Nakauriite (original) (raw)

A valid IMA mineral species

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About NakauriiteHide

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Formula:

Cu8(SO4)4(CO3)(OH)6 · 48H2O

May contain minor Mg, Ni.

Crystal System:

Orthorhombic

Name:

Named for the type locality.

The originally reported sulphate content appears to be questionable according to several literature sources; the crystal structure is unknown. Palenzona & Martinelli (2007) suggest a formula (Mg,Cu)x(CO3)y(OH)z•nH2O (x, y, z unknown).

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2948:9

c471d4d0-6ddf-43c6-8b34-640af657bcf6

IMA Classification of NakauriiteHide

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Type description reference:

Suzuki, Jujin, Ito, Masahiro, Sugiura, Tsutomu (1976) A new copper sulfate-carbonate hydroxide hydrate mineral, (Mn,Ni,Cu)8(SO4)4(CO3)(OH)6·48H2O, from Nakauri, Aichi Prefecture, Japan. The Journal of the Japanese Association of Mineralogists, Petrologists and Economic Geologists, 71 (7) 183-192 doi:10.2465/ganko1941.71.183

Classification of NakauriiteHide

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7.DG.30

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
G : With large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3

32.4.1.1

32 : COMPOUND SULFATES
4 : Hydrated Compound Sulfates containing Hydroxyl or Halogen

12.2.6

12 : Carbonates with other anions
2 : Carbonates with sulphate

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Nak IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of NakauriiteHide

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Density:

2.39(2) g/cm3 (Measured) 2.35 g/cm3 (Calculated)

Optical Data of NakauriiteHide

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RI values:

_n_α = 1.585 - 1.597 _n_β = 1.604 - 1.612 _n_γ = 1.612 - 1.618

2V:

Measured: 60° to 70°, Calculated: 65°

δ = 0.027

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

X = colorless, Y = very light greenish blue,Z = pale sky-blue to very light blue.

Chemistry of NakauriiteHide

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Mindat Formula:

Cu8(SO4)4(CO3)(OH)6 · 48H2O

May contain minor Mg, Ni.

Crystallography of NakauriiteHide

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Crystal System:

Orthorhombic

Cell Parameters:

a = 14.585 Å, b = 11.47 Å, c = 16.22 Å

Ratio:

a:b:c = 1.272 : 1 : 1.414

Unit Cell V:

2,713.44 ų (Calculated from Unit Cell)

Morphology:

Crystals are fibers, to 3 mm, in sprays and aggregates.

Comment:

Point Group: n.d; Space Group: n.d.

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
7.31 Å (100)
3.652 Å (20)
2.367 Å (16)
1.9148 Å (16)
4.840 Å (14)
3.936 Å (14)
2.397 Å (14)

Geological EnvironmentHide

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Type Occurrence of NakauriiteHide

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General Appearance of Type Material:

Bundled aggregates of very small slender to fibrous crystals, whose sizes are less than about 0.2 mm in length, 0.006 mm in width.

Place of Conservation of Type Material:

National Science Museum, Tokyo, Japan, M-24586; National Museum of Natural History, Washington, D.C., USA, 136584.

Geological Setting of Type Material:

Fissure-fillings in serpentinite

Associated Minerals at Type Locality:

Reference:

Suzuki, J., Ito, M., Sugiura, T. (1976) A new copper sulfate-carbonate hydroxide hydrate mineral, (Mn,Ni,Cu)8(SO4)4(CO3)(OH)6·48H2O, from Nakauri, Aichi Prefecture, Japan. Journal of Mineralogy, Petrology and Economic Geology: 71: 183-192.

