Tsaregorodtsevite (original) (raw)

A valid IMA mineral species

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About TsaregorodtseviteHide

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Formula:

(N(CH3)4)(AlSi5O12)

Colour:

Colourless to white

Crystal System:

Orthorhombic

Name:

Named after Sergei Vasil'evich Tsaregorodtsev (Сергей Васильевич Царегородцев) (1953-1986), Russian mineral collector of the Urals.

Sodalite Group. The mineral contains (as the only one known) the tetramethylammonium ion, [N(CH3)4]+.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:4034:7

77c00846-687a-4f60-82c5-f8f814036161

IMA Classification of TsaregorodtseviteHide

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IMA Formula:

N(CH3)4Si4(SiAl)O12

Type description reference:

Classification of TsaregorodtseviteHide

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9.FB.10

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions

76.2.3.8

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Tsa IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TsaregorodtseviteHide

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Colour:

Colourless to white

Hardness:

VHN120=796 - 893 kg/mm2 - Vickers

Density:

2.04(5) g/cm3 (Measured) 2.01 g/cm3 (Calculated)

Optical Data of TsaregorodtseviteHide

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RI values:

_n_α = 1.529(2) _n_γ = 1.531(2)

δ = 0.002

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of TsaregorodtseviteHide

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Mindat Formula:

(N(CH3)4)(AlSi5O12)

Crystallography of TsaregorodtseviteHide

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Crystal System:

Orthorhombic

Class (H-M):

222 - Disphenoidal

Cell Parameters:

a = 8.984(3) Å, b = 8.937(2) Å, c = 8.927(2) Å

Ratio:

a:b:c = 1.005 : 1 : 0.999

Unit Cell V:

716.75 ų (Calculated from Unit Cell)

Twinning:

Commonly sector twinned, as seen in thin section.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0012488 Tsaregorodtsevite Sokolova E V, Rybakov V B, Pautov L A, Pushcharovsky D Yu (1993) Structural changes in tsaregorodtsevite Doklady Akademii Nauk SSSR 332 309-312 1993 0 293
0012489 Tsaregorodtsevite Sokolova E V, Rybakov V B, Pautov L A, Pushcharovsky D Yu (1993) Structural changes in tsaregorodtsevite Doklady Akademii Nauk SSSR 332 309-312 1993 0 1143
0012490 Tsaregorodtsevite Sokolova E V, Rybakov V B, Pautov L A, Pushcharovsky D Yu (1993) Structural changes in tsaregorodtsevite Doklady Akademii Nauk SSSR 332 309-312 1993 0 1243
0020490 Tsaregorodtsevite Sokolova E V, Rybakov V B, Pautov L A (1991) The crystal structure of a new natural tetramethylammonium aluminosilicate [N(CH3)4][Si2(Si0.5Al0.5)O6]2 Soviet Physics Doklady 36 267-269 1991 Northern Ural Mountains, Mankhambo region, Russia 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Radiation - Copper Kα

Data Set:

Data courtesy of RRUFF project at University of Arizona, used with permission.

Powder Diffraction Data:

d-spacing Intensity
3.66 Å (100)
4.46 Å (82)
6.33 Å (60)
2.586 Å (15)
4.50 Å (12b)
3.16 Å (12)
2.832 Å (10)

Comments:

very close to ammonian sodalite

Geological EnvironmentHide

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Type Occurrence of TsaregorodtseviteHide

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General Appearance of Type Material:

Pseudocubic crystals, to 1 cm

Place of Conservation of Type Material:

Mining Institute, St. Petersburg, 2054/1; Il'menskii Preserve Museum, Miass, 3303, 3374, 5121; Vernadsky Geological Museum, Moscow, 59719, 59859; A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 87949; National Museum, Sofint5a, Bulgaria; National Museum, Prague, Czech Republic.

Reference:

Pautov, L.A., Karpenko, V.Y., Sokolova, E.V., Ignatenko, K.I. (1993) Tsaregorodtsevite N(CH3)4[Si2(Si0.5Al0.5)O6]2 — a new mineral. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 128(1): 128-135.

Synonyms of TsaregorodtseviteHide

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Other Language Names for TsaregorodtseviteHide

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Relationship of Tsaregorodtsevite to other SpeciesHide

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Other Members of this group:

Bolotinaite (Na7◻)(Al6Si6O24)F · 4H2O Iso. 43_m_ : I_43_m
Haüyne Na3Ca(Si3Al3)O12(SO4) Iso. 43_m_ : P_43_n
Lazurite Na7Ca(Al6Si6O24)(SO4)(S3) · H2O Iso. 43_m_ : P_43_n
Nosean Na8(Al6Si6O24)(SO4) · H2O Iso. 43_m_ : P_43_n
Sapozhnikovite Na8(Al6Si6O24)(HS)2 Iso. 43_m_ : P_43_n
Slyudyankaite Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O Tric. 1 : _P_1
Sodalite Na4(Si3Al3)O12Cl Iso. 43_m_ : P_43_n
Vladimirivanovite Na6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2O Orth. m m m _(_2/_m_2/_m_2/m )

