Tsaregorodtsevite (original) (raw)
A valid IMA mineral species
About TsaregorodtseviteHide
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Formula:
(N(CH3)4)(AlSi5O12)
Colour:
Colourless to white
Crystal System:
Orthorhombic
Name:
Named after Sergei Vasil'evich Tsaregorodtsev (Сергей Васильевич Царегородцев) (1953-1986), Russian mineral collector of the Urals.
Sodalite Group. The mineral contains (as the only one known) the tetramethylammonium ion, [N(CH3)4]+.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:4034:7
77c00846-687a-4f60-82c5-f8f814036161
IMA Classification of TsaregorodtseviteHide
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IMA Formula:
N(CH3)4Si4(SiAl)O12
Type description reference:
Classification of TsaregorodtseviteHide
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9.FB.10
9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.3.8
76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Tsa | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of TsaregorodtseviteHide
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Colour:
Colourless to white
Hardness:
VHN120=796 - 893 kg/mm2 - Vickers
Density:
2.04(5) g/cm3 (Measured) 2.01 g/cm3 (Calculated)
Optical Data of TsaregorodtseviteHide
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RI values:
_n_α = 1.529(2) _n_γ = 1.531(2)
δ = 0.002
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Chemistry of TsaregorodtseviteHide
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Mindat Formula:
(N(CH3)4)(AlSi5O12)
Crystallography of TsaregorodtseviteHide
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Crystal System:
Orthorhombic
Class (H-M):
222 - Disphenoidal
Cell Parameters:
a = 8.984(3) Å, b = 8.937(2) Å, c = 8.927(2) Å
Ratio:
a:b:c = 1.005 : 1 : 0.999
Unit Cell V:
716.75 ų (Calculated from Unit Cell)
Twinning:
Commonly sector twinned, as seen in thin section.
Crystal StructureHide
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ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0012488 | Tsaregorodtsevite | Sokolova E V, Rybakov V B, Pautov L A, Pushcharovsky D Yu (1993) Structural changes in tsaregorodtsevite Doklady Akademii Nauk SSSR 332 309-312 | 1993 | 0 | 293 | ||
0012489 | Tsaregorodtsevite | Sokolova E V, Rybakov V B, Pautov L A, Pushcharovsky D Yu (1993) Structural changes in tsaregorodtsevite Doklady Akademii Nauk SSSR 332 309-312 | 1993 | 0 | 1143 | ||
0012490 | Tsaregorodtsevite | Sokolova E V, Rybakov V B, Pautov L A, Pushcharovsky D Yu (1993) Structural changes in tsaregorodtsevite Doklady Akademii Nauk SSSR 332 309-312 | 1993 | 0 | 1243 | ||
0020490 | Tsaregorodtsevite | Sokolova E V, Rybakov V B, Pautov L A (1991) The crystal structure of a new natural tetramethylammonium aluminosilicate [N(CH3)4][Si2(Si0.5Al0.5)O6]2 Soviet Physics Doklady 36 267-269 | 1991 | Northern Ural Mountains, Mankhambo region, Russia | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder DiffractionHide
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Radiation - Copper Kα
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.66 Å | (100) |
4.46 Å | (82) |
6.33 Å | (60) |
2.586 Å | (15) |
4.50 Å | (12b) |
3.16 Å | (12) |
2.832 Å | (10) |
Comments:
very close to ammonian sodalite
Geological EnvironmentHide
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Type Occurrence of TsaregorodtseviteHide
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General Appearance of Type Material:
Pseudocubic crystals, to 1 cm
Place of Conservation of Type Material:
Mining Institute, St. Petersburg, 2054/1; Il'menskii Preserve Museum, Miass, 3303, 3374, 5121; Vernadsky Geological Museum, Moscow, 59719, 59859; A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 87949; National Museum, Sofint5a, Bulgaria; National Museum, Prague, Czech Republic.
Reference:
Pautov, L.A., Karpenko, V.Y., Sokolova, E.V., Ignatenko, K.I. (1993) Tsaregorodtsevite N(CH3)4[Si2(Si0.5Al0.5)O6]2 — a new mineral. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 128(1): 128-135.
