Nacaphite (original) (raw)

A valid IMA mineral species

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About NacaphiteHide

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Crystal System:

Monoclinic

Name:

Named for its composition, including sodium (NAtrium), CAlcium, and PHosphorus.

It may be in a homologous series with seidozerite, as suggested by some authors.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2824:6

42e0180d-b70c-42e1-b689-8d15160e9c57

IMA Classification of NacaphiteHide

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Type description reference:

Classification of NacaphiteHide

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8.BO.05

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
O : With only large cations, (OH, etc.):RO4 about 1:1

41.3.6.1

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
3 : (AB)3(XO4)Zq

22.1.5

22 : Phosphates, Arsenates or Vanadates with other Anions
1 : Phosphates, arsenates or vanadates with fluoride

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Ncp IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of NacaphiteHide

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Optical Data of NacaphiteHide

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RI values:

_n_α = 1.508 _n_β = 1.515 _n_γ = 1.520

2V:

Measured: 80° , Calculated: 80°

δ = 0.012

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of NacaphiteHide

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Mindat Formula:

Na2Ca(PO4)F

Crystallography of NacaphiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 13.3185(14) Å, b = 7.0964(8) Å, c = 10.6490(11) Å
β = 113.526(1)°

Ratio:

a:b:c = 1.877 : 1 : 1.501

Comment:

pseudo-orthorhombic C-centred (a = 10.65, b = 24.43, c = 7.10)

Crystal StructureHide

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X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
2.649 Å (100)
3.054 Å (45)
3.049 Å (40)
2.005 Å (40)
1.762 Å (33)
3.51 Å (24)
1.470 Å (21)

Geological EnvironmentHide

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Type Occurrence of NacaphiteHide

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Place of Conservation of Type Material:

Geology Museum, Kola Branch, Academy of Sciences, Apatity, Russia, 5534.
Mining Institute, St. Petersburg, Russia, 1116/2.
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 79854.
The Natural History Museum, London, England, 1994,15.

Geological Setting of Type Material:

Ijolite-urtite pegmatite in an apatite deposit.

Reference:

Khomyakov, A.P., Kazakova, M.E., Pushcharovskii, D.Y. (1980) Nacaphite, Na2CaPO4F, a new mineral. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 109(1): 50-52.

Synonyms of NacaphiteHide

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Other Language Names for NacaphiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.BO. Ariegilatite BaCa12(SiO4)4(PO4)2F2O Trig. 3_m_ _(_32/m ) : R_3_m
8.BO. Aravaite Ba2Ca18(SiO4)6(PO4)3(CO3)F3O Trig. 3_m_ _(_32/m ) : R_3_m
8.BO. Theuerdankite Ag3AsO4 Iso. 43_m_ : P_43_n
8.BO.10 Petitjeanite Bi3(PO4)2O(OH) Tric. 1 : _P_1
8.BO.10 Schumacherite Bi3(VO4)2O(OH) Tric. 1 : _P_1
8.BO.10 Preisingerite Bi3(AsO4)2O(OH) Tric. 1 : _P_1
8.BO.15 Hechtsbergite Bi2(VO4)O(OH) Mon. 2/m : _P_21/b
8.BO.15 Smrkovecite Bi2(PO4)O(OH) Mon. 2/m : _P_21/b
8.BO.15 Atelestite Bi2(AsO4)O(OH) Mon. 2/m : _P_21/b
8.BO.20 Sahlinite Pb14(AsO4)2O9Cl4 Mon. 2/m : _B_2/b
8.BO.20 Kombatite Pb14(VO4)2O9Cl4 Mon. 2/m : _B_2/b
8.BO.25 Heneuite CaMg5(CO3)(PO4)3(OH) Tric. 1 : _P_1
8.BO.30 Nefedovite Na5Ca4(PO4)4F Tric.
8.BO.35 Kuznetsovite [Hg2]2+Hg2+[AsO4]Cl Iso. 23 : _P_213
8.BO.40 Artsmithite [Hg2]2+2Al(PO4)1.74(OH)1.78 Mon. 2/m : _B_2/b
8.BO.45 Schlegelite Bi7(AsO4)3(MoO4)2O4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BO.50 Hereroite [Pb32(O,◻)21](AsO4)2[(Si,As,V,Mo]O4)2Cl10 Mon. 2/m : _B_2/b
8.BO.50 Erikjonssonite (Pb32O21)[(V,Si,Mo,As)O4]4Cl9 Mon. 2/m : _B_2/b
8.BO.55 Rudabányaite (Ag2Hg2)(AsO4)Cl Iso. 43_m_ : F_43_c
8.BO.60 Segerstromite Ca3(As5+O4)2[As3+(OH)3]2 Iso. 23 : _I_213
8.BO.65 Wiklundite Pb2(Mn2+,Zn)3(Fe3+,Mn2+)2(Mn2+,Mg)19(As3+O3)2[(Si,As5+)O4]6(OH)18Cl6 Trig. 3_m_ _(_32/m ) : R_3_c

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for NacaphiteHide

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Reference List:

Sokolova, E. V., Kabalov, Y. K., Ferraris, G., Schneider, J., Khomyakov, A. P. (1999) Modular approach in solving the crystal structure of a synthetic dimorph of nacaphite, Na2Ca[PO4]F, from powder-differaction data. The Canadian Mineralogist, 37 (1) 83-90

Krivovichev, S. V., Yakovenchuk, V. N., Ivanyuk, G. Yu., Pakhomovsky, Y. A., Armbruster, T., Selivanova, E. A. (2007) The crystal structure of nacaphite, Na2Ca(PO4)F: A re-investigation. The Canadian Mineralogist, 45 (4) 915-920 doi:10.2113/gscanmin.45.4.915

Localities for NacaphiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Russia
Murmansk Oblast Khibiny Massif Koashva Mt IGC Stop 2-2 Arzamastsev et al. (2008)
Koashva Open Pit 33 IGC excursion No 47 +1 other reference
Kukisvumchorr Mt Kirovskii apatite mine
Rasvumchorr Mt (TL) Pekov (1998) +1 other reference
Rasvumchorr Mine Apatitovyi Tsirk Pavel.M. Kartashov (n.d.)
Tsentral'nyi Mine Pekov I.V. et al. (2010)
The Carbonatite Stock in the vicinity of Tul'ilukht Bay Olenii Ruchei (Olenii Creek; Oleny Ruchei) Pekov (1998)
Lovozero Massif ...
Lovozersky District Karnasurt Mountain Pakhomovsky et al. (2014)