Nickelboussingaultite (original) (raw)

A valid IMA mineral species

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About NickelboussingaultiteHide

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Formula:

(NH4)2Ni(SO4)2 · 6H2O

Colour:

Greenish blue to emerald-green

Specific Gravity:

1.85 (Calculated)

Crystal System:

Monoclinic

Name:

Named in 1976 by L. K. Yakhontova, G. A. Siderenko, T. I. Stolyarova, I. I. Plyusnina, and T. L. Ivanova in honor of Jean-Baptiste Joseph Dieudonne Boussingault [1802-1887] and for being the nickel analog of the root-name mineral.

This page provides mineralogical data about Nickelboussingaultite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2896:3

3452ecc1-e32f-45d4-ab8a-066092a6a944

IMA Classification of NickelboussingaultiteHide

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Classification of NickelboussingaultiteHide

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7.CC.60

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations

29.3.7.3

29 : HYDRATED ACID AND NORMAL SULFATES
3 : A2B(XO4)2·xH2O

25.12.8

25 : Sulphates
12 : Sulphates of Co and Ni

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Nbsg IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of NickelboussingaultiteHide

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Colour:

Greenish blue to emerald-green

Density:

1.85 g/cm3 (Calculated)

Optical Data of NickelboussingaultiteHide

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RI values:

_n_α = 1.490 _n_β = 1.494 _n_γ = 1.501

δ = 0.011

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

X ∧ c = 0°–4°.

Comments:

X = pale blue; Z = yellow.

Chemistry of NickelboussingaultiteHide

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Mindat Formula:

(NH4)2Ni(SO4)2 · 6H2O

Crystallography of NickelboussingaultiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 9.21(2) Å, b = 12.46(2) Å, c = 12.50(3) Å
β = 106.87°

Ratio:

a:b:c = 0.739 : 1 : 1.003

Unit Cell V:

1,372.73 ų (Calculated from Unit Cell)

Comment:

by analogy to synthetic (NH4)2Ni(SO4)2 • 6H2O

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0020239 Nickelboussingaultite Montgomery H, Lingafelter E C (1964) The crystal structure of Tutton's salts. II. Magnesium ammonium sulfate hexahydrate and nickel ammonium sulfate hexahydrate Acta Crystallographica 17 1478-1479 1964 synthetic 0 293
0015578 Nickelboussingaultite Treushnikov E N, Kuskov V I, Soboleva L V, Belov N V (1978) Distribution of electron density in nickel ammonium sulphate hexahydrate [Ni*6H2O](NH4)2(SO4)2 from x-ray diffraction data Soviet Physics Crystallography 23 30-41 1978 synthetic 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
4.153 Å (100)
3.759 Å (80)
11.7 Å (70)
2.119 Å (70)
3.022 Å (60)
2.793 Å (60)
1.806 Å (60)

Comments:

Noril’sk, Russia. Data from the type description.

Geological EnvironmentHide

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Type Occurrence of NickelboussingaultiteHide

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General Appearance of Type Material:

Films resembling sinter on pentlandite-chalcopyrite ore.

Place of Conservation of Type Material:

A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 83553.

Associated Minerals at Type Locality:

Relationship of Nickelboussingaultite to other SpeciesHide

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Other Members of this group:

