm3 (Measured) 2.327 g/cm3 (Calculated)

Optical Data of KyanoxaliteHide

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RI values:

_n_ω = 1.494(1) _n_ε = 1.491(1)

δ = 0.003

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

E = colourless, O = light blue

Chemistry of KyanoxaliteHide

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Mindat Formula:

Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)

Crystallography of KyanoxaliteHide

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Class (H-M):

6 - Pyramidal

Cell Parameters:

a = 12.6792(6) Å, c = 5.1772(2) Å

Unit Cell V:

720.79 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
6.39 Å (44)
4.73 Å (92)
3.679 Å (72)
3.264 Å (100)
2.618 Å (36)
2.437 Å (24)
2.126 Å (29)

Geological EnvironmentHide

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Type Occurrence of KyanoxaliteHide

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General Appearance of Type Material:

Colorless to pale bluish anhedral, isometric to prismatic grains to 2mm.

Place of Conservation of Type Material:

Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia, registration 3735/1.

Geological Setting of Type Material:

Typically in tiny veinlets between nepheline grains or as replacement rims surrounding sodalite-nosean masses in matrix.

Associated Minerals at Type Locality:

Reference:

Chukanov, N.V., Pekov, I.V., Olysych, L.V., Massa, W., Yakubovich, O.V., Zadov, A.E., Rastsvetaeva, R.K., Vigasina, M.F. (2009) Kyanoxalite - a new cancrinite-group mineral with extra-framework oxalate anion, from Lovozero alkaline massif, Kola Peninsula. Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva: 138(6): 18-35.

Synonyms of KyanoxaliteHide

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Relationship of Kyanoxalite to other SpeciesHide

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Other Members of this group:

Afghanite (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 Trig. 3_m_ : P_31_c
Alloriite (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 Trig. 3_m_ : P_31_c
Balliranoite (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) Hex. 6 : _P_63
Betzite Na6Ca2(Al6Si6O24)Cl4 Hex. 6 : _P_63
Biachellaite (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O Trig. 3 : _P_3
Bystrite (Na,K)7Ca(Al6Si6O24)(S5)Cl Trig. 3_m_ : P_31_c
Cancrinite (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O Hex. 6 : _P_63
Cancrisilite Na7(Al5Si7O24)(CO3) · 3H2O Hex. 6_m_ m : P_63_m c
Carbobystrite Na8(Al6Si6O24)(CO3) · 3.5H2O Trig. 3_m_ : P_31_c
Davyne (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 Hex. 6/m : _P_63/m
Depmeierite Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) Hex. 6 : _P_63
Fantappièite [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O Trig. 3 : _R_3
Farneseite (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O Hex. 6/m : _P_63/m
Franzinite (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O Hex.
Giuseppettite (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 Trig. 3_m_ : P_31_c
Hydroxycancrinite Na8(Al6Si6O24)(OH)2 · 2H2O Hex. 6 : _P_63
Kircherite Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O Trig. 32 : _R_32
Liottite (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 Hex. 6 : _P_6
Marinellite (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O Trig. 3_m_ : P_31_c
Microsommite Na4K2Ca2(Al6Si6O24)(SO4)Cl2 Hex. 622 : _P_6322
Pitiglianoite Na6K2(Al6Si6O24)(SO4) · 2H2O Hex. 6 : _P_63
Quadridavyne (Na,K)6Ca2(Al6Si6O24)Cl4 Hex. 6/m : _P_63/m
Sacrofanite (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O Hex.
Steudelite Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O Hex. 6_m_2 : P_62_c
Sulfhydrylbystrite Na5K2Ca[Al6Si6O24](S5)2(SH) Trig. 3_m_ : P_31_c
Tounkite (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O Hex. 622 : _P_6222
UM2004-48-SiO:AlClCaNaS (Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3
UM2009-23-SiO:AlCCaClHKNaS (Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2O Trig. 3 : _P_3
Vishnevite (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O Hex. 6 : _P_63

