Nakauriite (original) (raw)
A valid IMA mineral species
About NakauriiteHide
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Formula:
Cu8(SO4)4(CO3)(OH)6 · 48H2O
May contain minor Mg, Ni.
Crystal System:
Orthorhombic
Name:
Named for the type locality.
The originally reported sulphate content appears to be questionable according to several literature sources; the crystal structure is unknown. Palenzona & Martinelli (2007) suggest a formula (Mg,Cu)x(CO3)y(OH)z•nH2O (x, y, z unknown).
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:2948:9
c471d4d0-6ddf-43c6-8b34-640af657bcf6
IMA Classification of NakauriiteHide
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Type description reference:
Suzuki, Jujin, Ito, Masahiro, Sugiura, Tsutomu (1976) A new copper sulfate-carbonate hydroxide hydrate mineral, (Mn,Ni,Cu)8(SO4)4(CO3)(OH)6·48H2O, from Nakauri, Aichi Prefecture, Japan. The Journal of the Japanese Association of Mineralogists, Petrologists and Economic Geologists, 71 (7) 183-192 doi:10.2465/ganko1941.71.183
Classification of NakauriiteHide
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7.DG.30
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
G : With large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3
32.4.1.1
32 : COMPOUND SULFATES
4 : Hydrated Compound Sulfates containing Hydroxyl or Halogen
12.2.6
12 : Carbonates with other anions
2 : Carbonates with sulphate
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Nak | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of NakauriiteHide
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Density:
2.39(2) g/cm3 (Measured) 2.35 g/cm3 (Calculated)
Optical Data of NakauriiteHide
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RI values:
_n_α = 1.585 - 1.597 _n_β = 1.604 - 1.612 _n_γ = 1.612 - 1.618
2V:
Measured: 60° to 70°, Calculated: 65°
δ = 0.027
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Comments:
X = colorless, Y = very light greenish blue,Z = pale sky-blue to very light blue.
Chemistry of NakauriiteHide
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Mindat Formula:
Cu8(SO4)4(CO3)(OH)6 · 48H2O
May contain minor Mg, Ni.
Crystallography of NakauriiteHide
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Crystal System:
Orthorhombic
Cell Parameters:
a = 14.585 Å, b = 11.47 Å, c = 16.22 Å
Ratio:
a:b:c = 1.272 : 1 : 1.414
Unit Cell V:
2,713.44 ų (Calculated from Unit Cell)
Morphology:
Crystals are fibers, to 3 mm, in sprays and aggregates.
Comment:
Point Group: n.d; Space Group: n.d.
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
7.31 Å | (100) |
3.652 Å | (20) |
2.367 Å | (16) |
1.9148 Å | (16) |
4.840 Å | (14) |
3.936 Å | (14) |
2.397 Å | (14) |
Geological EnvironmentHide
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Type Occurrence of NakauriiteHide
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General Appearance of Type Material:
Bundled aggregates of very small slender to fibrous crystals, whose sizes are less than about 0.2 mm in length, 0.006 mm in width.
Place of Conservation of Type Material:
National Science Museum, Tokyo, Japan, M-24586; National Museum of Natural History, Washington, D.C., USA, 136584.
Geological Setting of Type Material:
Fissure-fillings in serpentinite
Associated Minerals at Type Locality:
Reference:
Suzuki, J., Ito, M., Sugiura, T. (1976) A new copper sulfate-carbonate hydroxide hydrate mineral, (Mn,Ni,Cu)8(SO4)4(CO3)(OH)6·48H2O, from Nakauri, Aichi Prefecture, Japan. Journal of Mineralogy, Petrology and Economic Geology: 71: 183-192.
Synonyms of NakauriiteHide
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Other Language Names for NakauriiteHide
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Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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7.DG. | Mathesiusite | K5(UO2)4(SO4)4(VO5) · 4H2O | Tet. 4/m : _P_4/n |
---|---|---|---|
7.DG.05 | Darapskite | Na3(SO4)(NO3) · H2O | Mon. 2/m : _P_21/m |
7.DG.10 | Clinoungemachite | (Na, K, Fe, SO4) | Mon. 2/m |
7.DG.10 | Humberstonite | Na7K3Mg2(SO4)6(NO3)2 · 6H2O | Trig. 3 : _R_3 |