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7.CC. Cobaltoblödite Na2Co(SO4)2 · 4H2O Mon. 2/m : _P_21/b
7.CC. Andychristyite PbCu2+Te6+O5(H2O) Tric. 1 : _P_1
7.CC. Ammoniovoltaite (NH4)2Fe2+5Fe3+3Al(SO4)12(H2O)18 Iso. m_3_m _(_4/_m_32/m ) : F d_3_c
7.CC.05 Krausite KFe(SO4)2 · H2O Mon. 2/m : _P_21/m
7.CC.10 Tamarugite NaAl(SO4)2 · 6H2O Mon. 2/m : _P_21/b
7.CC.15 Kalinite KAl(SO4)2 · 11H2O Mon. 2/m : _B_2/b
7.CC.15 Mendozite NaAl(SO4)2 · 11H2O Mon. 2/m : _B_2/b
7.CC.20 Lonecreekite (NH4)Fe3+(SO4)2 · 12H2O Iso. m_3(2/m_3) : P _a_3
7.CC.20 Alum-(K) KAl(SO4)2 · 12H2O Iso. m_3(2/m_3) : P _a_3
7.CC.20 Alum-(Na) NaAl(SO4)2 · 12H2O Iso. m_3(2/m_3) : P _a_3
7.CC.20 Tschermigite (NH4)Al(SO4)2 · 12H2O Iso. m_3(2/m_3) : P _a_3
7.CC.20 Lanmuchangite Tl+Al(SO4)2 · 12H2O Iso. m_3(2/m_3) : P _a_3
7.CC.25 Voltaite K2Fe2+5Fe3+3Al(SO4)12 · 18H2O Iso. m_3_m _(_4/_m_32/m ) : F d_3_c
7.CC.25 Zincovoltaite K2Zn5Fe3+3Al(SO4)12 · 18H2O Iso. m_3_m _(_4/_m_32/m ) : F d_3_c
7.CC.25 Pertlikite K2(Fe2+,Mg)2Mg4Fe3+2Al(SO4)12 · 18H2O Tet. 4/m m m _(_4/_m_2/_m_2/m ) : _I_41/a c d
7.CC.25 Ammoniomagnesiovoltaite (NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2O Iso. m_3_m _(_4/_m_32/m ) : F d_3_c
7.CC.25 Magnesiovoltaite K2Mg5Fe3+3Al(SO4)12 · 18H2O Iso. m_3_m _(_4/_m_32/m ) : F d_3_c
7.CC.30 Kröhnkite Na2Cu(SO4)2 · 2H2O Mon. 2/m : _P_21/b
7.CC.35 Ferrinatrite Na3Fe(SO4)3 · 3H2O Trig. 3 : _P_3
7.CC.40 Goldichite KFe(SO4)2 · 4H2O Mon. 2/m : _P_21/b
7.CC.45 Löweite Na12Mg7(SO4)13 · 15H2O Trig. 3 : _R_3
7.CC.50 Blödite Na2Mg(SO4)2 · 4H2O Mon. 2/m : _P_21/b
7.CC.50 Nickelblödite Na2(Ni,Mg)(SO4)2 · 4H2O Mon. 2/m : _P_21/b
7.CC.50 Changoite Na2Zn(SO4)2 · 4H2O Mon. 2/m : _P_21/b
7.CC.55 Leonite K2Mg(SO4)2 · 4H2O Mon. 2/m : _B_2/m
7.CC.55 Mereiterite K2Fe(SO4)2 · 4H2O Mon. 2/m : _B_2/m
7.CC.60 Boussingaultite (NH4)2Mg(SO4)2 · 6H2O Mon. 2/m : _P_21/b
7.CC.60 Cyanochroite K2Cu(SO4)2 · 6H2O Mon. 2/m : _P_21/b
7.CC.60 Mohrite (NH4)2Fe(SO4)2 · 6H2O Mon. 2/m : _P_21/b
7.CC.60 Picromerite K2Mg(SO4)2 · 6H2O Mon. 2/m : _P_2/b
7.CC.60 Nickelpicromerite K2Ni(SO4)2 · 6H2O Mon. 2/m : _P_21/b
7.CC.60 Katerinopoulosite (NH4)2Zn(SO4)2 · 6H2O Mon. 2/m : _P_21/b
7.CC.65 Polyhalite K2Ca2Mg(SO4)4 · 2H2O Tric. 1
7.CC.70 Leightonite K2Ca2Cu(SO4)4 · 2H2O Mon. 2/m : _B_2/b
7.CC.75 Amarillite NaFe(SO4)2 · 6H2O Mon. 2/m : _B_2/b
7.CC.80 Konyaite Na2Mg(SO4)2 · 5H2O Mon. 2/m : _P_21/b
7.CC.85 Wattevilleite Na2Ca(SO4)2 · 4H2O (?) Orth.
7.CC.85 Xocolatlite Ca2Mn4+2(Te6+O6)2 · H2O Mon. 2/m : _P_2/m
7.CC.90 Eckhardite (Ca,Pb)Cu2+Te6+O5(H2O) Mon. 2/m

Other InformationHide

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IR Spectrum:

Displays features in the ranges 3300-2900, 1700-1600, and 1480-1430 cm-1 characteristic of tetrahedral NH4.

Thermal Behaviour:

The DTA curve shows endothermic effects at l80, 270, 340, and 400°C, due to dehydration; another at 500°C due to melting with no weight loss; and another near 850°C due to disassociation of the sulfate.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for NickelboussingaultiteHide

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Reference List:

Yahontova, L.K., Sidrenko, G.A., Stolyarova, T.I., Plyusnina, I.I., Ivanova, T.L. (1976) Nickelboussingaultite, sulfate from zones of Norilskih Mestorozhdenix. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva, 105(6), 710-720.

Hawthorne, F.C., Bladh, K.W., Burke, E.A.J., Ercit, S., Grew, E.S., Grice, J.D., Puziewicz, J., Roberts, A.C., Schedler, R.A., Shigley, J.E. (1986) New mineral names. American Mineralogist: 71: 1543-1548.

Localities for NickelboussingaultiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Germany
Lower Saxony Goslar District Harz (Landkreis Goslar) Heimberg quarry Schnorrer-Köhler (1991)
North Rhine-Westphalia Cologne Aachen Alsdorf Anna mine Witzke et al. (2015)
Greece
Attica East Attica Lavreotiki Lavrion Mining District Km 3 Kaminiza mines Esperanza Mine Rieck et al. (2018)
Russia (TL)
Krasnoyarsk Krai Taymyrskiy Autonomous Okrug Taimyr Peninsula Putoran Plateau Norilsk-Talnakh Mining Region Talnakh Cu-Ni Deposit (TL) Pekov (1998)
USA
Arizona Coconino County Cameron Mining District Cameron Excalibur Mineral Corporation Data +1 other reference
Unnamed U prospect [1] Williams (1995) +1 other reference