Synonyms of TsaregorodtseviteHide
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Other Language Names for TsaregorodtseviteHide
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Relationship of Tsaregorodtsevite to other SpeciesHide
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Other Members of this group:
Bolotinaite | (Na7◻)(Al6Si6O24)F · 4H2O | Iso. 43_m_ : I_43_m |
---|---|---|
Haüyne | Na3Ca(Si3Al3)O12(SO4) | Iso. 43_m_ : P_43_n |
Lazurite | Na7Ca(Al6Si6O24)(SO4)(S3) · H2O | Iso. 43_m_ : P_43_n |
Nosean | Na8(Al6Si6O24)(SO4) · H2O | Iso. 43_m_ : P_43_n |
Sapozhnikovite | Na8(Al6Si6O24)(HS)2 | Iso. 43_m_ : P_43_n |
Slyudyankaite | Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O | Tric. 1 : _P_1 |
Sodalite | Na4(Si3Al3)O12Cl | Iso. 43_m_ : P_43_n |
Vladimirivanovite | Na6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2O | Orth. m m m _(_2/_m_2/_m_2/m ) |
Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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9.FB. | Steudelite | Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O | Hex. 6_m_2 : P_62_c |
---|---|---|---|
9.FB. | Sapozhnikovite | Na8(Al6Si6O24)(HS)2 | Iso. 43_m_ : P_43_n |
9.FB. | Betzite | Na6Ca2(Al6Si6O24)Cl4 | Hex. 6 : _P_63 |
9.FB. | Slyudyankaite | Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O | Tric. 1 : _P_1 |
9.FB. | Bolotinaite | (Na7◻)(Al6Si6O24)F · 4H2O | Iso. 43_m_ : I_43_m |
9.FB. | Wenlanzhangite-(Y) | Y2V3+2V4+2(SiO4)2O4(OH)4 | Tric. 1 : _P_1 |
9.FB.05 | Afghanite | (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 | Trig. 3_m_ : P_31_c |
9.FB.05 | Bystrite | (Na,K)7Ca(Al6Si6O24)(S5)Cl | Trig. 3_m_ : P_31_c |
9.FB.05 | Cancrinite | (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Cancrisilite | Na7(Al5Si7O24)(CO3) · 3H2O | Hex. 6_m_ m : P_63_m c |
9.FB.05 | Davyne | (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 | Hex. 6/m : _P_63/m |
9.FB.05 | Franzinite | (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O | Hex. |
9.FB.05 | Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 | Trig. 3_m_ : P_31_c |
9.FB.05 | Hydroxycancrinite | Na8(Al6Si6O24)(OH)2 · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Liottite | (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 | Hex. 6 : _P_6 |
9.FB.05 | Microsommite | Na4K2Ca2(Al6Si6O24)(SO4)Cl2 | Hex. 622 : _P_6322 |
9.FB.05 | Pitiglianoite | Na6K2(Al6Si6O24)(SO4) · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Quadridavyne | (Na,K)6Ca2(Al6Si6O24)Cl4 | Hex. 6/m : _P_63/m |
9.FB.05 | Sacrofanite | (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O | Hex. |
9.FB.05 | Tounkite | (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O | Hex. 622 : _P_6222 |
9.FB.05 | Vishnevite | (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O | Hex. 6 : _P_63 |
9.FB.05 | Marinellite | (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O | Trig. 3_m_ : P_31_c |
9.FB.05 | Farneseite | (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O | Hex. 6/m : _P_63/m |
9.FB.05 | Alloriite | (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 | Trig. 3_m_ : P_31_c |
9.FB.05 | Biachellaite | (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O | Trig. 3 : _P_3 |
9.FB.05 | Fantappièite | [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O | Trig. 3 : _R_3 |
9.FB.05 | Kyanoxalite | Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5) | Hex. 6 : _P_63 |
9.FB.05 | Balliranoite | (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) | Hex. 6 : _P_63 |
9.FB.05 | Carbobystrite | Na8(Al6Si6O24)(CO3) · 3.5H2O | Trig. 3_m_ : P_31_c |
9.FB.05 | Depmeierite | Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) | Hex. 6 : _P_63 |
9.FB.05 | Kircherite | Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O | Trig. 32 : _R_32 |
9.FB.05 | Sulfhydrylbystrite | Na5K2Ca[Al6Si6O24](S5)2(SH) | Trig. 3_m_ : P_31_c |
9.FB.10 | Bicchulite | Ca2(Al2SiO6)(OH)2 | Iso. 43_m_ : I_43_m |
9.FB.10 | Danalite | Be3Fe2+4(SiO4)3S | Iso. 43_m_ : P_43_n |
9.FB.10 | Genthelvite | Be3Zn4(SiO4)3S | Iso. 43_m_ : P_43_n |
9.FB.10 | Haüyne | Na3Ca(Si3Al3)O12(SO4) | Iso. 43_m_ : P_43_n |
9.FB.10 | Helvine | Be3Mn2+4(SiO4)3S | Iso. 43_m_ : P_43_n |
9.FB.10 | Kamaishilite | Ca2(Al2SiO6)(OH)2 | Tet. |
9.FB.10 | Lazurite | Na7Ca(Al6Si6O24)(SO4)(S3) · H2O | Iso. 43_m_ : P_43_n |
9.FB.10 | Nosean | Na8(Al6Si6O24)(SO4) · H2O | Iso. 43_m_ : P_43_n |
9.FB.10 | Sodalite | Na4(Si3Al3)O12Cl | Iso. 43_m_ : P_43_n |
9.FB.10 | Tugtupite | Na4BeAlSi4O12Cl | Tet. 4 : _I_4 |
9.FB.10 | Vladimirivanovite | Na6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2O | Orth. m m m _(_2/_m_2/_m_2/m ) |
9.FB.15 | Marialite | Na4Al3Si9O24Cl | Tet. 4/m : _I_4/m |
9.FB.15 | Meionite | Ca4Al6Si6O24CO3 | Tet. 4/m : _I_4/m |
9.FB.15 | Silvialite | (Ca,Na)4(Al6Si6O24)(SO4,CO3) | Tet. 4/m : _I_4/m |
Other InformationHide
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Thermal Behaviour:
Evolves ammonia and eurotropine above 600°C, becoming pitch-black.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for TsaregorodtseviteHide
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References for TsaregorodtseviteHide
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Reference List:
Localities for TsaregorodtseviteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
Poland | |
---|---|
Lower Silesian Voivodeship Kłodzko County Nowa Ruda Słupiec Mine ⓘ Słupiec heap ? | Ł. Kruszewski (PXRD data) |
Silesian Voivodeship Wodzisław County Radlin ⓘ Marcel mine heap ? | Łukasz Kruszewski (2012) |
Russia (TL) | |
Khanty-Mansi Autonomous Okrug Man'-Khambo Mountains ⓘ Yaruta Mt (TL) | Pekov (1998) |