7.DG.10 | Ungemachite | K3Na8Fe(SO4)6(NO3)2 · 6H2O | Trig. 3 : _R_3 |
7.DG.15 | Bentorite | Ca6Cr2(SO4)3(OH)12 · 26H2O | Trig. 3_m_ : P_31_c |
7.DG.15 | Charlesite | Ca6(Al,Si)2(SO4)2[B(OH)4](OH,O)12 · 26H2O | Trig. 3_m_ : P_31_c |
7.DG.15 | Ettringite | Ca6Al2(SO4)3(OH)12 · 26H2O | Trig. 3_m_ : P_31_c |
7.DG.15 | Jouravskite | Ca3Mn4+(SO4)(CO3)(OH)6 · 12H2O | Hex. 6 : _P_63 |
7.DG.15 | Sturmanite | Ca6Fe3+2(SO4)2.5[B(OH)4](OH)12 · 25H2O | Trig. 3_m_ : P_31_c |
7.DG.15 | Thaumasite | Ca3(SO4)[Si(OH)6](CO3) · 12H2O | Hex. 6 : _P_63 |
7.DG.15 | Carraraite | Ca3(SO4)[Ge(OH)6](CO3) · 12H2O | Hex. |
7.DG.15 | Buryatite | Ca3(Si,Fe3+,Al)(SO4)B(OH)4(OH,O)6 · 12H2O | Trig. 3_m_ : P_31_c |
7.DG.15 | Birunite | Ca18(SiO3)8.5(CO3)8.5SO4 · 15H2O(?) | |
7.DG.15 | Hielscherite | Ca3Si(SO4)(SO3)(OH)6 · 11H2O | Hex. 6 : _P_63 |
7.DG.15 | Kottenheimite | Ca 3Si(SO4)2(OH)6 · 12H2O | Hex. 6/m : _P_63/m |
7.DG.15 | Imayoshiite | Ca3Al(CO3)[B(OH)4](OH)6 · 12H2O | Hex. 6 : _P_63 |
7.DG.15 | Tatarinovite | Ca3Al(SO4)[B(OH)4](OH)6 · 12H2O | Hex. 6 : _P_63 |
7.DG.15 | Siwaqaite | Ca6Al2(CrO4)3(OH)12 · 26H2O | Trig. 3_m_ : P_31_c |
7.DG.15 | Chiyokoite | Ca3Si(CO3)[B(OH)4]O (OH)5 · 12H2O | Hex. 6 : _P_63 |
7.DG.20 | Rapidcreekite | Ca2(SO4)(CO3) · 4H2O | Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n |
7.DG.25 | Tatarskite | Ca6Mg2(SO4)2(CO3)2(OH)4Cl4 · 7H2O | Orth. |
7.DG.35 | Chessexite | (Na,K)4Ca2(Mg,Zn)3Al8(SO4)10(SiO4)2 · 40H2O | Orth. |
7.DG.40 | Carlosruizite | K6(Na,K)4Na6Mg10(SeO4)12(IO3)12 · 12H2O | Trig. 3_m_ _(_32/m ) : _P_3_c_1 |
7.DG.40 | Fuenzalidaite | K6(Na,K)4Na6Mg10(SO4)12(IO3)12 · 12H2O | Trig. 3_m_ _(_32/m ) : _P_3_c_1 |
7.DG.45 | Chelyabinskite | (Ca,Mg)3(SO4,CO3)2[Si(OH)6] · 9H2O (?) | Orth. |
7.DG.55 | Ramazzoite | [Mg8Cu12(PO4)(CO3)4(OH)24(H2O)20][(H0.33SO4)3(H2O)36] | Iso. 43_m_ : P_43_m |
7.DG.60 | Witzkeite | Na4K4Ca(NO3)2(SO4)4 · 2H2O | Mon. 2/m : _B_2/b |
Other InformationHide
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Notes:
Effervescent in HCl, H2SO4, and HNO3
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for NakauriiteHide
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References for NakauriiteHide
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Reference List:
Suzuki, Jujin, Ito, Masahiro, Sugiura, Tsutomu (1976) A new copper sulfate-carbonate hydroxide hydrate mineral, (Mn,Ni,Cu)8(SO4)4(CO3)(OH)6·48H2O, from Nakauri, Aichi Prefecture, Japan. The Journal of the Japanese Association of Mineralogists, Petrologists and Economic Geologists, 71 (7) 183-192 doi:10.2465/ganko1941.71.183
Localities for NakauriiteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
Austria | |
---|---|
Styria Leoben District Sankt Stefan ob Leoben Lobminggraben ⓘ Lobminggraben quarry | Postl et al. (1988) +1 other reference |
Murtal District Sankt Marein-Feistritz ⓘ Gulsen | Postl et al. (1988) +1 other reference |
Germany | |
Rhineland-Palatinate Neuwied Unkel Rheinbreitbach Virneberg Mine ⓘ Slag dumps ? | Habel (2006) +1 other reference |
Saxony-Anhalt Mansfeld-Südharz ⓘ Eisleben | Christophe Boutry collection |
Greece | |
Attica East Attica Lavreotiki Lavrion mining district Sounion Cato Sounio mines ⓘ Sounion Mine No. 19 | Kolitsch et al. (2014) |
Italy | |
Liguria Genoa Genoa Borzoli ⓘ Mt. Ramazzo Mine | Palenzona et al. (2007) |
Lombardy Sondrio Province Torre di Santa Maria Ciappanico ⓘ Rocca Castellaccio | AA. VV. +1 other reference |
Japan (TL) | |
Aichi Prefecture Shinshiro city ⓘ Nakauri mine (TL) | Suzuki et al. (1976) +1 other reference |
Saitama Prefecture Kodama District ⓘ Kamikawa-machi (Kamikawa-mura) | Kosuge (1997) |
Russia | |
Chelyabinsk Oblast Verkhny Ufaley Ufaley District (Ufalei District) ⓘ Rodionovskoe chromite mine | V.A. Popov analytical data (2012) |
UK | |
Scotland Shetland Islands Unst ⓘ Hagdale Quarry | Braithwaite et al. (1983) |
USA | |
Nevada Nye County Gabbs Mining District ⓘ Gabbs | American Mineralogist |
ⓘ Sierra Magnesite Mine | Castor et al. (2004) |
Pennsylvania Lancaster County Fulton Township ⓘ Cedar Hill Quarry (Stoltzfuss Quarry) | |
ⓘ Haines & Kibblehouse Penn-Maryland Materials Quarry | Personally Collected 4/12/2008 |