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.FB. Steudelite Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O Hex. 6_m_2 : P_62_c
9.FB. Sapozhnikovite Na8(Al6Si6O24)(HS)2 Iso. 43_m_ : P_43_n
9.FB. Betzite Na6Ca2(Al6Si6O24)Cl4 Hex. 6 : _P_63
9.FB. Slyudyankaite Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O Tric. 1 : _P_1
9.FB. Bolotinaite (Na7◻)(Al6Si6O24)F · 4H2O Iso. 43_m_ : I_43_m
9.FB. Wenlanzhangite-(Y) Y2V3+2V4+2(SiO4)2O4(OH)4 Tric. 1 : _P_1
9.FB.05 Afghanite (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 Trig. 3_m_ : P_31_c
9.FB.05 Bystrite (Na,K)7Ca(Al6Si6O24)(S5)Cl Trig. 3_m_ : P_31_c
9.FB.05 Cancrinite (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O Hex. 6 : _P_63
9.FB.05 Cancrisilite Na7(Al5Si7O24)(CO3) · 3H2O Hex. 6_m_ m : P_63_m c
9.FB.05 Davyne (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 Hex. 6/m : _P_63/m
9.FB.05 Franzinite (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O Hex.
9.FB.05 Giuseppettite (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 Trig. 3_m_ : P_31_c
9.FB.05 Hydroxycancrinite Na8(Al6Si6O24)(OH)2 · 2H2O Hex. 6 : _P_63
9.FB.05 Liottite (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 Hex. 6 : _P_6
9.FB.05 Microsommite Na4K2Ca2(Al6Si6O24)(SO4)Cl2 Hex. 622 : _P_6322
9.FB.05 Pitiglianoite Na6K2(Al6Si6O24)(SO4) · 2H2O Hex. 6 : _P_63
9.FB.05 Quadridavyne (Na,K)6Ca2(Al6Si6O24)Cl4 Hex. 6/m : _P_63/m
9.FB.05 Sacrofanite (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O Hex.
9.FB.05 Tounkite (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O Hex. 622 : _P_6222
9.FB.05 Vishnevite (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O Hex. 6 : _P_63
9.FB.05 Marinellite (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O Trig. 3_m_ : P_31_c
9.FB.05 Farneseite (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O Hex. 6/m : _P_63/m
9.FB.05 Alloriite (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 Trig. 3_m_ : P_31_c
9.FB.05 Biachellaite (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O Trig. 3 : _P_3
9.FB.05 Fantappièite [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O Trig. 3 : _R_3
9.FB.05 Balliranoite (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) Hex. 6 : _P_63
9.FB.05 Carbobystrite Na8(Al6Si6O24)(CO3) · 3.5H2O Trig. 3_m_ : P_31_c
9.FB.05 Depmeierite Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) Hex. 6 : _P_63
9.FB.05 Kircherite Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O Trig. 32 : _R_32
9.FB.05 Sulfhydrylbystrite Na5K2Ca[Al6Si6O24](S5)2(SH) Trig. 3_m_ : P_31_c
9.FB.10 Bicchulite Ca2(Al2SiO6)(OH)2 Iso. 43_m_ : I_43_m
9.FB.10 Danalite Be3Fe2+4(SiO4)3S Iso. 43_m_ : P_43_n
9.FB.10 Genthelvite Be3Zn4(SiO4)3S Iso. 43_m_ : P_43_n
9.FB.10 Haüyne Na3Ca(Si3Al3)O12(SO4) Iso. 43_m_ : P_43_n
9.FB.10 Helvine Be3Mn2+4(SiO4)3S Iso. 43_m_ : P_43_n
9.FB.10 Kamaishilite Ca2(Al2SiO6)(OH)2 Tet.
9.FB.10 Lazurite Na7Ca(Al6Si6O24)(SO4)(S3) · H2O Iso. 43_m_ : P_43_n
9.FB.10 Nosean Na8(Al6Si6O24)(SO4) · H2O Iso. 43_m_ : P_43_n
9.FB.10 Sodalite Na4(Si3Al3)O12Cl Iso. 43_m_ : P_43_n
9.FB.10 Tsaregorodtsevite (N(CH3)4)(AlSi5O12) Orth. 222 : _I_222
9.FB.10 Tugtupite Na4BeAlSi4O12Cl Tet. 4 : _I_4
9.FB.10 Vladimirivanovite Na6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2O Orth. m m m _(_2/_m_2/_m_2/m )
9.FB.15 Marialite Na4Al3Si9O24Cl Tet. 4/m : _I_4/m
9.FB.15 Meionite Ca4Al6Si6O24CO3 Tet. 4/m : _I_4/m
9.FB.15 Silvialite (Ca,Na)4(Al6Si6O24)(SO4,CO3) Tet. 4/m : _I_4/m

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for KyanoxaliteHide

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Reference List:

Chukanov, N.V., Pekov, I.V., Olysych, L.V., Massa, W., Yakubovich, O.V., Zadov, A.E., Rastsvetaeva, R.K., Vigasina, M.F. (2009) Kyanoxalite - a new cancrinite-group mineral with extra-framework oxalate anion, from Lovozero alkaline massif, Kola Peninsula. Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva: 138(6): 18-35.

Pekov, I. V., Olysych, L. V., Chukanov, N. V., Zubkova, N. V., Pushcharovsky, D. Y., Van, K. V., Giester, G., Tillmanns, E. (2011) Crystal chemistry of cancrinite-group minerals with an AB-type framework: A review and new data. I. Chemical and structural variations. The Canadian Mineralogist, 49 (5) 1129-1150 doi:10.3749/canmin.49.5.1129

Chukanov, N. V., Pekov, I. V., Olysych, L. V., Zubkova, N. V., Vigasina, M. F. (2011) Crystal chemistry of cancrinite-group minerals with an AB-type framework: A review and new data. II. IR spectroscopy and its crystal-chemical implications. The Canadian Mineralogist, 49 (5) 1151-1164 doi:10.3749/canmin.49.5.1151

Chukanov, Nikita V., Vigasina, Marina F., Shendrik, Roman Yu., Varlamov, Dmitry A., Pekov, Igor V., Zubkova, Natalia V. (2022) Nature and Isomorphism of Extra-Framework Components in Cancrinite- and Sodalite-Related Minerals: New Data. Minerals, 12 (6) 729 doi:10.3390/min12060729

Localities for KyanoxaliteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Russia
Murmansk Oblast Lovozersky District Alluaiv Mountain Kyanoxalite et al. (from Geology of Ore Deposits)
Karnasurt Mountain (TL) Chukanov et al. (2009)
Selsurt Mountain Chukanov +6 other references