Synonyms of NakauriiteHide

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Other Language Names for NakauriiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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7.DG. Mathesiusite K5(UO2)4(SO4)4(VO5) · 4H2O Tet. 4/m : _P_4/n
7.DG.05 Darapskite Na3(SO4)(NO3) · H2O Mon. 2/m : _P_21/m
7.DG.10 Clinoungemachite (Na, K, Fe, SO4) Mon. 2/m
7.DG.10 Humberstonite Na7K3Mg2(SO4)6(NO3)2 · 6H2O Trig. 3 : _R_3
7.DG.10 Ungemachite K3Na8Fe(SO4)6(NO3)2 · 6H2O Trig. 3 : _R_3
7.DG.15 Bentorite Ca6Cr2(SO4)3(OH)12 · 26H2O Trig. 3_m_ : P_31_c
7.DG.15 Charlesite Ca6(Al,Si)2(SO4)2[B(OH)4](OH,O)12 · 26H2O Trig. 3_m_ : P_31_c
7.DG.15 Ettringite Ca6Al2(SO4)3(OH)12 · 26H2O Trig. 3_m_ : P_31_c
7.DG.15 Jouravskite Ca3Mn4+(SO4)(CO3)(OH)6 · 12H2O Hex. 6 : _P_63
7.DG.15 Sturmanite Ca6Fe3+2(SO4)2.5[B(OH)4](OH)12 · 25H2O Trig. 3_m_ : P_31_c
7.DG.15 Thaumasite Ca3(SO4)[Si(OH)6](CO3) · 12H2O Hex. 6 : _P_63
7.DG.15 Carraraite Ca3(SO4)[Ge(OH)6](CO3) · 12H2O Hex.
7.DG.15 Buryatite Ca3(Si,Fe3+,Al)(SO4)B(OH)4(OH,O)6 · 12H2O Trig. 3_m_ : P_31_c
7.DG.15 Birunite Ca18(SiO3)8.5(CO3)8.5SO4 · 15H2O(?)
7.DG.15 Hielscherite Ca3Si(SO4)(SO3)(OH)6 · 11H2O Hex. 6 : _P_63
7.DG.15 Kottenheimite Ca 3Si(SO4)2(OH)6 · 12H2O Hex. 6/m : _P_63/m
7.DG.15 Imayoshiite Ca3Al(CO3)[B(OH)4](OH)6 · 12H2O Hex. 6 : _P_63
7.DG.15 Tatarinovite Ca3Al(SO4)[B(OH)4](OH)6 · 12H2O Hex. 6 : _P_63
7.DG.15 Siwaqaite Ca6Al2(CrO4)3(OH)12 · 26H2O Trig. 3_m_ : P_31_c
7.DG.15 Chiyokoite Ca3Si(CO3)[B(OH)4]O (OH)5 · 12H2O Hex. 6 : _P_63
7.DG.20 Rapidcreekite Ca2(SO4)(CO3) · 4H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
7.DG.25 Tatarskite Ca6Mg2(SO4)2(CO3)2(OH)4Cl4 · 7H2O Orth.
7.DG.35 Chessexite (Na,K)4Ca2(Mg,Zn)3Al8(SO4)10(SiO4)2 · 40H2O Orth.
7.DG.40 Carlosruizite K6(Na,K)4Na6Mg10(SeO4)12(IO3)12 · 12H2O Trig. 3_m_ _(_32/m ) : _P_3_c_1
7.DG.40 Fuenzalidaite K6(Na,K)4Na6Mg10(SO4)12(IO3)12 · 12H2O Trig. 3_m_ _(_32/m ) : _P_3_c_1
7.DG.45 Chelyabinskite (Ca,Mg)3(SO4,CO3)2[Si(OH)6] · 9H2O (?) Orth.
7.DG.55 Ramazzoite [Mg8Cu12(PO4)(CO3)4(OH)24(H2O)20][(H0.33SO4)3(H2O)36] Iso. 43_m_ : P_43_m
7.DG.60 Witzkeite Na4K4Ca(NO3)2(SO4)4 · 2H2O Mon. 2/m : _B_2/b

Other InformationHide

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Notes:

Effervescent in HCl, H2SO4, and HNO3

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for NakauriiteHide

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Reference List:

Suzuki, Jujin, Ito, Masahiro, Sugiura, Tsutomu (1976) A new copper sulfate-carbonate hydroxide hydrate mineral, (Mn,Ni,Cu)8(SO4)4(CO3)(OH)6·48H2O, from Nakauri, Aichi Prefecture, Japan. The Journal of the Japanese Association of Mineralogists, Petrologists and Economic Geologists, 71 (7) 183-192 doi:10.2465/ganko1941.71.183

Kolitsch, U., Rieck, B., Brandstätter, F., Schreiber, F., Fabritz, K. H., Blaß, G., Gröbner, J. (2014) Neufunde aus dem altem Bergbau und den Schlacken von Lavrion (I). Mineralien-Welt, 25 (1). 60-75

Localities for NakauriiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Austria
Styria Leoben District Sankt Stefan ob Leoben Lobminggraben Lobminggraben quarry Postl et al. (1988) +1 other reference
Murtal District Sankt Marein-Feistritz Gulsen Postl et al. (1988) +1 other reference
Germany
Rhineland-Palatinate Neuwied Unkel Rheinbreitbach Virneberg Mine Slag dumps ? Habel (2006) +1 other reference
Saxony-Anhalt Mansfeld-Südharz Eisleben Christophe Boutry collection
Greece
Attica East Attica Lavreotiki Lavrion mining district Sounion Cato Sounio mines Sounion Mine No. 19 Kolitsch et al. (2014)
Italy
Liguria Genoa Genoa Borzoli Mt. Ramazzo Mine Palenzona et al. (2007)
Lombardy Sondrio Province Torre di Santa Maria Ciappanico Rocca Castellaccio AA. VV. +1 other reference
Japan (TL)
Aichi Prefecture Shinshiro city Nakauri mine (TL) Suzuki et al. (1976) +1 other reference
Saitama Prefecture Kodama District Kamikawa-machi (Kamikawa-mura) Kosuge (1997)
Russia
Chelyabinsk Oblast Verkhny Ufaley Ufaley District (Ufalei District) Rodionovskoe chromite mine V.A. Popov analytical data (2012)
UK
Scotland Shetland Islands Unst Hagdale Quarry Braithwaite et al. (1983)
USA
Nevada Nye County Gabbs Mining District Gabbs American Mineralogist
Sierra Magnesite Mine Castor et al. (2004)
Pennsylvania Lancaster County Fulton Township Cedar Hill Quarry (Stoltzfuss Quarry)
Haines & Kibblehouse Penn-Maryland Materials Quarry Personally Collected 4/12/2008