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.FB. Steudelite Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O Hex. 6_m_2 : P_62_c
9.FB. Sapozhnikovite Na8(Al6Si6O24)(HS)2 Iso. 43_m_ : P_43_n
9.FB. Betzite Na6Ca2(Al6Si6O24)Cl4 Hex. 6 : _P_63
9.FB. Slyudyankaite Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O Tric. 1 : _P_1
9.FB. Bolotinaite (Na7◻)(Al6Si6O24)F · 4H2O Iso. 43_m_ : I_43_m
9.FB. Wenlanzhangite-(Y) Y2V3+2V4+2(SiO4)2O4(OH)4 Tric. 1 : _P_1
9.FB.05 Afghanite (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 Trig. 3_m_ : P_31_c
9.FB.05 Bystrite (Na,K)7Ca(Al6Si6O24)(S5)Cl Trig. 3_m_ : P_31_c
9.FB.05 Cancrinite (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O Hex. 6 : _P_63
9.FB.05 Cancrisilite Na7(Al5Si7O24)(CO3) · 3H2O Hex. 6_m_ m : P_63_m c
9.FB.05 Davyne (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 Hex. 6/m : _P_63/m
9.FB.05 Franzinite (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O Hex.
9.FB.05 Giuseppettite (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 Trig. 3_m_ : P_31_c
9.FB.05 Hydroxycancrinite Na8(Al6Si6O24)(OH)2 · 2H2O Hex. 6 : _P_63
9.FB.05 Liottite (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 Hex. 6 : _P_6
9.FB.05 Microsommite Na4K2Ca2(Al6Si6O24)(SO4)Cl2 Hex. 622 : _P_6322
9.FB.05 Pitiglianoite Na6K2(Al6Si6O24)(SO4) · 2H2O Hex. 6 : _P_63
9.FB.05 Quadridavyne (Na,K)6Ca2(Al6Si6O24)Cl4 Hex. 6/m : _P_63/m
9.FB.05 Sacrofanite (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O Hex.
9.FB.05 Tounkite (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O Hex. 622 : _P_6222
9.FB.05 Vishnevite (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O Hex. 6 : _P_63
9.FB.05 Marinellite (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O Trig. 3_m_ : P_31_c
9.FB.05 Farneseite (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O Hex. 6/m : _P_63/m
9.FB.05 Alloriite (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 Trig. 3_m_ : P_31_c
9.FB.05 Biachellaite (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O Trig. 3 : _P_3
9.FB.05 Fantappièite [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O Trig. 3 : _R_3
9.FB.05 Kyanoxalite Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5) Hex. 6 : _P_63
9.FB.05 Balliranoite (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) Hex. 6 : _P_63
9.FB.05 Carbobystrite Na8(Al6Si6O24)(CO3) · 3.5H2O Trig. 3_m_ : P_31_c
9.FB.05 Depmeierite Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) Hex. 6 : _P_63
9.FB.05 Kircherite Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O Trig. 32 : _R_32
9.FB.05 Sulfhydrylbystrite Na5K2Ca[Al6Si6O24](S5)2(SH) Trig. 3_m_ : P_31_c
9.FB.10 Bicchulite Ca2(Al2SiO6)(OH)2 Iso. 43_m_ : I_43_m
9.FB.10 Danalite Be3Fe2+4(SiO4)3S Iso. 43_m_ : P_43_n
9.FB.10 Genthelvite Be3Zn4(SiO4)3S Iso. 43_m_ : P_43_n
9.FB.10 Haüyne Na3Ca(Si3Al3)O12(SO4) Iso. 43_m_ : P_43_n
9.FB.10 Helvine Be3Mn2+4(SiO4)3S Iso. 43_m_ : P_43_n
9.FB.10 Kamaishilite Ca2(Al2SiO6)(OH)2 Tet.
9.FB.10 Lazurite Na7Ca(Al6Si6O24)(SO4)(S3) · H2O Iso. 43_m_ : P_43_n
9.FB.10 Nosean Na8(Al6Si6O24)(SO4) · H2O Iso. 43_m_ : P_43_n
9.FB.10 Sodalite Na4(Si3Al3)O12Cl Iso. 43_m_ : P_43_n
9.FB.10 Tugtupite Na4BeAlSi4O12Cl Tet. 4 : _I_4
9.FB.10 Vladimirivanovite Na6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2O Orth. m m m _(_2/_m_2/_m_2/m )
9.FB.15 Marialite Na4Al3Si9O24Cl Tet. 4/m : _I_4/m
9.FB.15 Meionite Ca4Al6Si6O24CO3 Tet. 4/m : _I_4/m
9.FB.15 Silvialite (Ca,Na)4(Al6Si6O24)(SO4,CO3) Tet. 4/m : _I_4/m

Other InformationHide

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Thermal Behaviour:

Evolves ammonia and eurotropine above 600°C, becoming pitch-black.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for TsaregorodtseviteHide

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Reference List:

Sherriff, B.L., Sokolova, E.V., Cramer, J., Kunath-Fandrei, G., Jäger, C., Pautov, L.A. (1997) Changes in the crystal structure of tsaregorodtsevite [N(CH3)4][Si2(Si0.5Al0.5)O6]2 on heating. American Mineralogist: 82: 405-415.

Localities for TsaregorodtseviteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Poland
Lower Silesian Voivodeship Kłodzko County Nowa Ruda Słupiec Mine Słupiec heap ? Ł. Kruszewski (PXRD data)
Silesian Voivodeship Wodzisław County Radlin Marcel mine heap ? Łukasz Kruszewski (2012)
Russia (TL)
Khanty-Mansi Autonomous Okrug Man'-Khambo Mountains Yaruta Mt (TL) Pekov (1998)